Articles | Volume 17, issue 14
https://doi.org/10.5194/acp-17-8789-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-8789-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Atmospheric chemistry, sources and sinks of carbon suboxide, C3O2
Stephan Keßel
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
David Cabrera-Perez
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
Abraham Horowitz
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
Patrick R. Veres
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
now at: NOAA ESRL Chemical Sciences Division, Boulder, CO, USA
now at: Cooperative Institute for Research in Environmental Sciences, University of
Colorado, Boulder, CO, USA
Rolf Sander
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
Domenico Taraborrelli
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
now at: Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, Jülich, Germany
Maria Tucceri
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
John N. Crowley
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
Andrea Pozzer
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
Christof Stönner
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
Luc Vereecken
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
now at: Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, Jülich, Germany
Jos Lelieveld
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
Jonathan Williams
CORRESPONDING AUTHOR
Max Planck Institute for Chemistry, Hahn-Meitner-Weg 1, Mainz,
Germany
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Cited
7 citations as recorded by crossref.
- Study of carbon suboxide-containing clusters: A potential sink for cumulene X. Sheng et al. 10.1016/j.comptc.2018.09.005
- A novel electrochemical sensor based on thermally reduced graphene oxide for the sensitive determination of dopamine J. Gaidukevic et al. 10.1016/j.apsusc.2022.153257
- Pseudo-conformer models for linear molecules: Joint treatment of spectroscopic, electron diffraction and ab initio data for the C 3 O 2 molecule Y. Tarasov & I. Kochikov 10.1016/j.molstruc.2018.02.095
- Compilation of Henry's law constants (version 5.0.0) for water as solvent R. Sander 10.5194/acp-23-10901-2023
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
- Assessment of aldehyde contributions to PTR-MS m/z 69.07 in indoor air measurements L. Ernle et al. 10.1039/D3EA00055A
- Theoretical Study of the Temperature- and Pressure-Dependent Rate Constants for Nine Reactions between COn (n = 0–4), Om (m = 1–3), C2O, and C3O2 during the Radiolysis of Carbon Dioxide Y. Tang et al. 10.1021/acs.jpca.4c00681
7 citations as recorded by crossref.
- Study of carbon suboxide-containing clusters: A potential sink for cumulene X. Sheng et al. 10.1016/j.comptc.2018.09.005
- A novel electrochemical sensor based on thermally reduced graphene oxide for the sensitive determination of dopamine J. Gaidukevic et al. 10.1016/j.apsusc.2022.153257
- Pseudo-conformer models for linear molecules: Joint treatment of spectroscopic, electron diffraction and ab initio data for the C 3 O 2 molecule Y. Tarasov & I. Kochikov 10.1016/j.molstruc.2018.02.095
- Compilation of Henry's law constants (version 5.0.0) for water as solvent R. Sander 10.5194/acp-23-10901-2023
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
- Assessment of aldehyde contributions to PTR-MS m/z 69.07 in indoor air measurements L. Ernle et al. 10.1039/D3EA00055A
- Theoretical Study of the Temperature- and Pressure-Dependent Rate Constants for Nine Reactions between COn (n = 0–4), Om (m = 1–3), C2O, and C3O2 during the Radiolysis of Carbon Dioxide Y. Tang et al. 10.1021/acs.jpca.4c00681
Latest update: 23 Nov 2024
Short summary
In this study we identify an often overlooked stable oxide of carbon, namely carbon suboxide (C3O2), in ambient air. We have made C3O2 and in the laboratory determined its absorption cross section data and the rate of reaction with two important atmospheric oxidants, OH and O3. By incorporating known sources and sinks in a global model we have generated a first global picture of the distribution of this species in the atmosphere.
In this study we identify an often overlooked stable oxide of carbon, namely carbon suboxide...
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