Articles | Volume 18, issue 15
https://doi.org/10.5194/acp-18-10973-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-10973-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
06 Aug 2018
Research article |
| 06 Aug 2018
| 06 Aug 2018
Synthesis and characterisation of peroxypinic acids as proxies for highly oxygenated molecules (HOMs) in secondary organic aerosol
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW,
UK
Aurélie Delvaux
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW,
UK
Steven J. Campbell
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW,
UK
Peter J. Gallimore
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW,
UK
Peter Grice
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW,
UK
Duncan J. Howe
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW,
UK
Dominik Pitton
Institute of Inorganic and Analytical Chemistry, University of Mainz,
55128 Mainz, Germany
Magda Claeys
Department of Pharmaceutical Sciences, University of Antwerp, 2610
Antwerp, Belgium
Thorsten Hoffmann
Institute of Inorganic and Analytical Chemistry, University of Mainz,
55128 Mainz, Germany
Markus Kalberer
CORRESPONDING AUTHOR
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW,
UK
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Cited
18 citations as recorded by crossref.
- pH Dependence of the OH Reactivity of Organic Acids in the Aqueous Phase J. Amorim et al. 10.1021/acs.est.0c03331
- Atmospheric conditions and composition that influence PM2.5 oxidative potential in Beijing, China S. Campbell et al. 10.5194/acp-21-5549-2021
- On the fate of oxygenated organic molecules in atmospheric aerosol particles V. Pospisilova et al. 10.1126/sciadv.aax8922
- Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol M. Yao et al. 10.1021/acs.est.2c01297
- Characterisation of atmospheric organic aerosols with one- and multidimensional liquid chromatography and mass spectrometry: State of the art and future perspectives S. Hildmann & T. Hoffmann 10.1016/j.trac.2024.117698
- Particle-phase accretion forms dimer esters in pinene secondary organic aerosol C. Kenseth et al. 10.1126/science.adi0857
- Iron and Copper Alter the Oxidative Potential of Secondary Organic Aerosol: Insights from Online Measurements and Model Development S. Campbell et al. 10.1021/acs.est.3c01975
- Emission dynamics of reactive oxygen species and oxidative potential in particles from a petrol car and wood stove B. Utinger et al. 10.5194/ar-3-205-2025
- Persistence of Monoterpene-Derived Organic Peroxides in the Atmospheric Aqueous Phase Z. Liu et al. 10.1021/acsearthspacechem.2c00145
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Characterizing Hydroxyl Radical Formation from the Light-Driven Fe(II)–Peracetic Acid Reaction, a Key Process for Aerosol-Cloud Chemistry S. Campbell et al. 10.1021/acs.est.3c10684
- An automated online field instrument to quantify the oxidative potential of aerosol particles via ascorbic acid oxidation B. Utinger et al. 10.5194/amt-16-2641-2023
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Short-lived reactive components substantially contribute to particulate matter oxidative potential S. Campbell et al. 10.1126/sciadv.adp8100
- Structures and reactivity of peroxy radicals and dimeric products revealed by online tandem mass spectrometry S. Tomaz et al. 10.1038/s41467-020-20532-2
- Analytical methods for peroxo acids – a review F. Sode 10.1039/C9AY00860H
- Development of a Physiologically Relevant Online Chemical Assay To Quantify Aerosol Oxidative Potential S. Campbell et al. 10.1021/acs.analchem.9b03282
18 citations as recorded by crossref.
- pH Dependence of the OH Reactivity of Organic Acids in the Aqueous Phase J. Amorim et al. 10.1021/acs.est.0c03331
- Atmospheric conditions and composition that influence PM2.5 oxidative potential in Beijing, China S. Campbell et al. 10.5194/acp-21-5549-2021
- On the fate of oxygenated organic molecules in atmospheric aerosol particles V. Pospisilova et al. 10.1126/sciadv.aax8922
- Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol M. Yao et al. 10.1021/acs.est.2c01297
- Characterisation of atmospheric organic aerosols with one- and multidimensional liquid chromatography and mass spectrometry: State of the art and future perspectives S. Hildmann & T. Hoffmann 10.1016/j.trac.2024.117698
- Particle-phase accretion forms dimer esters in pinene secondary organic aerosol C. Kenseth et al. 10.1126/science.adi0857
- Iron and Copper Alter the Oxidative Potential of Secondary Organic Aerosol: Insights from Online Measurements and Model Development S. Campbell et al. 10.1021/acs.est.3c01975
- Emission dynamics of reactive oxygen species and oxidative potential in particles from a petrol car and wood stove B. Utinger et al. 10.5194/ar-3-205-2025
- Persistence of Monoterpene-Derived Organic Peroxides in the Atmospheric Aqueous Phase Z. Liu et al. 10.1021/acsearthspacechem.2c00145
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Characterizing Hydroxyl Radical Formation from the Light-Driven Fe(II)–Peracetic Acid Reaction, a Key Process for Aerosol-Cloud Chemistry S. Campbell et al. 10.1021/acs.est.3c10684
- An automated online field instrument to quantify the oxidative potential of aerosol particles via ascorbic acid oxidation B. Utinger et al. 10.5194/amt-16-2641-2023
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Short-lived reactive components substantially contribute to particulate matter oxidative potential S. Campbell et al. 10.1126/sciadv.adp8100
- Structures and reactivity of peroxy radicals and dimeric products revealed by online tandem mass spectrometry S. Tomaz et al. 10.1038/s41467-020-20532-2
- Analytical methods for peroxo acids – a review F. Sode 10.1039/C9AY00860H
- Development of a Physiologically Relevant Online Chemical Assay To Quantify Aerosol Oxidative Potential S. Campbell et al. 10.1021/acs.analchem.9b03282
Latest update: 17 May 2025
Short summary
Aerosol particles are a major public health concern, but particle properties contributing to their toxicity are not well known. Oxidising components such as peroxy acids might contribute significantly to particle toxicity. However, there is a lack of analytical methods for their characterisation. We synthesized three peroxy acids, developed an analysis method and showed that degradation affects peracid yield, likely leading to underestimation of their concentration in conventional analyses.
Aerosol particles are a major public health concern, but particle properties contributing to...
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