Articles | Volume 17, issue 2
https://doi.org/10.5194/acp-17-883-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-883-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| Highlight paper
| 
20 Jan 2017
Research article | Highlight paper |
| 20 Jan 2017
Determination of the atmospheric lifetime and global warming potential of sulfur hexafluoride using a three-dimensional model
Tamás Kovács
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Wuhu Feng
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
NCAS, School of Earth and Environment, University of Leeds, Leeds, LS2
9JT, UK
Anna Totterdill
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
John M. C. Plane
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Sandip Dhomse
NCAS, School of Earth and Environment, University of Leeds, Leeds, LS2
9JT, UK
Juan Carlos Gómez-Martín
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Gabriele P. Stiller
Karlsruhe Institute of Technology, IMK-ASF, PO BOX 3640, 76021
Karlsruhe, Germany
Florian J. Haenel
Karlsruhe Institute of Technology, IMK-ASF, PO BOX 3640, 76021
Karlsruhe, Germany
Christopher Smith
Energy Research Institute, School of Chemical and Process Engineering,
University of Leeds, Leeds, LS2 9JT, UK
Piers M. Forster
NCAS, School of Earth and Environment, University of Leeds, Leeds, LS2
9JT, UK
Rolando R. García
National Center for Atmospheric Research (NCAR), Boulder, Colorado,
USA
Daniel R. Marsh
National Center for Atmospheric Research (NCAR), Boulder, Colorado,
USA
Martyn P. Chipperfield
CORRESPONDING AUTHOR
NCAS, School of Earth and Environment, University of Leeds, Leeds, LS2
9JT, UK
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51 citations as recorded by crossref.
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- Towards a complete elucidation of the ro-vibrational band structure in the SF6 infrared spectrum from full quantum-mechanical calculations M. Rey et al. 10.1039/D0CP05727D
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- New infrared absorption cross sections for the infrared limb sounding of sulfur hexafluoride (SF6) J. Harrison 10.1016/j.jqsrt.2020.107202
- Simulating age of air and the distribution of SF<sub>6</sub> in the stratosphere with the SILAM model R. Kouznetsov et al. 10.5194/acp-20-5837-2020
- Theoretical Characterizations on the Eco-Friendly Gas Tetrafluoropropyne for Electrical Insulation to Replace Sulfur Hexafluoride M. Zhang et al. 10.1021/acs.jpca.3c04940
- Theoretical study on the interaction between SF6 and TiO2(001) surface: A DFT+U study Y. Wu et al. 10.1016/j.jfluchem.2024.110272
- Ground-based FTIR retrievals of SF<sub>6</sub> on Reunion Island M. Zhou et al. 10.5194/amt-11-651-2018
- On the impact of recent developments of the LMDz atmospheric general circulation model on the simulation of CO<sub>2</sub> transport M. Remaud et al. 10.5194/gmd-11-4489-2018
- Artificial Greenhouse Gases as Exoplanet Technosignatures E. Schwieterman et al. 10.3847/1538-4357/ad4ce8
- Ground-based high-resolution remote sensing of sulphur hexafluoride (SF6) over Hefei, China: characterization, optical misalignment, influence, and variability H. Yin et al. 10.1364/OE.440193
- Updated Global Warming Potentials and Radiative Efficiencies of Halocarbons and Other Weak Atmospheric Absorbers Ø. Hodnebrog et al. 10.1029/2019RG000691
- The interhemispheric gradient of SF6 in the upper troposphere T. Schuck et al. 10.5194/acp-24-689-2024
- Sustained growth of sulfur hexafluoride emissions in China inferred from atmospheric observations M. An et al. 10.1038/s41467-024-46084-3
- Activation and Catalytic Degradation of SF6 and PhSF5 at a Bismuth Center V. Béland et al. 10.1021/jacs.4c07044
- The strength of the meridional overturning circulation of the stratosphere M. Linz et al. 10.1038/ngeo3013
- Decoupling the Effects of Transport and Chemical Loss on Tropospheric Composition: A Model Study of Path‐Dependent Lifetimes H. Yang et al. 10.1002/2017JD027871
- Impacts of meteoric sulfur in the Earth's atmosphere J. Gómez Martín et al. 10.1002/2017JD027218
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- Environment-Friendly and Efficient Gaseous Insulator as a Potential Alternative to SF6 H. Kharal et al. 10.3390/pr7100740
- Degradation of SF6 by dielectric barrier discharge cooperating with TiO2 photocatalysis: Insights into the reaction mechanism Y. Wu et al. 10.1016/j.apsusc.2024.159957
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- Extreme learning machine and genetic algorithm in quantitative analysis of sulfur hexafluoride by infrared spectroscopy H. Liu et al. 10.1364/AO.450805
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- Theoretical Study on the Mechanisms and Kinetics of Atmospheric Oxidation of Tetrafluoropropyne and Its Analogues M. Zhang et al. 10.1021/acs.jpca.3c08331
- The impact of sulfur hexafluoride (SF<sub>6</sub>) sinks on age of air climatologies and trends S. Loeffel et al. 10.5194/acp-22-1175-2022
- Measurement report: Radiative efficiencies of (CF3)2CFCN, CF3OCFCF2, and CF3OCF2CF3 B. Trisna et al. 10.5194/acp-23-4489-2023
- Evaluation of stratospheric age of air from CF<sub>4</sub>, C<sub>2</sub>F<sub>6</sub>, C<sub>3</sub>F<sub>8</sub>, CHF<sub>3</sub>, HFC-125, HFC-227ea and SF<sub>6</sub>; implications for the calculations of halocarbon lifetimes, fractional release factors and ozone depletion potentials E. Leedham Elvidge et al. 10.5194/acp-18-3369-2018
- Organic and inorganic bromine measurements around the extratropical tropopause and lowermost stratosphere: insights into the transport pathways and total bromine M. Rotermund et al. 10.5194/acp-21-15375-2021
- The increasing atmospheric burden of the greenhouse gas sulfur hexafluoride (SF<sub>6</sub>) P. Simmonds et al. 10.5194/acp-20-7271-2020
- Investigation of the Arc Characteristics in a Nozzle with C4F7N/CO2 Mixtures W. Wang et al. 10.3390/en17184593
- Experimental research and reaction process analysis of degradation of strong greenhouse gas SF 6 using 304 stainless steel J. Ma et al. 10.1080/15567036.2024.2421423
Discussed (final revised paper)
Latest update: 23 Nov 2024
Short summary
Sulfur hexafluoride (SF6) is a very potent greenhouse gas, which is present in the atmosphere only through its industrial use, for example as an electrical insulator. To estimate accurately the impact of SF6 emissions on climate we need to know how long it persists in the atmosphere before being removed. Previous estimates of the SF6 lifetime indicate a large degree of uncertainty. Here we use a detailed atmospheric model to calculate a current best estimate of the SF6 lifetime.
Sulfur hexafluoride (SF6) is a very potent greenhouse gas, which is present in the atmosphere...
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