Articles | Volume 17, issue 5
https://doi.org/10.5194/acp-17-3453-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-3453-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Formation of highly oxygenated low-volatility products from cresol oxidation
Rebecca H. Schwantes
CORRESPONDING AUTHOR
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: National Center for Atmospheric Research, Boulder, Colorado, USA
Katherine A. Schilling
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: Chemistry and Firearms Branch, US Army Criminal Investigation Laboratory, Forest Park, Georgia, USA
Renee C. McVay
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: Cooperative Institute for Research in Environmental Science and National Oceanic and Atmospheric Administration, Boulder, Colorado, USA
Hanna Lignell
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: South Coast Air Quality Management District, Diamond Bar, California, USA
Matthew M. Coggon
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: Cooperative Institute for Research in Environmental Science and National Oceanic and Atmospheric Administration, Boulder, Colorado, USA
Xuan Zhang
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: National Center for Atmospheric Research, Boulder, Colorado, USA
Paul O. Wennberg
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, USA
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, California 91125, USA
John H. Seinfeld
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, California 91125, USA
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- Increasing role of phenolic oxidative branch in daytime oxidation process of aromatics in Chinese haze period F. Wang et al. 10.1016/j.scitotenv.2022.159578
- Low-volatility compounds contribute significantly to isoprene secondary organic aerosol (SOA) under high-NO<sub><i>x</i></sub> conditions R. Schwantes et al. 10.5194/acp-19-7255-2019
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- Unveiling the pH-Dependent Yields of H2O2 and OH by Aqueous-Phase Ozonolysis of m-Cresol in the Atmosphere H. Pang et al. 10.1021/acs.est.1c08962
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- Investigating the Atmospheric Fate and Kinetics of OH Radical-Initiated Oxidation Reactions for Epoxybutane Isomers: Theoretical Insight S. Daimari et al. 10.1021/acs.jpca.4c00379
- Constraining the response factors of an extractive electrospray ionization mass spectrometer for near-molecular aerosol speciation D. Wang et al. 10.5194/amt-14-6955-2021
- Anthropogenic Volatile Organic Compound (AVOC) Autoxidation as a Source of Highly Oxygenated Organic Molecules (HOM) M. Rissanen 10.1021/acs.jpca.1c06465
- Combined Smog Chamber/Oxidation Flow Reactor Study on Aging of Secondary Organic Aerosol from Photooxidation of Aromatic Hydrocarbons T. Chen et al. 10.1021/acs.est.3c04089
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons M. Song et al. 10.6023/A21050224
- Secondary organic aerosol formation from monocyclic aromatic hydrocarbons: insights from laboratory studies Z. Yang et al. 10.1039/D1EM00409C
- Chemical composition of secondary organic aerosol particles formed from mixtures of anthropogenic and biogenic precursors Y. Shao et al. 10.5194/acp-22-9799-2022
- Gas–particle partitioning of toluene oxidation products: an experimental and modeling study V. Lannuque et al. 10.5194/acp-23-15537-2023
- Insight into the composition of organic compounds ( ≥ C6) in PM2.5 in wintertime in Beijing, China R. Lyu et al. 10.5194/acp-19-10865-2019
- Molecular Composition of Anthropogenic Oxygenated Organic Molecules and Their Contribution to Organic Aerosol in a Coastal City C. Yang et al. 10.1021/acs.est.3c03244
- Effective regulation of surface bridging hydroxyls on TiO2 for superior photocatalytic activity via ozone treatment B. Liu et al. 10.1016/j.apcatb.2021.120952
- Phenolic and Acidic Compounds in Radiation Fog at Strasbourg Metropolitan D. Khoury et al. 10.3390/atmos15101240
- Oxygenated organic molecules produced by low-NOx photooxidation of aromatic compounds: contributions to secondary organic aerosol and steric hindrance X. Cheng et al. 10.5194/acp-24-2099-2024
- Secondary organic aerosol production from local emissions dominates the organic aerosol budget over Seoul, South Korea, during KORUS-AQ B. Nault et al. 10.5194/acp-18-17769-2018
- Assessing the Uncertainties in Ozone and SOA Predictions due to Different Branching Ratios of the Cresol Pathway in the Toluene-OH Oxidation Mechanism J. Zhang et al. 10.1021/acsearthspacechem.1c00092
- Total OH reactivity measurements for the OH-initiated oxidation of aromatic hydrocarbons in the presence of NOx K. Sato et al. 10.1016/j.atmosenv.2017.10.036
- Investigations into the gas-phase photolysis and OH radical kinetics of nitrocatechols: implications of intramolecular interactions on their atmospheric behaviour C. Roman et al. 10.5194/acp-22-2203-2022
- Secondary Organic Aerosol Formation from the Photooxidation of Aromatic Ketone Intermediate Volatile Organic Compounds C. Liang et al. 10.1021/acs.est.4c05384
- Aqueous-Phase Photooxidation of Vanillin in the Presence of Nitrite: Characteristics, Products, and Mechanism M. Cai et al. 10.1021/acsestair.4c00013
- Experimental and theoretical study of the reactivity of a series of epoxides with chlorine atoms at 298 K C. Tovar et al. 10.1039/D0CP06033J
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- Gas-phase IR cross-sections and single crystal structures data for atmospheric relevant nitrocatechols C. Roman et al. 10.1016/j.saa.2021.120379
- Gas-phase composition and secondary organic aerosol formation from standard and particle filter-retrofitted gasoline direct injection vehicles investigated in a batch and flow reactor S. Pieber et al. 10.5194/acp-18-9929-2018
- Precursors and formation of secondary organic aerosols from wildfires in the Euro-Mediterranean region M. Majdi et al. 10.5194/acp-19-5543-2019
- Measurement report: Important contributions of oxygenated compounds to emissions and chemistry of volatile organic compounds in urban air C. Wu et al. 10.5194/acp-20-14769-2020
- The origin of potential precursors of secondary organic aerosols during combustion of biochar and softwood in residential heating J. Růžičková et al. 10.1016/j.psep.2022.03.036
- Formation of secondary organic aerosol from nitrate radical oxidation of phenolic VOCs: Implications for nitration mechanisms and brown carbon formation R. Mayorga et al. 10.1016/j.atmosenv.2020.117910
- Particle-Bound Highly Oxidized Organic Molecules Derived from Aromatic Hydrocarbons in an Urban Atmosphere M. Zhu et al. 10.1021/acs.estlett.2c00841
- Photo-oxidation of Aromatic Hydrocarbons Produces Low-Volatility Organic Compounds M. Wang et al. 10.1021/acs.est.0c02100
- Different chlorine and hydroxyl radical environments impact m-xylene oxidation products N. Bhattacharyya et al. 10.1039/D3EA00024A
- Measurement report: Online measurement of gas-phase nitrated phenols utilizing a CI-LToF-MS: primary sources and secondary formation K. Song et al. 10.5194/acp-21-7917-2021
- Linking gas, particulate, and toxic endpoints to air emissions in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) H. Pye et al. 10.5194/acp-23-5043-2023
- Empirical Approach to Quantifying Sensitivity in Different Chemical Ionization Techniques for Organonitrates and Nitroaromatics Constrained by Ion–Molecule Reaction and Transmission Efficiency S. He et al. 10.1021/acs.analchem.4c03751
- Elucidating key factors in regulating budgets of ozone and its precursors in atmospheric boundary layer X. Song et al. 10.1038/s41612-024-00818-8
Latest update: 23 Nov 2024
Short summary
Toluene, one of the principle aromatic compounds present in the atmosphere, is oxidized by OH to produce cresol and other products. Here later-generation low-volatility oxygenated products from cresol oxidation by OH are detected in the gas and particle phases. This work identifies a simple and significant mechanism for toluene secondary organic aerosol formation through the cresol pathway. Likely the phenolic pathway of other aromatic compounds is also important for secondary organic aerosol.
Toluene, one of the principle aromatic compounds present in the atmosphere, is oxidized by OH to...
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