Research article
10 Mar 2017
Research article
| 10 Mar 2017
Formation of highly oxygenated low-volatility products from cresol oxidation
Rebecca H. Schwantes et al.
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Cited
54 citations as recorded by crossref.
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- Multigeneration Production of Secondary Organic Aerosol from Toluene Photooxidation Y. Li et al. 10.1021/acs.est.1c02026
- Mechanistic study of the formation of ring-retaining and ring-opening products from the oxidation of aromatic compounds under urban atmospheric conditions A. Zaytsev et al. 10.5194/acp-19-15117-2019
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- The roles of volatile organic compound deposition and oxidation mechanisms in determining secondary organic aerosol production: a global perspective using the UKCA chemistry–climate model (vn8.4) J. Kelly et al. 10.5194/gmd-12-2539-2019
- Atmospheric Processing of Nitrophenols and Nitrocresols From Biomass Burning Emissions H. Wang et al. 10.1029/2020JD033401
- Formation of highly oxygenated organic molecules from aromatic compounds U. Molteni et al. 10.5194/acp-18-1909-2018
- Development and evaluation of a new compact mechanism for aromatic oxidation in atmospheric models K. Bates et al. 10.5194/acp-21-18351-2021
- Reassessing the atmospheric oxidation mechanism of toluene Y. Ji et al. 10.1073/pnas.1705463114
- Multi-generation OH oxidation as a source for highly oxygenated organic molecules from aromatics O. Garmash et al. 10.5194/acp-20-515-2020
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Unified Theory of Vapor–Wall Mass Transport in Teflon-Walled Environmental Chambers Y. Huang et al. 10.1021/acs.est.7b05575
- Modeling of the chemistry in oxidation flow reactors with high initial NO Z. Peng & J. Jimenez 10.5194/acp-17-11991-2017
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- Secondary organic aerosol formation from smoldering and flaming combustion of biomass: a box model parametrization based on volatility basis set G. Stefenelli et al. 10.5194/acp-19-11461-2019
- Differences of the oxidation process and secondary organic aerosol formation at low and high precursor concentrations T. Chen et al. 10.1016/j.jes.2018.11.011
- Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NO<sub><i>x</i></sub> conditions X. Cheng et al. 10.5194/acp-21-12005-2021
- Organic aerosol source apportionment in Zurich using an extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF-MS) – Part 2: Biomass burning influences in winter L. Qi et al. 10.5194/acp-19-8037-2019
- Radical chemistry in oxidation flow reactors for atmospheric chemistry research Z. Peng & J. Jimenez 10.1039/C9CS00766K
- Variability and Time of Day Dependence of Ozone Photochemistry in Western Wildfire Plumes M. Robinson et al. 10.1021/acs.est.1c01963
- Evaluation of the chemical composition of gas- and particle-phase products of aromatic oxidation A. Mehra et al. 10.5194/acp-20-9783-2020
- New Insights into the Radical Chemistry and Product Distribution in the OH-Initiated Oxidation of Benzene L. Xu et al. 10.1021/acs.est.0c04780
- Spatiotemporal variation, sources, and secondary transformation potential of volatile organic compounds in Xi'an, China M. Song et al. 10.5194/acp-21-4939-2021
- Evolution of OH reactivity in NO-free volatile organic compound photooxidation investigated by the fully explicit GECKO-A model Z. Peng et al. 10.5194/acp-21-14649-2021
- A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates W. Fan et al. 10.1016/j.jhazmat.2022.128406
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- Molecular characterization of alkyl nitrates in atmospheric aerosols by ion mobility mass spectrometry X. Zhang et al. 10.5194/amt-12-5535-2019
- Mitigation of Secondary Organic Aerosol Formation from Log Wood Burning Emissions by Catalytic Removal of Aromatic Hydrocarbons S. Pieber et al. 10.1021/acs.est.8b04124
- A steady-state continuous flow chamber for the study of daytime and nighttime chemistry under atmospherically relevant NO levels X. Zhang et al. 10.5194/amt-11-2537-2018
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- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons M. Song et al. 10.6023/A21050224
- Secondary organic aerosol formation from monocyclic aromatic hydrocarbons: insights from laboratory studies Z. Yang et al. 10.1039/D1EM00409C
- Insight into the composition of organic compounds ( ≥ C<sub>6</sub>) in PM<sub>2.5</sub> in wintertime in Beijing, China R. Lyu et al. 10.5194/acp-19-10865-2019
- Effective regulation of surface bridging hydroxyls on TiO2 for superior photocatalytic activity via ozone treatment B. Liu et al. 10.1016/j.apcatb.2021.120952
- Secondary organic aerosol production from local emissions dominates the organic aerosol budget over Seoul, South Korea, during KORUS-AQ B. Nault et al. 10.5194/acp-18-17769-2018
- Assessing the Uncertainties in Ozone and SOA Predictions due to Different Branching Ratios of the Cresol Pathway in the Toluene-OH Oxidation Mechanism J. Zhang et al. 10.1021/acsearthspacechem.1c00092
- Total OH reactivity measurements for the OH-initiated oxidation of aromatic hydrocarbons in the presence of NOx K. Sato et al. 10.1016/j.atmosenv.2017.10.036
- Investigations into the gas-phase photolysis and OH radical kinetics of nitrocatechols: implications of intramolecular interactions on their atmospheric behaviour C. Roman et al. 10.5194/acp-22-2203-2022
- Experimental and theoretical study of the reactivity of a series of epoxides with chlorine atoms at 298 K C. Tovar et al. 10.1039/D0CP06033J
- Gas-phase IR cross-sections and single crystal structures data for atmospheric relevant nitrocatechols C. Roman et al. 10.1016/j.saa.2021.120379
- Gas-phase composition and secondary organic aerosol formation from standard and particle filter-retrofitted gasoline direct injection vehicles investigated in a batch and flow reactor S. Pieber et al. 10.5194/acp-18-9929-2018
- Precursors and formation of secondary organic aerosols from wildfires in the Euro-Mediterranean region M. Majdi et al. 10.5194/acp-19-5543-2019
- Measurement report: Important contributions of oxygenated compounds to emissions and chemistry of volatile organic compounds in urban air C. Wu et al. 10.5194/acp-20-14769-2020
- The origin of potential precursors of secondary organic aerosols during combustion of biochar and softwood in residential heating J. Růžičková et al. 10.1016/j.psep.2022.03.036
- Formation of secondary organic aerosol from nitrate radical oxidation of phenolic VOCs: Implications for nitration mechanisms and brown carbon formation R. Mayorga et al. 10.1016/j.atmosenv.2020.117910
- Photo-oxidation of Aromatic Hydrocarbons Produces Low-Volatility Organic Compounds M. Wang et al. 10.1021/acs.est.0c02100
- Estimation of Secondary Organic Aerosol Formation During a Photochemical Smog Episode in Shanghai, China H. Wang et al. 10.1029/2019JD032033
- Measurement report: Online measurement of gas-phase nitrated phenols utilizing a CI-LToF-MS: primary sources and secondary formation K. Song et al. 10.5194/acp-21-7917-2021
54 citations as recorded by crossref.
- Explosive Secondary Aerosol Formation during Severe Haze in the North China Plain J. Peng et al. 10.1021/acs.est.0c07204
- Nighttime and daytime dark oxidation chemistry in wildfire plumes: an observation and model analysis of FIREX-AQ aircraft data Z. Decker et al. 10.5194/acp-21-16293-2021
- Multigeneration Production of Secondary Organic Aerosol from Toluene Photooxidation Y. Li et al. 10.1021/acs.est.1c02026
- Mechanistic study of the formation of ring-retaining and ring-opening products from the oxidation of aromatic compounds under urban atmospheric conditions A. Zaytsev et al. 10.5194/acp-19-15117-2019
- Nitrite-Mediated Photooxidation of Vanillin in the Atmospheric Aqueous Phase H. Pang et al. 10.1021/acs.est.9b03649
- Gasoline aromatics: a critical determinant of urban secondary organic aerosol formation J. Peng et al. 10.5194/acp-17-10743-2017
- Secondary organic aerosol yields from the oxidation of benzyl alcohol S. Charan et al. 10.5194/acp-20-13167-2020
- Model Evaluation of New Techniques for Maintaining High-NO Conditions in Oxidation Flow Reactors for the Study of OH-Initiated Atmospheric Chemistry Z. Peng et al. 10.1021/acsearthspacechem.7b00070
- The roles of volatile organic compound deposition and oxidation mechanisms in determining secondary organic aerosol production: a global perspective using the UKCA chemistry–climate model (vn8.4) J. Kelly et al. 10.5194/gmd-12-2539-2019
- Atmospheric Processing of Nitrophenols and Nitrocresols From Biomass Burning Emissions H. Wang et al. 10.1029/2020JD033401
- Formation of highly oxygenated organic molecules from aromatic compounds U. Molteni et al. 10.5194/acp-18-1909-2018
- Development and evaluation of a new compact mechanism for aromatic oxidation in atmospheric models K. Bates et al. 10.5194/acp-21-18351-2021
- Reassessing the atmospheric oxidation mechanism of toluene Y. Ji et al. 10.1073/pnas.1705463114
- Multi-generation OH oxidation as a source for highly oxygenated organic molecules from aromatics O. Garmash et al. 10.5194/acp-20-515-2020
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Unified Theory of Vapor–Wall Mass Transport in Teflon-Walled Environmental Chambers Y. Huang et al. 10.1021/acs.est.7b05575
- Modeling of the chemistry in oxidation flow reactors with high initial NO Z. Peng & J. Jimenez 10.5194/acp-17-11991-2017
- Effects of NO and SO2 on the secondary organic aerosol formation from the photooxidation of 1,3,5-trimethylbenzene: A new source of organosulfates Z. Yang et al. 10.1016/j.envpol.2020.114742
- Secondary organic aerosol formation from smoldering and flaming combustion of biomass: a box model parametrization based on volatility basis set G. Stefenelli et al. 10.5194/acp-19-11461-2019
- Differences of the oxidation process and secondary organic aerosol formation at low and high precursor concentrations T. Chen et al. 10.1016/j.jes.2018.11.011
- Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NO<sub><i>x</i></sub> conditions X. Cheng et al. 10.5194/acp-21-12005-2021
- Organic aerosol source apportionment in Zurich using an extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF-MS) – Part 2: Biomass burning influences in winter L. Qi et al. 10.5194/acp-19-8037-2019
- Radical chemistry in oxidation flow reactors for atmospheric chemistry research Z. Peng & J. Jimenez 10.1039/C9CS00766K
- Variability and Time of Day Dependence of Ozone Photochemistry in Western Wildfire Plumes M. Robinson et al. 10.1021/acs.est.1c01963
- Evaluation of the chemical composition of gas- and particle-phase products of aromatic oxidation A. Mehra et al. 10.5194/acp-20-9783-2020
- New Insights into the Radical Chemistry and Product Distribution in the OH-Initiated Oxidation of Benzene L. Xu et al. 10.1021/acs.est.0c04780
- Spatiotemporal variation, sources, and secondary transformation potential of volatile organic compounds in Xi'an, China M. Song et al. 10.5194/acp-21-4939-2021
- Evolution of OH reactivity in NO-free volatile organic compound photooxidation investigated by the fully explicit GECKO-A model Z. Peng et al. 10.5194/acp-21-14649-2021
- A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates W. Fan et al. 10.1016/j.jhazmat.2022.128406
- Low-volatility compounds contribute significantly to isoprene secondary organic aerosol (SOA) under high-NO<sub><i>x</i></sub> conditions R. Schwantes et al. 10.5194/acp-19-7255-2019
- Molecular characterization of alkyl nitrates in atmospheric aerosols by ion mobility mass spectrometry X. Zhang et al. 10.5194/amt-12-5535-2019
- Mitigation of Secondary Organic Aerosol Formation from Log Wood Burning Emissions by Catalytic Removal of Aromatic Hydrocarbons S. Pieber et al. 10.1021/acs.est.8b04124
- A steady-state continuous flow chamber for the study of daytime and nighttime chemistry under atmospherically relevant NO levels X. Zhang et al. 10.5194/amt-11-2537-2018
- Constraining the response factors of an extractive electrospray ionization mass spectrometer for near-molecular aerosol speciation D. Wang et al. 10.5194/amt-14-6955-2021
- Anthropogenic Volatile Organic Compound (AVOC) Autoxidation as a Source of Highly Oxygenated Organic Molecules (HOM) M. Rissanen 10.1021/acs.jpca.1c06465
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Advances on Atmospheric Oxidation Mechanism of Typical Aromatic Hydrocarbons M. Song et al. 10.6023/A21050224
- Secondary organic aerosol formation from monocyclic aromatic hydrocarbons: insights from laboratory studies Z. Yang et al. 10.1039/D1EM00409C
- Insight into the composition of organic compounds ( ≥ C<sub>6</sub>) in PM<sub>2.5</sub> in wintertime in Beijing, China R. Lyu et al. 10.5194/acp-19-10865-2019
- Effective regulation of surface bridging hydroxyls on TiO2 for superior photocatalytic activity via ozone treatment B. Liu et al. 10.1016/j.apcatb.2021.120952
- Secondary organic aerosol production from local emissions dominates the organic aerosol budget over Seoul, South Korea, during KORUS-AQ B. Nault et al. 10.5194/acp-18-17769-2018
- Assessing the Uncertainties in Ozone and SOA Predictions due to Different Branching Ratios of the Cresol Pathway in the Toluene-OH Oxidation Mechanism J. Zhang et al. 10.1021/acsearthspacechem.1c00092
- Total OH reactivity measurements for the OH-initiated oxidation of aromatic hydrocarbons in the presence of NOx K. Sato et al. 10.1016/j.atmosenv.2017.10.036
- Investigations into the gas-phase photolysis and OH radical kinetics of nitrocatechols: implications of intramolecular interactions on their atmospheric behaviour C. Roman et al. 10.5194/acp-22-2203-2022
- Experimental and theoretical study of the reactivity of a series of epoxides with chlorine atoms at 298 K C. Tovar et al. 10.1039/D0CP06033J
- Gas-phase IR cross-sections and single crystal structures data for atmospheric relevant nitrocatechols C. Roman et al. 10.1016/j.saa.2021.120379
- Gas-phase composition and secondary organic aerosol formation from standard and particle filter-retrofitted gasoline direct injection vehicles investigated in a batch and flow reactor S. Pieber et al. 10.5194/acp-18-9929-2018
- Precursors and formation of secondary organic aerosols from wildfires in the Euro-Mediterranean region M. Majdi et al. 10.5194/acp-19-5543-2019
- Measurement report: Important contributions of oxygenated compounds to emissions and chemistry of volatile organic compounds in urban air C. Wu et al. 10.5194/acp-20-14769-2020
- The origin of potential precursors of secondary organic aerosols during combustion of biochar and softwood in residential heating J. Růžičková et al. 10.1016/j.psep.2022.03.036
- Formation of secondary organic aerosol from nitrate radical oxidation of phenolic VOCs: Implications for nitration mechanisms and brown carbon formation R. Mayorga et al. 10.1016/j.atmosenv.2020.117910
- Photo-oxidation of Aromatic Hydrocarbons Produces Low-Volatility Organic Compounds M. Wang et al. 10.1021/acs.est.0c02100
- Estimation of Secondary Organic Aerosol Formation During a Photochemical Smog Episode in Shanghai, China H. Wang et al. 10.1029/2019JD032033
- Measurement report: Online measurement of gas-phase nitrated phenols utilizing a CI-LToF-MS: primary sources and secondary formation K. Song et al. 10.5194/acp-21-7917-2021
Latest update: 02 Jul 2022
Short summary
Toluene, one of the principle aromatic compounds present in the atmosphere, is oxidized by OH to produce cresol and other products. Here later-generation low-volatility oxygenated products from cresol oxidation by OH are detected in the gas and particle phases. This work identifies a simple and significant mechanism for toluene secondary organic aerosol formation through the cresol pathway. Likely the phenolic pathway of other aromatic compounds is also important for secondary organic aerosol.
Toluene, one of the principle aromatic compounds present in the atmosphere, is oxidized by OH to...
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