Articles | Volume 17, issue 6
https://doi.org/10.5194/acp-17-4081-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-4081-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
27 Mar 2017
Research article |
| 27 Mar 2017
Evidence for renoxification in the tropical marine boundary layer
Wolfson Atmospheric Chemistry Laboratories (WACL), Department of
Chemistry, University of York, Heslington, York, YO10 5DD, UK
now at: Facility for Airborne Atmospheric Measurements (FAAM),
Building 146, Cranfield University, Cranfield, MK43 0AL, UK
Mathew J. Evans
Wolfson Atmospheric Chemistry Laboratories (WACL), Department of
Chemistry, University of York, Heslington, York, YO10 5DD, UK
National Centre for Atmospheric Science (NCAS), University of York,
Heslington, York, YO10 5DD, UK
Leigh R. Crilley
School of Geography, Earth and Environmental Sciences, University of
Birmingham, Edgbaston, Birmingham, B15 2TT, UK
William J. Bloss
School of Geography, Earth and Environmental Sciences, University of
Birmingham, Edgbaston, Birmingham, B15 2TT, UK
Tomás Sherwen
Wolfson Atmospheric Chemistry Laboratories (WACL), Department of
Chemistry, University of York, Heslington, York, YO10 5DD, UK
Katie A. Read
Wolfson Atmospheric Chemistry Laboratories (WACL), Department of
Chemistry, University of York, Heslington, York, YO10 5DD, UK
National Centre for Atmospheric Science (NCAS), University of York,
Heslington, York, YO10 5DD, UK
James D. Lee
Wolfson Atmospheric Chemistry Laboratories (WACL), Department of
Chemistry, University of York, Heslington, York, YO10 5DD, UK
National Centre for Atmospheric Science (NCAS), University of York,
Heslington, York, YO10 5DD, UK
Lucy J. Carpenter
Wolfson Atmospheric Chemistry Laboratories (WACL), Department of
Chemistry, University of York, Heslington, York, YO10 5DD, UK
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Cited
45 citations as recorded by crossref.
- Global Impact of Particulate Nitrate Photolysis on Fine Sulfate Aerosol L. Liu et al. 10.1021/acs.estlett.4c00416
- Production of HONO from NO<sub>2</sub> uptake on illuminated TiO<sub>2</sub> aerosol particles and following the illumination of mixed TiO<sub>2</sub>∕ammonium nitrate particles J. Dyson et al. 10.5194/acp-21-5755-2021
- Synthesizing evidence for the external cycling of NOx in high- to low-NOx atmospheres C. Ye et al. 10.1038/s41467-023-43866-z
- Nitrogen oxides in the free troposphere: implications for tropospheric oxidants and the interpretation of satellite NO2 measurements V. Shah et al. 10.5194/acp-23-1227-2023
- Global budget of tropospheric ozone: Evaluating recent model advances with satellite (OMI), aircraft (IAGOS), and ozonesonde observations L. Hu et al. 10.1016/j.atmosenv.2017.08.036
- Tropospheric HONO distribution and chemistry in the southeastern US C. Ye et al. 10.5194/acp-18-9107-2018
- Laboratory Investigation of Renoxification from the Photolysis of Inorganic Particulate Nitrate Q. Shi et al. 10.1021/acs.est.0c06049
- The positive effect of formaldehyde on the photocatalytic renoxification of nitrate on TiO2 particles Y. Liu et al. 10.5194/acp-22-11347-2022
- Nitrous acid (HONO) emissions under real-world driving conditions from vehicles in a UK road tunnel L. Kramer et al. 10.5194/acp-20-5231-2020
- Superoxide and Nitrous Acid Production from Nitrate Photolysis Is Enhanced by Dissolved Aliphatic Organic Matter X. Wang et al. 10.1021/acs.estlett.0c00806
- An investigation into the chemistry of HONO in the marine boundary layer at Tudor Hill Marine Atmospheric Observatory in Bermuda Y. Zhu et al. 10.5194/acp-22-6327-2022
- Unveiling the underestimated direct emissions of nitrous acid (HONO) Q. Zhang et al. 10.1073/pnas.2302048120
- Observational Evidence of Unknown NOx Source and Its Perturbation of Oxidative Capacity in Bermuda's Marine Boundary Layer Y. Wang et al. 10.1029/2023JD039582
- On the Importance of Surface-Enhanced Renoxification as an Oxides of Nitrogen Source in Rural and Urban New York State M. Ninneman et al. 10.1021/acsearthspacechem.0c00185
- Nitrous acid in marine boundary layer over eastern Bohai Sea, China: Characteristics, sources, and implications L. Wen et al. 10.1016/j.scitotenv.2019.03.225
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- Formation mechanisms and atmospheric implications of summertime nitrous acid (HONO) during clean, ozone pollution and double high-level PM2.5 and O3 pollution periods in Beijing H. Xuan et al. 10.1016/j.scitotenv.2022.159538
- Insights Into NOx and HONO Chemistry in the Tropical Marine Boundary Layer at Cape Verde During the MarParCloud Campaign Y. Jiang et al. 10.1029/2023JD038865
- Constraints on Aerosol Nitrate Photolysis as a Potential Source of HONO and NOx P. Romer et al. 10.1021/acs.est.8b03861
- Nitrous Acid (HONO) Formation from the Irradiation of Aqueous Nitrate Solutions in the Presence of Marine Chromophoric Dissolved Organic Matter: Comparison to Other Organic Photosensitizers S. Mora Garcia et al. 10.1021/acsearthspacechem.1c00292
- Sea spray aerosol chemical composition: elemental and molecular mimics for laboratory studies of heterogeneous and multiphase reactions T. Bertram et al. 10.1039/C7CS00008A
- Enhanced HONO Formation from Aqueous Nitrate Photochemistry in the Presence of Marine Relevant Organics: Impact of Marine-Dissolved Organic Matter (m-DOM) Concentration on HONO Yields and Potential Synergistic Effects of Compounds within m-DOM S. Mora García et al. 10.1021/acsestair.4c00006
- High resolution, extreme isotopic variability of precipitation nitrate L. Rose et al. 10.1016/j.atmosenv.2019.03.012
- Long-term NO<sub><i>x</i></sub> measurements in the remote marine tropical troposphere S. Andersen et al. 10.5194/amt-14-3071-2021
- Extensive field evidence for the release of HONO from the photolysis of nitrate aerosols S. Andersen et al. 10.1126/sciadv.add6266
- A portable, robust, stable, and tunable calibration source for gas-phase nitrous acid (HONO) M. Lao et al. 10.5194/amt-13-5873-2020
- Insights into HONO sources from observations during a solar eclipse A. Singh et al. 10.1039/D1EA00010A
- Amplified role of potential HONO sources in O<sub>3</sub> formation in North China Plain during autumn haze aggravating processes J. Zhang et al. 10.5194/acp-22-3275-2022
- Tropospheric NO2 vertical profiles over South Korea and their relation to oxidant chemistry: implications for geostationary satellite retrievals and the observation of NO2 diurnal variation from space L. Yang et al. 10.5194/acp-23-2465-2023
- Is the ocean surface a source of nitrous acid (HONO) in the marine boundary layer? L. Crilley et al. 10.5194/acp-21-18213-2021
- Simultaneous Measurement of Gaseous HONO and NO2− in Solutions from Aqueous Nitrate Photolysis Mediated by Organics Y. Zhao et al. 10.3390/atmos15111279
- Nitrous acid budgets in the coastal atmosphere: potential daytime marine sources X. Zhong et al. 10.5194/acp-23-14761-2023
- HONO, Particulate Nitrite, and Snow Nitrite at a Midlatitude Urban Site during Wintertime Q. Chen et al. 10.1021/acsearthspacechem.9b00023
- Factors Influencing the Formation of Nitrous Acid from Photolysis of Particulate Nitrate R. Sommariva et al. 10.1021/acs.jpca.3c03853
- Global impact of nitrate photolysis in sea-salt aerosol on NO<sub><i>x</i></sub>, OH, and O<sub>3</sub> in the marine boundary layer P. Kasibhatla et al. 10.5194/acp-18-11185-2018
- On the discrepancy of HCl processing in the core of the wintertime polar vortices J. Grooß et al. 10.5194/acp-18-8647-2018
- Dominant Processes of HONO Derived from Multiple Field Observations in Contrasting Environments Y. Jiang et al. 10.1021/acs.estlett.2c00004
- A seasonal analysis of aerosol NO3− sources and NOx oxidation pathways in the Southern Ocean marine boundary layer J. Burger et al. 10.5194/acp-23-5605-2023
- Origins of atmospheric nitrous acid and their contributions to OH radical from ship plumes, marine atmosphere, and continental air masses over South China Sea X. Ni et al. 10.1016/j.scitotenv.2024.175841
- Background nitrogen dioxide (NO2) over the United States and its implications for satellite observations and trends: effects of nitrate photolysis, aircraft, and open fires R. Dang et al. 10.5194/acp-23-6271-2023
- Impact of particulate nitrate photolysis on air quality over the Northern Hemisphere G. Sarwar et al. 10.1016/j.scitotenv.2024.170406
- Particulate nitrate photolysis in the atmosphere M. Gen et al. 10.1039/D1EA00087J
- Fundamental oxidation processes in the remote marine atmosphere investigated using the NO–NO2–O3 photostationary state S. Andersen et al. 10.5194/acp-22-15747-2022
- Changes in tropospheric air quality related to the protection of stratospheric ozone in a changing climate S. Madronich et al. 10.1007/s43630-023-00369-6
- Observation-Based Diagnostics of Reactive Nitrogen Recycling through HONO Heterogenous Production: Divergent Implications for Ozone Production and Emission Control K. Chong et al. 10.1021/acs.est.3c07967
45 citations as recorded by crossref.
- Global Impact of Particulate Nitrate Photolysis on Fine Sulfate Aerosol L. Liu et al. 10.1021/acs.estlett.4c00416
- Production of HONO from NO<sub>2</sub> uptake on illuminated TiO<sub>2</sub> aerosol particles and following the illumination of mixed TiO<sub>2</sub>∕ammonium nitrate particles J. Dyson et al. 10.5194/acp-21-5755-2021
- Synthesizing evidence for the external cycling of NOx in high- to low-NOx atmospheres C. Ye et al. 10.1038/s41467-023-43866-z
- Nitrogen oxides in the free troposphere: implications for tropospheric oxidants and the interpretation of satellite NO2 measurements V. Shah et al. 10.5194/acp-23-1227-2023
- Global budget of tropospheric ozone: Evaluating recent model advances with satellite (OMI), aircraft (IAGOS), and ozonesonde observations L. Hu et al. 10.1016/j.atmosenv.2017.08.036
- Tropospheric HONO distribution and chemistry in the southeastern US C. Ye et al. 10.5194/acp-18-9107-2018
- Laboratory Investigation of Renoxification from the Photolysis of Inorganic Particulate Nitrate Q. Shi et al. 10.1021/acs.est.0c06049
- The positive effect of formaldehyde on the photocatalytic renoxification of nitrate on TiO2 particles Y. Liu et al. 10.5194/acp-22-11347-2022
- Nitrous acid (HONO) emissions under real-world driving conditions from vehicles in a UK road tunnel L. Kramer et al. 10.5194/acp-20-5231-2020
- Superoxide and Nitrous Acid Production from Nitrate Photolysis Is Enhanced by Dissolved Aliphatic Organic Matter X. Wang et al. 10.1021/acs.estlett.0c00806
- An investigation into the chemistry of HONO in the marine boundary layer at Tudor Hill Marine Atmospheric Observatory in Bermuda Y. Zhu et al. 10.5194/acp-22-6327-2022
- Unveiling the underestimated direct emissions of nitrous acid (HONO) Q. Zhang et al. 10.1073/pnas.2302048120
- Observational Evidence of Unknown NOx Source and Its Perturbation of Oxidative Capacity in Bermuda's Marine Boundary Layer Y. Wang et al. 10.1029/2023JD039582
- On the Importance of Surface-Enhanced Renoxification as an Oxides of Nitrogen Source in Rural and Urban New York State M. Ninneman et al. 10.1021/acsearthspacechem.0c00185
- Nitrous acid in marine boundary layer over eastern Bohai Sea, China: Characteristics, sources, and implications L. Wen et al. 10.1016/j.scitotenv.2019.03.225
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- Formation mechanisms and atmospheric implications of summertime nitrous acid (HONO) during clean, ozone pollution and double high-level PM2.5 and O3 pollution periods in Beijing H. Xuan et al. 10.1016/j.scitotenv.2022.159538
- Insights Into NOx and HONO Chemistry in the Tropical Marine Boundary Layer at Cape Verde During the MarParCloud Campaign Y. Jiang et al. 10.1029/2023JD038865
- Constraints on Aerosol Nitrate Photolysis as a Potential Source of HONO and NOx P. Romer et al. 10.1021/acs.est.8b03861
- Nitrous Acid (HONO) Formation from the Irradiation of Aqueous Nitrate Solutions in the Presence of Marine Chromophoric Dissolved Organic Matter: Comparison to Other Organic Photosensitizers S. Mora Garcia et al. 10.1021/acsearthspacechem.1c00292
- Sea spray aerosol chemical composition: elemental and molecular mimics for laboratory studies of heterogeneous and multiphase reactions T. Bertram et al. 10.1039/C7CS00008A
- Enhanced HONO Formation from Aqueous Nitrate Photochemistry in the Presence of Marine Relevant Organics: Impact of Marine-Dissolved Organic Matter (m-DOM) Concentration on HONO Yields and Potential Synergistic Effects of Compounds within m-DOM S. Mora García et al. 10.1021/acsestair.4c00006
- High resolution, extreme isotopic variability of precipitation nitrate L. Rose et al. 10.1016/j.atmosenv.2019.03.012
- Long-term NO<sub><i>x</i></sub> measurements in the remote marine tropical troposphere S. Andersen et al. 10.5194/amt-14-3071-2021
- Extensive field evidence for the release of HONO from the photolysis of nitrate aerosols S. Andersen et al. 10.1126/sciadv.add6266
- A portable, robust, stable, and tunable calibration source for gas-phase nitrous acid (HONO) M. Lao et al. 10.5194/amt-13-5873-2020
- Insights into HONO sources from observations during a solar eclipse A. Singh et al. 10.1039/D1EA00010A
- Amplified role of potential HONO sources in O<sub>3</sub> formation in North China Plain during autumn haze aggravating processes J. Zhang et al. 10.5194/acp-22-3275-2022
- Tropospheric NO2 vertical profiles over South Korea and their relation to oxidant chemistry: implications for geostationary satellite retrievals and the observation of NO2 diurnal variation from space L. Yang et al. 10.5194/acp-23-2465-2023
- Is the ocean surface a source of nitrous acid (HONO) in the marine boundary layer? L. Crilley et al. 10.5194/acp-21-18213-2021
- Simultaneous Measurement of Gaseous HONO and NO2− in Solutions from Aqueous Nitrate Photolysis Mediated by Organics Y. Zhao et al. 10.3390/atmos15111279
- Nitrous acid budgets in the coastal atmosphere: potential daytime marine sources X. Zhong et al. 10.5194/acp-23-14761-2023
- HONO, Particulate Nitrite, and Snow Nitrite at a Midlatitude Urban Site during Wintertime Q. Chen et al. 10.1021/acsearthspacechem.9b00023
- Factors Influencing the Formation of Nitrous Acid from Photolysis of Particulate Nitrate R. Sommariva et al. 10.1021/acs.jpca.3c03853
- Global impact of nitrate photolysis in sea-salt aerosol on NO<sub><i>x</i></sub>, OH, and O<sub>3</sub> in the marine boundary layer P. Kasibhatla et al. 10.5194/acp-18-11185-2018
- On the discrepancy of HCl processing in the core of the wintertime polar vortices J. Grooß et al. 10.5194/acp-18-8647-2018
- Dominant Processes of HONO Derived from Multiple Field Observations in Contrasting Environments Y. Jiang et al. 10.1021/acs.estlett.2c00004
- A seasonal analysis of aerosol NO3− sources and NOx oxidation pathways in the Southern Ocean marine boundary layer J. Burger et al. 10.5194/acp-23-5605-2023
- Origins of atmospheric nitrous acid and their contributions to OH radical from ship plumes, marine atmosphere, and continental air masses over South China Sea X. Ni et al. 10.1016/j.scitotenv.2024.175841
- Background nitrogen dioxide (NO2) over the United States and its implications for satellite observations and trends: effects of nitrate photolysis, aircraft, and open fires R. Dang et al. 10.5194/acp-23-6271-2023
- Impact of particulate nitrate photolysis on air quality over the Northern Hemisphere G. Sarwar et al. 10.1016/j.scitotenv.2024.170406
- Particulate nitrate photolysis in the atmosphere M. Gen et al. 10.1039/D1EA00087J
- Fundamental oxidation processes in the remote marine atmosphere investigated using the NO–NO2–O3 photostationary state S. Andersen et al. 10.5194/acp-22-15747-2022
- Changes in tropospheric air quality related to the protection of stratospheric ozone in a changing climate S. Madronich et al. 10.1007/s43630-023-00369-6
- Observation-Based Diagnostics of Reactive Nitrogen Recycling through HONO Heterogenous Production: Divergent Implications for Ozone Production and Emission Control K. Chong et al. 10.1021/acs.est.3c07967
Latest update: 20 Nov 2024
Short summary
The source of ozone-depleting compounds in the remote troposphere has been thought to be long-range transport of secondary pollutants such as organic nitrates. Processing of organic nitrates to nitric acid and subsequent deposition on surfaces in the atmosphere was thought to remove these nitrates from the ozone–NOx–HOx cycle. We found through observation of NOx in the remote tropical troposphere at the Cape Verde Observatory that surface nitrates can be released back into the atmosphere.
The source of ozone-depleting compounds in the remote troposphere has been thought to be...
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