Articles | Volume 18, issue 14
https://doi.org/10.5194/acp-18-10433-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-10433-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
23 Jul 2018
Research article |
| 23 Jul 2018
Observations of sesquiterpenes and their oxidation products in central Amazonia during the wet and dry seasons
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, Berkeley, California 94720, USA
Gabriel Isaacman-VanWertz
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, Berkeley, California 94720, USA
now at: Department of Civil and Environmental Engineering, Virginia Tech,
Blacksburg, Virginia 24061, USA
Rebecca A. Wernis
Department of Civil and Environmental Engineering, University of
California, Berkeley, Berkeley, California 94720, USA
Meng Meng
Department of Chemical Engineering, University of California, Berkeley,
Berkeley, California 94720, USA
now at: Department of Chemical Engineering and Applied
Chemistry, University of Toronto, Toronto, CA, USA
Ventura Rivera
Department of Chemical Engineering, University of California, Berkeley,
Berkeley, California 94720, USA
Nathan M. Kreisberg
Aerosol Dynamics Inc., Berkeley, California 94710, USA
Susanne V. Hering
Aerosol Dynamics Inc., Berkeley, California 94710, USA
Mads S. Bering
Department of Chemistry, Aarhus University, 8000 Aarhus C, Denmark
Marianne Glasius
Department of Chemistry, Aarhus University, 8000 Aarhus C, Denmark
Mary Alice Upshur
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA
Ariana Gray Bé
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA
Regan J. Thomson
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA
Franz M. Geiger
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA
John H. Offenberg
National Exposure Research Laboratory, Exposure Methods and
Measurements Division, United States Environmental Protection Agency,
Research Triangle Park, North Carolina 27711, USA
Michael Lewandowski
National Exposure Research Laboratory, Exposure Methods and
Measurements Division, United States Environmental Protection Agency,
Research Triangle Park, North Carolina 27711, USA
Ivan Kourtchev
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW,
UK
Markus Kalberer
Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW,
UK
Suzane de Sá
School of Engineering and Applied Sciences, Harvard University,
Cambridge, Massachusetts 02138, USA
Scot T. Martin
School of Engineering and Applied Sciences, Harvard University,
Cambridge, Massachusetts 02138, USA
Department of Earth and Planetary Sciences, Harvard University,
Cambridge, Massachusetts 02138, USA
M. Lizabeth Alexander
Environmental Molecular Sciences Laboratory, Pacific Northwest
National Laboratory, Richland, Washington 99352, USA
Brett B. Palm
Dept. of Chemistry and Cooperative Institute for Research in
Environmental Sciences (CIRES), University of Colorado, Boulder, Colorado 80309, USA
Weiwei Hu
Dept. of Chemistry and Cooperative Institute for Research in
Environmental Sciences (CIRES), University of Colorado, Boulder, Colorado 80309, USA
Pedro Campuzano-Jost
Dept. of Chemistry and Cooperative Institute for Research in
Environmental Sciences (CIRES), University of Colorado, Boulder, Colorado 80309, USA
Douglas A. Day
Dept. of Chemistry and Cooperative Institute for Research in
Environmental Sciences (CIRES), University of Colorado, Boulder, Colorado 80309, USA
Jose L. Jimenez
Dept. of Chemistry and Cooperative Institute for Research in
Environmental Sciences (CIRES), University of Colorado, Boulder, Colorado 80309, USA
Yingjun Liu
School of Engineering and Applied Sciences, Harvard University,
Cambridge, Massachusetts 02138, USA
now at: Department of Environmental Science, Policy, and Management,
University of California, Berkeley, Berkeley, California 94720, USA
Karena A. McKinney
School of Engineering and Applied Sciences, Harvard University,
Cambridge, Massachusetts 02138, USA
now at: Department of Chemistry, Colby College, Waterville, Maine 04901,
USA
Paulo Artaxo
Department of Applied Physics, University of São Paulo, SP,
Brazil
Juarez Viegas
Instituto Nacional de Pesquisas da Amazonia, Manaus, AM, Brazil
Antonio Manzi
Instituto Nacional de Pesquisas da Amazonia, Manaus, AM, Brazil
Maria B. Oliveira
Universidade do Estado do Amazonas, Manaus, AM, Brazil
Rodrigo de Souza
Universidade do Estado do Amazonas, Manaus, AM, Brazil
Luiz A. T. Machado
Instituto Nacional de Pesquisas Espiacais, São José dos
Campos, SP, Brazil
Karla Longo
Instituto Nacional de Pesquisas Espiacais, Cachoeira Paulista, SP,
Brazil
Allen H. Goldstein
Department of Environmental Science, Policy, and Management,
University of California, Berkeley, Berkeley, California 94720, USA
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Cited
44 citations as recorded by crossref.
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- Dry Deposition of Ozone Over Land: Processes, Measurement, and Modeling O. Clifton et al. 10.1029/2019RG000670
- Contributions of biomass-burning, urban, and biogenic emissions to the concentrations and light-absorbing properties of particulate matter in central Amazonia during the dry season S. de Sá et al. 10.5194/acp-19-7973-2019
- Characterizing Airborne Phthalate Concentrations and Dynamics in a Normally Occupied Residence D. Lunderberg et al. 10.1021/acs.est.9b02123
- Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A C. Mouchel-Vallon et al. 10.5194/acp-20-5995-2020
- Contrasting Reactive Organic Carbon Observations in the Southeast United States (SOAS) and Southern California (CalNex) C. Heald et al. 10.1021/acs.est.0c05027
- Oxidation product characterization from ozonolysis of the diterpene <i>ent</i>-kaurene Y. Luo et al. 10.5194/acp-22-5619-2022
- Improving thermal desorption aerosol gas chromatography using a dual-trap design H. Ren et al. 10.1016/j.chroma.2019.04.045
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- Nocturnal Boundary Layer Erosion Analysis in the Amazon Using Large-Eddy Simulation during GoAmazon Project 2014/5 R. Carneiro et al. 10.3390/atmos12020240
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- Contribution of Terpenes to Ozone Formation and Secondary Organic Aerosols in a Subtropical Forest Impacted by Urban Pollution C. Salvador et al. 10.3390/atmos11111232
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- Chemical Signatures of Seasonally Unique Anthropogenic Influences on Organic Aerosol Composition in the Central Amazon E. Franklin et al. 10.1021/acs.est.2c07260
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- New Evidence for the Importance of Non‐Stomatal Pathways in Ozone Deposition During Extreme Heat and Dry Anomalies A. Wong et al. 10.1029/2021GL095717
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- Atmospheric β-Caryophyllene-Derived Ozonolysis Products at Interfaces A. Bé et al. 10.1021/acsearthspacechem.8b00156
- Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon L. Yee et al. 10.1021/acs.est.0c00805
- Composition, concentration, and oxidant reactivity of sesquiterpenes in the southeastern U.S. G. Frazier et al. 10.1039/D2EA00059H
- The maximum carbonyl ratio (MCR) as a new index for the structural classification of secondary organic aerosol components Y. Zhang et al. 10.1002/rcm.9113
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- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
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- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Amazonian biogenic volatile organic compounds under global change A. Yáñez‐Serrano et al. 10.1111/gcb.15185
- Dynamic environmental interactions shaped by vegetative plant volatiles R. Escobar-Bravo et al. 10.1039/D2NP00061J
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Development of an in situ dual-channel thermal desorption gas chromatography instrument for consistent quantification of volatile, intermediate-volatility and semivolatile organic compounds R. Wernis et al. 10.5194/amt-14-6533-2021
- Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest R. Zaveri et al. 10.1126/sciadv.abj0329
- Seasonal shifts in isoprenoid emission composition from three hyperdominant tree species in central Amazonia E. Gomes Alves et al. 10.1111/plb.13419
- Urban pollution greatly enhances formation of natural aerosols over the Amazon rainforest M. Shrivastava et al. 10.1038/s41467-019-08909-4
43 citations as recorded by crossref.
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- Key challenges for tropospheric chemistry in the Southern Hemisphere C. Paton-Walsh et al. 10.1525/elementa.2021.00050
- Emissions of organic compounds from western US wildfires and their near-fire transformations Y. Liang et al. 10.5194/acp-22-9877-2022
- A perspective on the development of gas-phase chemical mechanisms for Eulerian air quality models W. Stockwell et al. 10.1080/10962247.2019.1694605
- Measurement report: Variability in the composition of biogenic volatile organic compounds in a Southeastern US forest and their role in atmospheric reactivity D. McGlynn et al. 10.5194/acp-21-15755-2021
- Long-term measurements of volatile organic compounds highlight the importance of sesquiterpenes for the atmospheric chemistry of a boreal forest H. Hellén et al. 10.5194/acp-18-13839-2018
- Chemical composition of ultrafine aerosol particles in central Amazonia during the wet season H. Glicker et al. 10.5194/acp-19-13053-2019
- Linking gas, particulate, and toxic endpoints to air emissions in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) H. Pye et al. 10.5194/acp-23-5043-2023
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Dry Deposition of Ozone Over Land: Processes, Measurement, and Modeling O. Clifton et al. 10.1029/2019RG000670
- Contributions of biomass-burning, urban, and biogenic emissions to the concentrations and light-absorbing properties of particulate matter in central Amazonia during the dry season S. de Sá et al. 10.5194/acp-19-7973-2019
- Characterizing Airborne Phthalate Concentrations and Dynamics in a Normally Occupied Residence D. Lunderberg et al. 10.1021/acs.est.9b02123
- Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A C. Mouchel-Vallon et al. 10.5194/acp-20-5995-2020
- Contrasting Reactive Organic Carbon Observations in the Southeast United States (SOAS) and Southern California (CalNex) C. Heald et al. 10.1021/acs.est.0c05027
- Oxidation product characterization from ozonolysis of the diterpene <i>ent</i>-kaurene Y. Luo et al. 10.5194/acp-22-5619-2022
- Improving thermal desorption aerosol gas chromatography using a dual-trap design H. Ren et al. 10.1016/j.chroma.2019.04.045
- Portable ozone calibration source independent of changes in temperature, pressure and humidity for research and regulatory applications J. Birks et al. 10.5194/amt-11-4797-2018
- Minor contributions of daytime monoterpenes are major contributors to atmospheric reactivity D. McGlynn et al. 10.5194/bg-20-45-2023
- Nocturnal Boundary Layer Erosion Analysis in the Amazon Using Large-Eddy Simulation during GoAmazon Project 2014/5 R. Carneiro et al. 10.3390/atmos12020240
- Chemical composition of PM<sub>2.5</sub> in October 2017 Northern California wildfire plumes Y. Liang et al. 10.5194/acp-21-5719-2021
- Cryptogamic organisms are a substantial source and sink for volatile organic compounds in the Amazon region A. Edtbauer et al. 10.1038/s43247-021-00328-y
- Characteristics and degradation of organic aerosols from cooking sources based on hourly observations of organic molecular markers in urban environments R. Li et al. 10.5194/acp-23-3065-2023
- Contribution of Terpenes to Ozone Formation and Secondary Organic Aerosols in a Subtropical Forest Impacted by Urban Pollution C. Salvador et al. 10.3390/atmos11111232
- Tropical and Boreal Forest – Atmosphere Interactions: A Review P. Artaxo et al. 10.16993/tellusb.34
- Chemical Signatures of Seasonally Unique Anthropogenic Influences on Organic Aerosol Composition in the Central Amazon E. Franklin et al. 10.1021/acs.est.2c07260
- Optimisation of a thermal desorption–gas chromatography–mass spectrometry method for the analysis of monoterpenes, sesquiterpenes and diterpenes A. Helin et al. 10.5194/amt-13-3543-2020
- New Evidence for the Importance of Non‐Stomatal Pathways in Ozone Deposition During Extreme Heat and Dry Anomalies A. Wong et al. 10.1029/2021GL095717
- Atmospheric organic vapors in two European pine forests measured by a Vocus PTR-TOF: insights into monoterpene and sesquiterpene oxidation processes H. Li et al. 10.5194/acp-21-4123-2021
- Atmospheric β-Caryophyllene-Derived Ozonolysis Products at Interfaces A. Bé et al. 10.1021/acsearthspacechem.8b00156
- Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon L. Yee et al. 10.1021/acs.est.0c00805
- Composition, concentration, and oxidant reactivity of sesquiterpenes in the southeastern U.S. G. Frazier et al. 10.1039/D2EA00059H
- The maximum carbonyl ratio (MCR) as a new index for the structural classification of secondary organic aerosol components Y. Zhang et al. 10.1002/rcm.9113
- Ch3MS-RF: a random forest model for chemical characterization and improved quantification of unidentified atmospheric organics detected by chromatography–mass spectrometry techniques E. Franklin et al. 10.5194/amt-15-3779-2022
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Quartz filter-based thermal desorption gas chromatography mass spectrometry for in-situ molecular level measurement of ambient organic aerosols H. Ren et al. 10.1016/j.chroma.2019.01.010
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Amazonian biogenic volatile organic compounds under global change A. Yáñez‐Serrano et al. 10.1111/gcb.15185
- Dynamic environmental interactions shaped by vegetative plant volatiles R. Escobar-Bravo et al. 10.1039/D2NP00061J
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Development of an in situ dual-channel thermal desorption gas chromatography instrument for consistent quantification of volatile, intermediate-volatility and semivolatile organic compounds R. Wernis et al. 10.5194/amt-14-6533-2021
- Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest R. Zaveri et al. 10.1126/sciadv.abj0329
- Seasonal shifts in isoprenoid emission composition from three hyperdominant tree species in central Amazonia E. Gomes Alves et al. 10.1111/plb.13419
1 citations as recorded by crossref.
Discussed (preprint)
Latest update: 28 Sep 2023
Short summary
Biogenic volatile organic compounds react in the atmosphere to form secondary organic aerosol, yet the chemical pathways remain unclear. We collected filter samples and deployed a semi-volatile thermal desorption aerosol gas chromatograph in the central Amazon. We measured 30 sesquiterpenes and 4 diterpenes and find them to be important for reactive ozone loss. We estimate that sesquiterpene oxidation contributes at least 0.4–5 % (median 1 %) of observed submicron organic aerosol mass.
Biogenic volatile organic compounds react in the atmosphere to form secondary organic aerosol,...
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