Articles | Volume 17, issue 2
https://doi.org/10.5194/acp-17-883-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-883-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| Highlight paper
| 
20 Jan 2017
Research article | Highlight paper |
| 20 Jan 2017
Determination of the atmospheric lifetime and global warming potential of sulfur hexafluoride using a three-dimensional model
Tamás Kovács
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Wuhu Feng
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
NCAS, School of Earth and Environment, University of Leeds, Leeds, LS2
9JT, UK
Anna Totterdill
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
John M. C. Plane
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Sandip Dhomse
NCAS, School of Earth and Environment, University of Leeds, Leeds, LS2
9JT, UK
Juan Carlos Gómez-Martín
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Gabriele P. Stiller
Karlsruhe Institute of Technology, IMK-ASF, PO BOX 3640, 76021
Karlsruhe, Germany
Florian J. Haenel
Karlsruhe Institute of Technology, IMK-ASF, PO BOX 3640, 76021
Karlsruhe, Germany
Christopher Smith
Energy Research Institute, School of Chemical and Process Engineering,
University of Leeds, Leeds, LS2 9JT, UK
Piers M. Forster
NCAS, School of Earth and Environment, University of Leeds, Leeds, LS2
9JT, UK
Rolando R. García
National Center for Atmospheric Research (NCAR), Boulder, Colorado,
USA
Daniel R. Marsh
National Center for Atmospheric Research (NCAR), Boulder, Colorado,
USA
Martyn P. Chipperfield
CORRESPONDING AUTHOR
NCAS, School of Earth and Environment, University of Leeds, Leeds, LS2
9JT, UK
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53 citations as recorded by crossref.
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- Atmospheric trends of long-lived halogenated gases derived from 15 years of IASI measurements H. De Longueville et al. 10.1016/j.jqsrt.2023.108755
- New infrared absorption cross sections for the infrared limb sounding of sulfur hexafluoride (SF6) J. Harrison 10.1016/j.jqsrt.2020.107202
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- Theoretical Characterizations on the Eco-Friendly Gas Tetrafluoropropyne for Electrical Insulation to Replace Sulfur Hexafluoride M. Zhang et al. 10.1021/acs.jpca.3c04940
- Theoretical study on the interaction between SF6 and TiO2(001) surface: A DFT+U study Y. Wu et al. 10.1016/j.jfluchem.2024.110272
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- Updated Global Warming Potentials and Radiative Efficiencies of Halocarbons and Other Weak Atmospheric Absorbers Ø. Hodnebrog et al. 10.1029/2019RG000691
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- Sustained growth of sulfur hexafluoride emissions in China inferred from atmospheric observations M. An et al. 10.1038/s41467-024-46084-3
- Activation and Catalytic Degradation of SF6 and PhSF5 at a Bismuth Center V. Béland et al. 10.1021/jacs.4c07044
- The strength of the meridional overturning circulation of the stratosphere M. Linz et al. 10.1038/ngeo3013
- Decoupling the Effects of Transport and Chemical Loss on Tropospheric Composition: A Model Study of Path‐Dependent Lifetimes H. Yang et al. 10.1002/2017JD027871
- Impacts of meteoric sulfur in the Earth's atmosphere J. Gómez Martín et al. 10.1002/2017JD027218
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- Quantification of the SF6 lifetime based on mesospheric loss measured in the stratospheric polar vortex E. Ray et al. 10.1002/2016JD026198
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- Directions of Development of Diagnostic Methods of Vacuum Medium-Voltage Switchgear P. Węgierek et al. 10.3390/en16052087
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- The impact of sulfur hexafluoride (SF6) sinks on age of air climatologies and trends S. Loeffel et al. 10.5194/acp-22-1175-2022
- Measurement report: Radiative efficiencies of (CF3)2CFCN, CF3OCFCF2, and CF3OCF2CF3 B. Trisna et al. 10.5194/acp-23-4489-2023
- Evaluation of stratospheric age of air from CF4, C2F6, C3F8, CHF3, HFC-125, HFC-227ea and SF6; implications for the calculations of halocarbon lifetimes, fractional release factors and ozone depletion potentials E. Leedham Elvidge et al. 10.5194/acp-18-3369-2018
- Organic and inorganic bromine measurements around the extratropical tropopause and lowermost stratosphere: insights into the transport pathways and total bromine M. Rotermund et al. 10.5194/acp-21-15375-2021
- The increasing atmospheric burden of the greenhouse gas sulfur hexafluoride (SF6) P. Simmonds et al. 10.5194/acp-20-7271-2020
- Investigation of the Arc Characteristics in a Nozzle with C4F7N/CO2 Mixtures W. Wang et al. 10.3390/en17184593
- Experimental research and reaction process analysis of degradation of strong greenhouse gas SF 6 using 304 stainless steel J. Ma et al. 10.1080/15567036.2024.2421423
53 citations as recorded by crossref.
- Sensitivity of age of air trends to the derivation method for non-linear increasing inert SF6 F. Fritsch et al. 10.5194/acp-20-8709-2020
- Rational regulating pore structures of covalent organic frameworks for sulfur hexafluoride capture and separation Q. Liao et al. 10.1016/j.seppur.2022.122595
- Mechanistic and kinetic study of the oxidation of trifluoroacetonitrile by hydroxyl and oxygen M. Zhang et al. 10.1002/qua.27147
- Towards a complete elucidation of the ro-vibrational band structure in the SF6 infrared spectrum from full quantum-mechanical calculations M. Rey et al. 10.1039/D0CP05727D
- Atmospheric trends of long-lived halogenated gases derived from 15 years of IASI measurements H. De Longueville et al. 10.1016/j.jqsrt.2023.108755
- New infrared absorption cross sections for the infrared limb sounding of sulfur hexafluoride (SF6) J. Harrison 10.1016/j.jqsrt.2020.107202
- Simulating age of air and the distribution of SF6 in the stratosphere with the SILAM model R. Kouznetsov et al. 10.5194/acp-20-5837-2020
- Theoretical Characterizations on the Eco-Friendly Gas Tetrafluoropropyne for Electrical Insulation to Replace Sulfur Hexafluoride M. Zhang et al. 10.1021/acs.jpca.3c04940
- Theoretical study on the interaction between SF6 and TiO2(001) surface: A DFT+U study Y. Wu et al. 10.1016/j.jfluchem.2024.110272
- Ground-based FTIR retrievals of SF6 on Reunion Island M. Zhou et al. 10.5194/amt-11-651-2018
- On the impact of recent developments of the LMDz atmospheric general circulation model on the simulation of CO2 transport M. Remaud et al. 10.5194/gmd-11-4489-2018
- Artificial Greenhouse Gases as Exoplanet Technosignatures E. Schwieterman et al. 10.3847/1538-4357/ad4ce8
- Ground-based high-resolution remote sensing of sulphur hexafluoride (SF6) over Hefei, China: characterization, optical misalignment, influence, and variability H. Yin et al. 10.1364/OE.440193
- Updated Global Warming Potentials and Radiative Efficiencies of Halocarbons and Other Weak Atmospheric Absorbers Ø. Hodnebrog et al. 10.1029/2019RG000691
- The interhemispheric gradient of SF6 in the upper troposphere T. Schuck et al. 10.5194/acp-24-689-2024
- Sustained growth of sulfur hexafluoride emissions in China inferred from atmospheric observations M. An et al. 10.1038/s41467-024-46084-3
- Activation and Catalytic Degradation of SF6 and PhSF5 at a Bismuth Center V. Béland et al. 10.1021/jacs.4c07044
- The strength of the meridional overturning circulation of the stratosphere M. Linz et al. 10.1038/ngeo3013
- Decoupling the Effects of Transport and Chemical Loss on Tropospheric Composition: A Model Study of Path‐Dependent Lifetimes H. Yang et al. 10.1002/2017JD027871
- Impacts of meteoric sulfur in the Earth's atmosphere J. Gómez Martín et al. 10.1002/2017JD027218
- Comparison of mean age of air in five reanalyses using the BASCOE transport model S. Chabrillat et al. 10.5194/acp-18-14715-2018
- Role Of the Sun and the Middle atmosphere/thermosphere/ionosphere In Climate (ROSMIC): a retrospective and prospective view W. Ward et al. 10.1186/s40645-021-00433-8
- Measurement report: Greenhouse gas profiles and age of air from the 2021 HEMERA-TWIN balloon launch T. Schuck et al. 10.5194/acp-25-4333-2025
- Environment-Friendly and Efficient Gaseous Insulator as a Potential Alternative to SF6 H. Kharal et al. 10.3390/pr7100740
- Degradation of SF6 by dielectric barrier discharge cooperating with TiO2 photocatalysis: Insights into the reaction mechanism Y. Wu et al. 10.1016/j.apsusc.2024.159957
- A quantum chemical prediction on arc interruption capability of dielectric gases M. Zhang et al. 10.1002/qua.27224
- Age of air as a diagnostic for transport timescales in global models M. Krol et al. 10.5194/gmd-11-3109-2018
- Bipolar carbon and hydrogen isotope constraints on the Holocene methane budget J. Beck et al. 10.5194/bg-15-7155-2018
- Ab Initio Optimized All‐Atom Force Field for Vapor–Liquid Equilibria Simulation of Trifluoromethanesulfonyl Fluoride W. Liu et al. 10.1002/qua.70035
- Mechanistic and Kinetic Investigations on Decomposition of Trifluoromethanesulfonyl Fluoride in the Presence of Water Vapor and Electric Field M. Zhang et al. 10.1021/acs.jpca.2c07614
- A global re-analysis of regionally resolved emissions and atmospheric mole fractions of SF6 for the period 2005–2021 M. Vojta et al. 10.5194/acp-24-12465-2024
- Electron swarm coefficients and critical field strength of the gaseous ternary mixtures CF3I-SF6-N2 and CF3I-SF6-CO2 O. González-Magaña et al. 10.1088/1361-6463/ab7620
- Extreme learning machine and genetic algorithm in quantitative analysis of sulfur hexafluoride by infrared spectroscopy H. Liu et al. 10.1364/AO.450805
- Quantification of the SF6 lifetime based on mesospheric loss measured in the stratospheric polar vortex E. Ray et al. 10.1002/2016JD026198
- Quantifying the effect of mixing on the mean age of air in CCMVal-2 and CCMI-1 models S. Dietmüller et al. 10.5194/acp-18-6699-2018
- Correction of stratospheric age of air (AoA) derived from sulfur hexafluoride (SF6) for the effect of chemical sinks H. Garny et al. 10.5194/acp-24-4193-2024
- Directions of Development of Diagnostic Methods of Vacuum Medium-Voltage Switchgear P. Węgierek et al. 10.3390/en16052087
- Asymmetry and pathways of inter-hemispheric transport in the upper troposphere and lower stratosphere X. Yan et al. 10.5194/acp-21-6627-2021
- Tracking and Reducing SF6 Usage in Radiation Oncology: A Step Toward Net-Zero Health Care Emissions K. Lichter et al. 10.1016/j.prro.2023.06.003
- Trends in N2O and SF6 mole fractions in archived air samples from Cape Meares, Oregon (USA), 1978–1996 T. Rolfe & A. Rice 10.5194/acp-19-8967-2019
- Theoretical Investigation on Atmospheric Chemistry of Nitryl Cyanide: A Novel Fluorine-Free Dielectric Gas P. Heng et al. 10.1021/acs.jpca.3c02769
- Seasonal Variations of SF6, CO2, CH4, and N2O in the UT/LS Region due to Emissions, Transport, and Chemistry J. Bisht et al. 10.1029/2020JD033541
- Evaluating the Environmental Impact of Radiation Therapy Using Life Cycle Assessments: A Critical Review K. Lichter et al. 10.1016/j.ijrobp.2023.04.036
- Gravitational separation of Ar∕N2 and age of air in the lowermost stratosphere in airborne observations and a chemical transport model B. Birner et al. 10.5194/acp-20-12391-2020
- Gravimetric Standard Gas Mixtures for Global Monitoring of Atmospheric SF6 J. Lim et al. 10.1021/acs.analchem.7b02545
- Theoretical Study on the Mechanisms and Kinetics of Atmospheric Oxidation of Tetrafluoropropyne and Its Analogues M. Zhang et al. 10.1021/acs.jpca.3c08331
- The impact of sulfur hexafluoride (SF6) sinks on age of air climatologies and trends S. Loeffel et al. 10.5194/acp-22-1175-2022
- Measurement report: Radiative efficiencies of (CF3)2CFCN, CF3OCFCF2, and CF3OCF2CF3 B. Trisna et al. 10.5194/acp-23-4489-2023
- Evaluation of stratospheric age of air from CF4, C2F6, C3F8, CHF3, HFC-125, HFC-227ea and SF6; implications for the calculations of halocarbon lifetimes, fractional release factors and ozone depletion potentials E. Leedham Elvidge et al. 10.5194/acp-18-3369-2018
- Organic and inorganic bromine measurements around the extratropical tropopause and lowermost stratosphere: insights into the transport pathways and total bromine M. Rotermund et al. 10.5194/acp-21-15375-2021
- The increasing atmospheric burden of the greenhouse gas sulfur hexafluoride (SF6) P. Simmonds et al. 10.5194/acp-20-7271-2020
- Investigation of the Arc Characteristics in a Nozzle with C4F7N/CO2 Mixtures W. Wang et al. 10.3390/en17184593
- Experimental research and reaction process analysis of degradation of strong greenhouse gas SF 6 using 304 stainless steel J. Ma et al. 10.1080/15567036.2024.2421423
Discussed (final revised paper)
Latest update: 21 May 2025
Short summary
Sulfur hexafluoride (SF6) is a very potent greenhouse gas, which is present in the atmosphere only through its industrial use, for example as an electrical insulator. To estimate accurately the impact of SF6 emissions on climate we need to know how long it persists in the atmosphere before being removed. Previous estimates of the SF6 lifetime indicate a large degree of uncertainty. Here we use a detailed atmospheric model to calculate a current best estimate of the SF6 lifetime.
Sulfur hexafluoride (SF6) is a very potent greenhouse gas, which is present in the atmosphere...
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