Articles | Volume 18, issue 14
Atmos. Chem. Phys., 18, 10433–10457, 2018
https://doi.org/10.5194/acp-18-10433-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue: Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5)...
Research article
23 Jul 2018
Research article
| 23 Jul 2018
Observations of sesquiterpenes and their oxidation products in central Amazonia during the wet and dry seasons
Lindsay D. Yee et al.
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Cited
30 citations as recorded by crossref.
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- Key challenges for tropospheric chemistry in the Southern Hemisphere C. Paton-Walsh et al. 10.1525/elementa.2021.00050
- A perspective on the development of gas-phase chemical mechanisms for Eulerian air quality models W. Stockwell et al. 10.1080/10962247.2019.1694605
- Measurement report: Variability in the composition of biogenic volatile organic compounds in a Southeastern US forest and their role in atmospheric reactivity D. McGlynn et al. 10.5194/acp-21-15755-2021
- Long-term measurements of volatile organic compounds highlight the importance of sesquiterpenes for the atmospheric chemistry of a boreal forest H. Hellén et al. 10.5194/acp-18-13839-2018
- Chemical composition of ultrafine aerosol particles in central Amazonia during the wet season H. Glicker et al. 10.5194/acp-19-13053-2019
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Dry Deposition of Ozone Over Land: Processes, Measurement, and Modeling O. Clifton et al. 10.1029/2019RG000670
- Contributions of biomass-burning, urban, and biogenic emissions to the concentrations and light-absorbing properties of particulate matter in central Amazonia during the dry season S. de Sá et al. 10.5194/acp-19-7973-2019
- Characterizing Airborne Phthalate Concentrations and Dynamics in a Normally Occupied Residence D. Lunderberg et al. 10.1021/acs.est.9b02123
- Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A C. Mouchel-Vallon et al. 10.5194/acp-20-5995-2020
- Contrasting Reactive Organic Carbon Observations in the Southeast United States (SOAS) and Southern California (CalNex) C. Heald et al. 10.1021/acs.est.0c05027
- Improving thermal desorption aerosol gas chromatography using a dual-trap design H. Ren et al. 10.1016/j.chroma.2019.04.045
- Portable ozone calibration source independent of changes in temperature, pressure and humidity for research and regulatory applications J. Birks et al. 10.5194/amt-11-4797-2018
- Nocturnal Boundary Layer Erosion Analysis in the Amazon Using Large-Eddy Simulation during GoAmazon Project 2014/5 R. Carneiro et al. 10.3390/atmos12020240
- Chemical composition of PM<sub>2.5</sub> in October 2017 Northern California wildfire plumes Y. Liang et al. 10.5194/acp-21-5719-2021
- Cryptogamic organisms are a substantial source and sink for volatile organic compounds in the Amazon region A. Edtbauer et al. 10.1038/s43247-021-00328-y
- Contribution of Terpenes to Ozone Formation and Secondary Organic Aerosols in a Subtropical Forest Impacted by Urban Pollution C. Salvador et al. 10.3390/atmos11111232
- Optimisation of a thermal desorption–gas chromatography–mass spectrometry method for the analysis of monoterpenes, sesquiterpenes and diterpenes A. Helin et al. 10.5194/amt-13-3543-2020
- Atmospheric organic vapors in two European pine forests measured by a Vocus PTR-TOF: insights into monoterpene and sesquiterpene oxidation processes H. Li et al. 10.5194/acp-21-4123-2021
- Atmospheric β-Caryophyllene-Derived Ozonolysis Products at Interfaces A. Bé et al. 10.1021/acsearthspacechem.8b00156
- Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon L. Yee et al. 10.1021/acs.est.0c00805
- The maximum carbonyl ratio (MCR) as a new index for the structural classification of secondary organic aerosol components Y. Zhang et al. 10.1002/rcm.9113
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Quartz filter-based thermal desorption gas chromatography mass spectrometry for in-situ molecular level measurement of ambient organic aerosols H. Ren et al. 10.1016/j.chroma.2019.01.010
- Amazonian biogenic volatile organic compounds under global change A. Yáñez‐Serrano et al. 10.1111/gcb.15185
- Development of an in situ dual-channel thermal desorption gas chromatography instrument for consistent quantification of volatile, intermediate-volatility and semivolatile organic compounds R. Wernis et al. 10.5194/amt-14-6533-2021
- Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest R. Zaveri et al. 10.1126/sciadv.abj0329
- Urban pollution greatly enhances formation of natural aerosols over the Amazon rainforest M. Shrivastava et al. 10.1038/s41467-019-08909-4
29 citations as recorded by crossref.
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- Key challenges for tropospheric chemistry in the Southern Hemisphere C. Paton-Walsh et al. 10.1525/elementa.2021.00050
- A perspective on the development of gas-phase chemical mechanisms for Eulerian air quality models W. Stockwell et al. 10.1080/10962247.2019.1694605
- Measurement report: Variability in the composition of biogenic volatile organic compounds in a Southeastern US forest and their role in atmospheric reactivity D. McGlynn et al. 10.5194/acp-21-15755-2021
- Long-term measurements of volatile organic compounds highlight the importance of sesquiterpenes for the atmospheric chemistry of a boreal forest H. Hellén et al. 10.5194/acp-18-13839-2018
- Chemical composition of ultrafine aerosol particles in central Amazonia during the wet season H. Glicker et al. 10.5194/acp-19-13053-2019
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Dry Deposition of Ozone Over Land: Processes, Measurement, and Modeling O. Clifton et al. 10.1029/2019RG000670
- Contributions of biomass-burning, urban, and biogenic emissions to the concentrations and light-absorbing properties of particulate matter in central Amazonia during the dry season S. de Sá et al. 10.5194/acp-19-7973-2019
- Characterizing Airborne Phthalate Concentrations and Dynamics in a Normally Occupied Residence D. Lunderberg et al. 10.1021/acs.est.9b02123
- Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A C. Mouchel-Vallon et al. 10.5194/acp-20-5995-2020
- Contrasting Reactive Organic Carbon Observations in the Southeast United States (SOAS) and Southern California (CalNex) C. Heald et al. 10.1021/acs.est.0c05027
- Improving thermal desorption aerosol gas chromatography using a dual-trap design H. Ren et al. 10.1016/j.chroma.2019.04.045
- Portable ozone calibration source independent of changes in temperature, pressure and humidity for research and regulatory applications J. Birks et al. 10.5194/amt-11-4797-2018
- Nocturnal Boundary Layer Erosion Analysis in the Amazon Using Large-Eddy Simulation during GoAmazon Project 2014/5 R. Carneiro et al. 10.3390/atmos12020240
- Chemical composition of PM<sub>2.5</sub> in October 2017 Northern California wildfire plumes Y. Liang et al. 10.5194/acp-21-5719-2021
- Cryptogamic organisms are a substantial source and sink for volatile organic compounds in the Amazon region A. Edtbauer et al. 10.1038/s43247-021-00328-y
- Contribution of Terpenes to Ozone Formation and Secondary Organic Aerosols in a Subtropical Forest Impacted by Urban Pollution C. Salvador et al. 10.3390/atmos11111232
- Optimisation of a thermal desorption–gas chromatography–mass spectrometry method for the analysis of monoterpenes, sesquiterpenes and diterpenes A. Helin et al. 10.5194/amt-13-3543-2020
- Atmospheric organic vapors in two European pine forests measured by a Vocus PTR-TOF: insights into monoterpene and sesquiterpene oxidation processes H. Li et al. 10.5194/acp-21-4123-2021
- Atmospheric β-Caryophyllene-Derived Ozonolysis Products at Interfaces A. Bé et al. 10.1021/acsearthspacechem.8b00156
- Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon L. Yee et al. 10.1021/acs.est.0c00805
- The maximum carbonyl ratio (MCR) as a new index for the structural classification of secondary organic aerosol components Y. Zhang et al. 10.1002/rcm.9113
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Quartz filter-based thermal desorption gas chromatography mass spectrometry for in-situ molecular level measurement of ambient organic aerosols H. Ren et al. 10.1016/j.chroma.2019.01.010
- Amazonian biogenic volatile organic compounds under global change A. Yáñez‐Serrano et al. 10.1111/gcb.15185
- Development of an in situ dual-channel thermal desorption gas chromatography instrument for consistent quantification of volatile, intermediate-volatility and semivolatile organic compounds R. Wernis et al. 10.5194/amt-14-6533-2021
- Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest R. Zaveri et al. 10.1126/sciadv.abj0329
1 citations as recorded by crossref.
Discussed (preprint)
Latest update: 08 Aug 2022
Short summary
Biogenic volatile organic compounds react in the atmosphere to form secondary organic aerosol, yet the chemical pathways remain unclear. We collected filter samples and deployed a semi-volatile thermal desorption aerosol gas chromatograph in the central Amazon. We measured 30 sesquiterpenes and 4 diterpenes and find them to be important for reactive ozone loss. We estimate that sesquiterpene oxidation contributes at least 0.4–5 % (median 1 %) of observed submicron organic aerosol mass.
Biogenic volatile organic compounds react in the atmosphere to form secondary organic aerosol,...
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