Articles | Volume 17, issue 5
https://doi.org/10.5194/acp-17-3713-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-3713-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Seasonal variations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica
Department of Chemical Science and Engineering, School of Materials
and Chemical Technology, Tokyo Institute of Technology, G1-17, 4259 Nagatsuta-cho,
Midori-ku, Yokohama 226-8502, Japan
Shohei Hattori
Department of Chemical Science and Engineering, School of Materials
and Chemical Technology, Tokyo Institute of Technology, G1-17, 4259 Nagatsuta-cho,
Midori-ku, Yokohama 226-8502, Japan
Joel Savarino
IGE, Univ. Grenoble Alpes, CNRS, IRD, INP-G, 38000 Grenoble, France
Bruno Jourdain
IGE, Univ. Grenoble Alpes, CNRS, IRD, INP-G, 38000 Grenoble, France
Susanne Preunkert
IGE, Univ. Grenoble Alpes, CNRS, IRD, INP-G, 38000 Grenoble, France
Michel Legrand
IGE, Univ. Grenoble Alpes, CNRS, IRD, INP-G, 38000 Grenoble, France
Nicolas Caillon
IGE, Univ. Grenoble Alpes, CNRS, IRD, INP-G, 38000 Grenoble, France
Albane Barbero
IGE, Univ. Grenoble Alpes, CNRS, IRD, INP-G, 38000 Grenoble, France
Kota Kuribayashi
Department of Environmental Chemistry and Engineering, Tokyo Institute
of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8502, Japan
Naohiro Yoshida
Department of Chemical Science and Engineering, School of Materials
and Chemical Technology, Tokyo Institute of Technology, G1-17, 4259 Nagatsuta-cho,
Midori-ku, Yokohama 226-8502, Japan
Earth-Life Science Institute, Tokyo Institute of Technology,
Meguro-ku, Tokyo 152-8551, Japan
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- Isotopic constraints on heterogeneous sulfate production in Beijing haze P. He et al. 10.5194/acp-18-5515-2018
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- A Complete Isotope (δ15N, δ18O, Δ17O) Investigation of Atmospherically Deposited Nitrate in Glacial‐Hydrologic Systems Across the Third Pole Region M. Lin et al. 10.1029/2019JD031878
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31 citations as recorded by crossref.
- Assessing the Seasonal Dynamics of Nitrate and Sulfate Aerosols at the South Pole Utilizing Stable Isotopes W. Walters et al. 10.1029/2019JD030517
- Atmospheric Δ<sup>17</sup>O(NO<sub>3</sub><sup>−</sup>) reveals nocturnal chemistry dominates nitrate production in Beijing haze P. He et al. 10.5194/acp-18-14465-2018
- Isotopic constraints on the formation pathways and sources of atmospheric nitrate in the Mt. Everest region K. Wang et al. 10.1016/j.envpol.2020.115274
- Isotopic Constraints on the Formation Mechanisms of Sulfate Aerosols in the Summer Arctic Marine Boundary Layer P. He et al. 10.1029/2022JD036601
- Formation Mechanisms and Source Apportionments of Nitrate Aerosols in a Megacity of Eastern China Based On Multiple Isotope Observations M. Fan et al. 10.1029/2022JD038129
- Oxidation pathways and emission sources of atmospheric particulate nitrate in Seoul: based on <i>δ</i><sup>15</sup>N and Δ<sup>17</sup>O measurements S. Lim et al. 10.5194/acp-22-5099-2022
- Preparation and characterization of new sulfate reference materials for Δ17O analysis G. Su et al. 10.1039/D2JA00022A
- A diurnal story of Δ17O($$\rm{NO}_{3}^{-}$$) in urban Nanjing and its implication for nitrate aerosol formation Y. Zhang et al. 10.1038/s41612-022-00273-3
- Regional Characteristics of Atmospheric Sulfate Formation in East Antarctica Imprinted on 17O‐Excess Signature S. Ishino et al. 10.1029/2020JD033583
- Changes in nitrate accumulation mechanisms as PM2.5 levels increase on the North China Plain: A perspective from the dual isotopic compositions of nitrate L. Luo et al. 10.1016/j.chemosphere.2020.127915
- Application of Stable Isotope Techniques in Tracing the Sources of Atmospheric NOX and Nitrate S. Zhen et al. 10.3390/pr10122549
- Heterogeneous sulfate aerosol formation mechanisms during wintertime Chinese haze events: air quality model assessment using observations of sulfate oxygen isotopes in Beijing J. Shao et al. 10.5194/acp-19-6107-2019
- Photolytic modification of seasonal nitrate isotope cycles in East Antarctica P. Akers et al. 10.5194/acp-22-15637-2022
- Multiyear Measurements on Δ17O of Stream Nitrate Indicate High Nitrate Production in a Temperate Forest S. Huang et al. 10.1021/acs.est.9b07839
- Homogeneous sulfur isotope signature in East Antarctica and implication for sulfur source shifts through the last glacial-interglacial cycle S. Ishino et al. 10.1038/s41598-019-48801-1
- A seasonal analysis of aerosol NO3− sources and NOx oxidation pathways in the Southern Ocean marine boundary layer J. Burger et al. 10.5194/acp-23-5605-2023
- Spatial variation of isotopic compositions of snowpack nitrate related to post-depositional processes in eastern Dronning Maud Land, East Antarctica K. Noro et al. 10.2343/geochemj.2.0519
- Tracing the sources and formation pathways of atmospheric particulate nitrate over the Pacific Ocean using stable isotopes K. Kamezaki et al. 10.1016/j.atmosenv.2019.04.026
- The importance of alkyl nitrates and sea ice emissions to atmospheric NO<sub><i>x</i></sub> sources and cycling in the summertime Southern Ocean marine boundary layer J. Burger et al. 10.5194/acp-22-1081-2022
- The observation of isotopic compositions of atmospheric nitrate in Shanghai China and its implication for reactive nitrogen chemistry P. He et al. 10.1016/j.scitotenv.2020.136727
- Isotopic evidence for acidity-driven enhancement of sulfate formation after SO 2 emission control S. Hattori et al. 10.1126/sciadv.abd4610
- 2600-years of stratospheric volcanism through sulfate isotopes E. Gautier et al. 10.1038/s41467-019-08357-0
- Isotopic constraints on atmospheric sulfate formation pathways in the Mt. Everest region, southern Tibetan Plateau K. Wang et al. 10.5194/acp-21-8357-2021
- Using stable isotopes to distinguish atmospheric nitrate production and its contribution to the surface ocean across hemispheres G. Shi et al. 10.1016/j.epsl.2021.116914
- Vertically uniform formation pathways of tropospheric sulfate aerosols in East China detected from triple stable oxygen and radiogenic sulfur isotopes M. Lin et al. 10.1002/2017GL073637
- Isotopic constraints on heterogeneous sulfate production in Beijing haze P. He et al. 10.5194/acp-18-5515-2018
- Stratospheric Gas‐Phase Production Alone Cannot Explain Observations of Atmospheric Perchlorate on Earth Y. Chan et al. 10.1029/2023GL102745
- A 60 Year Record of Atmospheric Aerosol Depositions Preserved in a High‐Accumulation Dome Ice Core, Southeast Greenland Y. Iizuka et al. 10.1002/2017JD026733
- A Complete Isotope (δ15N, δ18O, Δ17O) Investigation of Atmospherically Deposited Nitrate in Glacial‐Hydrologic Systems Across the Third Pole Region M. Lin et al. 10.1029/2019JD031878
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- The mass-independent oxygen isotopic composition in sulfate aerosol-a useful tool to identify sulfate formation: a review Y. Zhao et al. 10.1016/j.atmosres.2020.105447
Discussed (final revised paper)
Discussed (preprint)
Latest update: 29 Sep 2023
Short summary
We show the first simultaneous observations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica. The contrasting seasonal trends between oxygen isotopes of ozone and those of sulfate and nitrate indicate that these signatures in sulfate and nitrate are mainly controlled by changes in oxidation chemistry. We also discuss the specific oxidation chemistry induced by the unique phenomena at the site.
We show the first simultaneous observations of triple oxygen isotopic compositions of...
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