Articles | Volume 17, issue 3
https://doi.org/10.5194/acp-17-2423-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-2423-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Diffusion coefficients of organic molecules in sucrose–water solutions and comparison with Stokes–Einstein predictions
Yuri Chenyakin
Department of Chemistry, University of British Columbia, Vancouver, BC, V6T
1Z1, Canada
Dagny A. Ullmann
Department of Chemistry, University of British Columbia, Vancouver, BC, V6T
1Z1, Canada
Erin Evoy
Department of Chemistry, University of British Columbia, Vancouver, BC, V6T
1Z1, Canada
Lindsay Renbaum-Wolff
Department of Chemistry, University of British Columbia, Vancouver, BC, V6T
1Z1, Canada
now at: Aerodyne Research, Inc., Billerica, MA 01821,
Boston College, Chestnut Hill, MA 02467, USA
Saeid Kamal
CORRESPONDING AUTHOR
Department of Chemistry, University of British Columbia, Vancouver, BC, V6T
1Z1, Canada
Department of Chemistry, University of British Columbia, Vancouver, BC, V6T
1Z1, Canada
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Latest update: 23 Nov 2024
Short summary
Viscosity measurements, along with the Stokes–Einstein relation, have been used to estimate the diffusion rates of organics within SOA particles. To test the Stokes–Einstein relation, we measured the diffusion coefficients of three fluorescent organic dyes within sucrose–water solutions with varying water activity. The diffusion coefficients were measured using fluorescence recovery after photobleaching. The results should be useful for predicting the diffusion of organics with SOA particles.
Viscosity measurements, along with the Stokes–Einstein relation, have been used to estimate the...
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