Articles | Volume 17, issue 14
https://doi.org/10.5194/acp-17-8635-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-8635-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
17 Jul 2017
Research article |
| 17 Jul 2017
Nitrate radical oxidation of γ-terpinene: hydroxy nitrate, total organic nitrate, and secondary organic aerosol yields
Jonathan H. Slade
CORRESPONDING AUTHOR
Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA
Chloé de Perre
Department of Agronomy, Purdue University, West Lafayette, IN 47907, USA
Linda Lee
Department of Agronomy, Purdue University, West Lafayette, IN 47907, USA
Paul B. Shepson
Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA
Department of Earth, Atmospheric, and Planetary Sciences, Purdue
University, West Lafayette, IN 47907, USA
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Cited
16 citations as recorded by crossref.
- Relative Humidity Changes the Role of SO2 in Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1021/acs.jpclett.1c01550
- An experimental study of the reactivity of terpinolene and <i>β</i>-caryophyllene with the nitrate radical A. Fouqueau et al. 10.5194/acp-22-6411-2022
- Leaf enclosure measurements for determining volatile organic compound emission capacity from Cannabis spp. C. Wang et al. 10.1016/j.atmosenv.2018.10.049
- Secondary aerosol formation from mixtures of marine volatile organic compounds in a potential aerosol mass oxidative flow reactor A. Moore et al. 10.1039/D3EA00169E
- Chemical composition and hydrolysis of organic nitrate aerosol formed from hydroxyl and nitrate radical oxidation of <i>α</i>-pinene and <i>β</i>-pinene M. Takeuchi & N. Ng 10.5194/acp-19-12749-2019
- Secondary organic aerosol (SOA) yields from NO<sub>3</sub> radical + isoprene based on nighttime aircraft power plant plume transects J. Fry et al. 10.5194/acp-18-11663-2018
- NOx enhances secondary organic aerosol formation from nighttime γ-terpinene ozonolysis L. Xu et al. 10.1016/j.atmosenv.2020.117375
- Understanding interactions of organic nitrates with the surface and bulk of organic films: implications for particle growth in the atmosphere A. Vander Wall et al. 10.1039/C8EM00348C
- Abundance of NO3 Derived Organo-Nitrates and Their Importance in the Atmosphere A. Foulds et al. 10.3390/atmos12111381
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Potential regional air quality impacts of cannabis cultivation facilities in Denver, Colorado C. Wang et al. 10.5194/acp-19-13973-2019
- Hyperconjugation enhances electrophilic addition to monocyclic monoterpenes: a Fukui function perspective J. Amador-Balderas et al. 10.1007/s00894-018-3825-2
- The production and hydrolysis of organic nitrates from OH radical oxidation of <i>β</i>-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Evidence for a kinetically controlled burying mechanism for growth of high viscosity secondary organic aerosol A. Vander Wall et al. 10.1039/C9EM00379G
- A comparative and experimental study of the reactivity with nitrate radical of two terpenes: <i>α</i>-terpinene and <i>γ</i>-terpinene A. Fouqueau et al. 10.5194/acp-20-15167-2020
- Important Oxidants and Their Impact on the Environmental Effects of Aerosols M. Ge et al. 10.1021/acs.jpca.0c10236
16 citations as recorded by crossref.
- Relative Humidity Changes the Role of SO2 in Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1021/acs.jpclett.1c01550
- An experimental study of the reactivity of terpinolene and <i>β</i>-caryophyllene with the nitrate radical A. Fouqueau et al. 10.5194/acp-22-6411-2022
- Leaf enclosure measurements for determining volatile organic compound emission capacity from Cannabis spp. C. Wang et al. 10.1016/j.atmosenv.2018.10.049
- Secondary aerosol formation from mixtures of marine volatile organic compounds in a potential aerosol mass oxidative flow reactor A. Moore et al. 10.1039/D3EA00169E
- Chemical composition and hydrolysis of organic nitrate aerosol formed from hydroxyl and nitrate radical oxidation of <i>α</i>-pinene and <i>β</i>-pinene M. Takeuchi & N. Ng 10.5194/acp-19-12749-2019
- Secondary organic aerosol (SOA) yields from NO<sub>3</sub> radical + isoprene based on nighttime aircraft power plant plume transects J. Fry et al. 10.5194/acp-18-11663-2018
- NOx enhances secondary organic aerosol formation from nighttime γ-terpinene ozonolysis L. Xu et al. 10.1016/j.atmosenv.2020.117375
- Understanding interactions of organic nitrates with the surface and bulk of organic films: implications for particle growth in the atmosphere A. Vander Wall et al. 10.1039/C8EM00348C
- Abundance of NO3 Derived Organo-Nitrates and Their Importance in the Atmosphere A. Foulds et al. 10.3390/atmos12111381
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Potential regional air quality impacts of cannabis cultivation facilities in Denver, Colorado C. Wang et al. 10.5194/acp-19-13973-2019
- Hyperconjugation enhances electrophilic addition to monocyclic monoterpenes: a Fukui function perspective J. Amador-Balderas et al. 10.1007/s00894-018-3825-2
- The production and hydrolysis of organic nitrates from OH radical oxidation of <i>β</i>-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Evidence for a kinetically controlled burying mechanism for growth of high viscosity secondary organic aerosol A. Vander Wall et al. 10.1039/C9EM00379G
- A comparative and experimental study of the reactivity with nitrate radical of two terpenes: <i>α</i>-terpinene and <i>γ</i>-terpinene A. Fouqueau et al. 10.5194/acp-20-15167-2020
- Important Oxidants and Their Impact on the Environmental Effects of Aerosols M. Ge et al. 10.1021/acs.jpca.0c10236
Latest update: 17 Apr 2024
Short summary
This study provides new insight into the oxidation of polyolefinic monoterpenes and the dependence of the formation and yields of organic nitrates (ON) and secondary organic aerosol (SOA) on hydrocarbon structure. Here we have elucidated the ON, hydroxy nitrate, and SOA yields from the NO3 oxidation of γ-terpinene, a potentially relevant nighttime ON precursor in the Midwestern US. The results advance our understanding of the chemistry that influences NOx, O3 production, and aerosol formation.
This study provides new insight into the oxidation of polyolefinic monoterpenes and the...
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