Articles | Volume 17, issue 5
https://doi.org/10.5194/acp-17-3453-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-3453-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Formation of highly oxygenated low-volatility products from cresol oxidation
Rebecca H. Schwantes
CORRESPONDING AUTHOR
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: National Center for Atmospheric Research, Boulder, Colorado, USA
Katherine A. Schilling
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: Chemistry and Firearms Branch, US Army Criminal Investigation Laboratory, Forest Park, Georgia, USA
Renee C. McVay
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: Cooperative Institute for Research in Environmental Science and National Oceanic and Atmospheric Administration, Boulder, Colorado, USA
Hanna Lignell
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: South Coast Air Quality Management District, Diamond Bar, California, USA
Matthew M. Coggon
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: Cooperative Institute for Research in Environmental Science and National Oceanic and Atmospheric Administration, Boulder, Colorado, USA
Xuan Zhang
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, USA
Current Affiliation: National Center for Atmospheric Research, Boulder, Colorado, USA
Paul O. Wennberg
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, USA
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, California 91125, USA
John H. Seinfeld
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, California 91125, USA
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- Constraining the response factors of an extractive electrospray ionization mass spectrometer for near-molecular aerosol speciation D. Wang et al. 10.5194/amt-14-6955-2021
- Anthropogenic Volatile Organic Compound (AVOC) Autoxidation as a Source of Highly Oxygenated Organic Molecules (HOM) M. Rissanen 10.1021/acs.jpca.1c06465
- Combined Smog Chamber/Oxidation Flow Reactor Study on Aging of Secondary Organic Aerosol from Photooxidation of Aromatic Hydrocarbons T. Chen et al. 10.1021/acs.est.3c04089
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons M. Song et al. 10.6023/A21050224
- Secondary organic aerosol formation from monocyclic aromatic hydrocarbons: insights from laboratory studies Z. Yang et al. 10.1039/D1EM00409C
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Latest update: 16 Aug 2024
Short summary
Toluene, one of the principle aromatic compounds present in the atmosphere, is oxidized by OH to produce cresol and other products. Here later-generation low-volatility oxygenated products from cresol oxidation by OH are detected in the gas and particle phases. This work identifies a simple and significant mechanism for toluene secondary organic aerosol formation through the cresol pathway. Likely the phenolic pathway of other aromatic compounds is also important for secondary organic aerosol.
Toluene, one of the principle aromatic compounds present in the atmosphere, is oxidized by OH to...
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