Articles | Volume 17, issue 1
https://doi.org/10.5194/acp-17-159-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-159-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
04 Jan 2017
Research article |
| 04 Jan 2017
Molecular composition and volatility of isoprene photochemical oxidation secondary organic aerosol under low- and high-NOx conditions
Emma L. D'Ambro
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
Department of Chemistry, University of Washington, Seattle, WA 98195, USA
Ben H. Lee
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
Jiumeng Liu
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, WA 99352, USA
John E. Shilling
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, WA 99352, USA
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99352, USA
Cassandra J. Gaston
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
now at: Rosenstiel School of Marine & Atmospheric Science, University of Miami, FL 33149, USA
Felipe D. Lopez-Hilfiker
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
now at: Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Zurich, Switzerland
Siegfried Schobesberger
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
Rahul A. Zaveri
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, WA 99352, USA
Claudia Mohr
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
now at: Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, Germany
Anna Lutz
Department of Chemistry, Atmospheric Science, University of Gothenburg, Gothenburg, Sweden
Zhenfa Zhang
Department of Environmental Sciences and Engineering, Gillings School of Global and Public Health, University of North Carolina, Chapel Hill, NC 27599, USA
Avram Gold
Department of Environmental Sciences and Engineering, Gillings School of Global and Public Health, University of North Carolina, Chapel Hill, NC 27599, USA
Jason D. Surratt
Department of Environmental Sciences and Engineering, Gillings School of Global and Public Health, University of North Carolina, Chapel Hill, NC 27599, USA
Jean C. Rivera-Rios
John A. Paulson School of Engineering and Applied Sciences and Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
Frank N. Keutsch
John A. Paulson School of Engineering and Applied Sciences and Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
Joel A. Thornton
CORRESPONDING AUTHOR
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
Department of Chemistry, University of Washington, Seattle, WA 98195, USA
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Cited
59 citations as recorded by crossref.
- Primary Formation of Highly Oxidized Multifunctional Products in the OH-Initiated Oxidation of Isoprene: A Combined Theoretical and Experimental Study S. Wang et al. 10.1021/acs.est.8b02783
- Assessing the Potential Mechanisms of Isomerization Reactions of Isoprene Epoxydiols on Secondary Organic Aerosol A. Watanabe et al. 10.1021/acs.est.8b01780
- Isomerization of Second-Generation Isoprene Peroxy Radicals: Epoxide Formation and Implications for Secondary Organic Aerosol Yields E. D’Ambro et al. 10.1021/acs.est.7b00460
- Assessing Potential Oligomerization Reaction Mechanisms of Isoprene Epoxydiols on Secondary Organic Aerosol S. Stropoli et al. 10.1021/acs.est.8b05247
- PyCHAM (v2.1.1): a Python box model for simulating aerosol chambers S. O'Meara et al. 10.5194/gmd-14-675-2021
- Flight Deployment of a High‐Resolution Time‐of‐Flight Chemical Ionization Mass Spectrometer: Observations of Reactive Halogen and Nitrogen Oxide Species B. Lee et al. 10.1029/2017JD028082
- A Near-Explicit Mechanistic Evaluation of Isoprene Photochemical Secondary Organic Aerosol Formation and Evolution: Simulations of Multiple Chamber Experiments with and without Added NOx J. Thornton et al. 10.1021/acsearthspacechem.0c00118
- Closing the Reactive Carbon Flux Budget: Observations From Dual Mass Spectrometers Over a Coniferous Forest M. Vermeuel et al. 10.1029/2023JD038753
- Secondary Organic Aerosol (SOA) through Uptake of Isoprene Hydroxy Hydroperoxides (ISOPOOH) and its Oxidation Products P. Mettke et al. 10.1021/acsearthspacechem.2c00385
- Diverse Reactions in Highly Functionalized Organic Aerosols during Thermal Desorption Z. Zhao et al. 10.1021/acsearthspacechem.9b00312
- Molecular characterization of organic aerosol in winter from Beijing using UHPLC-Orbitrap MS Z. Wang et al. 10.1016/j.scitotenv.2021.151507
- Aerosol characteristics at the Southern Great Plains site during the HI-SCALE campaign J. Liu et al. 10.5194/acp-21-5101-2021
- Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.9b05514
- Isoprene-derived secondary organic aerosol in the global aerosol–chemistry–climate model ECHAM6.3.0–HAM2.3–MOZ1.0 S. Stadtler et al. 10.5194/gmd-11-3235-2018
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Semi-volatile and highly oxygenated gaseous and particulate organic compounds observed above a boreal forest canopy B. Lee et al. 10.5194/acp-18-11547-2018
- Estimating the saturation vapor pressures of isoprene oxidation products C<sub>5</sub>H<sub>12</sub>O<sub>6</sub> and C<sub>5</sub>H<sub>10</sub>O<sub>6</sub> using COSMO-RS T. Kurtén et al. 10.5194/acp-18-17589-2018
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- Partitioning of Organonitrates in the Production of Secondary Organic Aerosols from α-Pinene Photo-Oxidation E. Aruffo et al. 10.1021/acs.est.1c08380
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
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- Low-volatility compounds contribute significantly to isoprene secondary organic aerosol (SOA) under high-NO<sub><i>x</i></sub> conditions R. Schwantes et al. 10.5194/acp-19-7255-2019
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Growth Kinetics and Size Distribution Dynamics of Viscous Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.7b04623
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- Chlorine-initiated oxidation of <i>n</i>-alkanes under high-NO<sub><i>x</i></sub> conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO–CIMS D. Wang & L. Hildebrandt Ruiz 10.5194/acp-18-15535-2018
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- Computational Comparison of Different Reagent Ions in the Chemical Ionization of Oxidized Multifunctional Compounds N. Hyttinen et al. 10.1021/acs.jpca.7b10015
- Secondary organic aerosol of PM2.5 in a mountainous forest area in southeastern China: Molecular compositions and tracers implication Z. Hong et al. 10.1016/j.scitotenv.2018.10.370
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- A Coupled Volatility and Molecular Composition Based Source Apportionment of Atmospheric Organic Aerosol P. Rund et al. 10.1021/acsearthspacechem.3c00034
- Rapid production of highly oxidized molecules in isoprene aerosol via peroxy and alkoxy radical isomerization pathways in low and high NOx environments: Combined laboratory, computational and field studies M. Jaoui et al. 10.1016/j.scitotenv.2021.145592
- Isothermal Evaporation of α-Pinene Ozonolysis SOA: Volatility, Phase State, and Oligomeric Composition E. D’Ambro et al. 10.1021/acsearthspacechem.8b00084
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
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- Using highly time-resolved online mass spectrometry to examine biogenic and anthropogenic contributions to organic aerosol in Beijing A. Mehra et al. 10.1039/D0FD00080A
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
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- A model framework to retrieve thermodynamic and kinetic properties of organic aerosol from composition-resolved thermal desorption measurements S. Schobesberger et al. 10.5194/acp-18-14757-2018
- Gas-Phase Reactions of Isoprene and Its Major Oxidation Products P. Wennberg et al. 10.1021/acs.chemrev.7b00439
- An omnipresent diversity and variability in the chemical composition of atmospheric functionalized organic aerosol J. Ditto et al. 10.1038/s42004-018-0074-3
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- Effect of inorganic-to-organic mass ratio on the heterogeneous OH reaction rates of erythritol: implications for atmospheric chemical stability of 2-methyltetrols R. Xu et al. 10.5194/acp-20-3879-2020
- Multifunctional Products of Isoprene Oxidation in Polluted Atmosphere and Their Contribution to SOA Z. Xu et al. 10.1029/2020GL089276
- Chamber-based insights into the factors controlling epoxydiol (IEPOX) secondary organic aerosol (SOA) yield, composition, and volatility E. D'Ambro et al. 10.5194/acp-19-11253-2019
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- A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application T. Bannan et al. 10.5194/amt-12-1429-2019
- Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol Y. Chen et al. 10.1021/acs.est.3c03532
- Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest R. Zaveri et al. 10.1126/sciadv.abj0329
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al. 10.1080/02786826.2022.2133593
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
- Impact of Thermal Decomposition on Thermal Desorption Instruments: Advantage of Thermogram Analysis for Quantifying Volatility Distributions of Organic Species H. Stark et al. 10.1021/acs.est.7b00160
57 citations as recorded by crossref.
- Primary Formation of Highly Oxidized Multifunctional Products in the OH-Initiated Oxidation of Isoprene: A Combined Theoretical and Experimental Study S. Wang et al. 10.1021/acs.est.8b02783
- Assessing the Potential Mechanisms of Isomerization Reactions of Isoprene Epoxydiols on Secondary Organic Aerosol A. Watanabe et al. 10.1021/acs.est.8b01780
- Isomerization of Second-Generation Isoprene Peroxy Radicals: Epoxide Formation and Implications for Secondary Organic Aerosol Yields E. D’Ambro et al. 10.1021/acs.est.7b00460
- Assessing Potential Oligomerization Reaction Mechanisms of Isoprene Epoxydiols on Secondary Organic Aerosol S. Stropoli et al. 10.1021/acs.est.8b05247
- PyCHAM (v2.1.1): a Python box model for simulating aerosol chambers S. O'Meara et al. 10.5194/gmd-14-675-2021
- Flight Deployment of a High‐Resolution Time‐of‐Flight Chemical Ionization Mass Spectrometer: Observations of Reactive Halogen and Nitrogen Oxide Species B. Lee et al. 10.1029/2017JD028082
- A Near-Explicit Mechanistic Evaluation of Isoprene Photochemical Secondary Organic Aerosol Formation and Evolution: Simulations of Multiple Chamber Experiments with and without Added NOx J. Thornton et al. 10.1021/acsearthspacechem.0c00118
- Closing the Reactive Carbon Flux Budget: Observations From Dual Mass Spectrometers Over a Coniferous Forest M. Vermeuel et al. 10.1029/2023JD038753
- Secondary Organic Aerosol (SOA) through Uptake of Isoprene Hydroxy Hydroperoxides (ISOPOOH) and its Oxidation Products P. Mettke et al. 10.1021/acsearthspacechem.2c00385
- Diverse Reactions in Highly Functionalized Organic Aerosols during Thermal Desorption Z. Zhao et al. 10.1021/acsearthspacechem.9b00312
- Molecular characterization of organic aerosol in winter from Beijing using UHPLC-Orbitrap MS Z. Wang et al. 10.1016/j.scitotenv.2021.151507
- Aerosol characteristics at the Southern Great Plains site during the HI-SCALE campaign J. Liu et al. 10.5194/acp-21-5101-2021
- Particle-Phase Diffusion Modulates Partitioning of Semivolatile Organic Compounds to Aged Secondary Organic Aerosol R. Zaveri et al. 10.1021/acs.est.9b05514
- Isoprene-derived secondary organic aerosol in the global aerosol–chemistry–climate model ECHAM6.3.0–HAM2.3–MOZ1.0 S. Stadtler et al. 10.5194/gmd-11-3235-2018
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Semi-volatile and highly oxygenated gaseous and particulate organic compounds observed above a boreal forest canopy B. Lee et al. 10.5194/acp-18-11547-2018
- Estimating the saturation vapor pressures of isoprene oxidation products C<sub>5</sub>H<sub>12</sub>O<sub>6</sub> and C<sub>5</sub>H<sub>10</sub>O<sub>6</sub> using COSMO-RS T. Kurtén et al. 10.5194/acp-18-17589-2018
- Isoprene–Chlorine Oxidation in the Presence of NOx and Implications for Urban Atmospheric Chemistry D. Wang et al. 10.1021/acs.est.1c07048
- Partitioning of Organonitrates in the Production of Secondary Organic Aerosols from α-Pinene Photo-Oxidation E. Aruffo et al. 10.1021/acs.est.1c08380
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- Low-volatility compounds contribute significantly to isoprene secondary organic aerosol (SOA) under high-NO<sub><i>x</i></sub> conditions R. Schwantes et al. 10.5194/acp-19-7255-2019
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
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- Chlorine-initiated oxidation of <i>n</i>-alkanes under high-NO<sub><i>x</i></sub> conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO–CIMS D. Wang & L. Hildebrandt Ruiz 10.5194/acp-18-15535-2018
- Chemical Characterization of Highly Functionalized Organonitrates Contributing to Night-Time Organic Aerosol Mass Loadings and Particle Growth W. Huang et al. 10.1021/acs.est.8b05826
- Parameterized Yields of Semivolatile Products from Isoprene Oxidation under Different NOx Levels: Impacts of Chemical Aging and Wall-Loss of Reactive Gases L. Xing et al. 10.1021/acs.est.8b00373
- Computational Comparison of Different Reagent Ions in the Chemical Ionization of Oxidized Multifunctional Compounds N. Hyttinen et al. 10.1021/acs.jpca.7b10015
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- <i>α</i>-Pinene secondary organic aerosol at low temperature: chemical composition and implications for particle viscosity W. Huang et al. 10.5194/acp-18-2883-2018
- On the calibration of FIGAERO-ToF-CIMS: importance and impact of calibrant delivery for the particle-phase calibration A. Ylisirniö et al. 10.5194/amt-14-355-2021
- Oxygenated products formed from OH-initiated reactions of trimethylbenzene: autoxidation and accretion Y. Wang et al. 10.5194/acp-20-9563-2020
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- A Coupled Volatility and Molecular Composition Based Source Apportionment of Atmospheric Organic Aerosol P. Rund et al. 10.1021/acsearthspacechem.3c00034
- Rapid production of highly oxidized molecules in isoprene aerosol via peroxy and alkoxy radical isomerization pathways in low and high NOx environments: Combined laboratory, computational and field studies M. Jaoui et al. 10.1016/j.scitotenv.2021.145592
- Isothermal Evaporation of α-Pinene Ozonolysis SOA: Volatility, Phase State, and Oligomeric Composition E. D’Ambro et al. 10.1021/acsearthspacechem.8b00084
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Characteristics of secondary organic aerosols tracers in PM2.5 in three central cities of the Yangtze river delta, China C. Yang et al. 10.1016/j.chemosphere.2022.133637
- Using highly time-resolved online mass spectrometry to examine biogenic and anthropogenic contributions to organic aerosol in Beijing A. Mehra et al. 10.1039/D0FD00080A
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- A vacuum ultraviolet ion source (VUV-IS) for iodide–chemical ionization mass spectrometry: a substitute for radioactive ion sources Y. Ji et al. 10.5194/amt-13-3683-2020
- Determining the Relative Reactivity of Sulfate, Bisulfate, and Organosulfates with Epoxides on Secondary Organic Aerosol E. Aoki et al. 10.1021/acsearthspacechem.0c00178
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- Gas-Phase Reactions of Isoprene and Its Major Oxidation Products P. Wennberg et al. 10.1021/acs.chemrev.7b00439
- An omnipresent diversity and variability in the chemical composition of atmospheric functionalized organic aerosol J. Ditto et al. 10.1038/s42004-018-0074-3
- A robust clustering algorithm for analysis of composition-dependent organic aerosol thermal desorption measurements Z. Li et al. 10.5194/acp-20-2489-2020
- Effect of inorganic-to-organic mass ratio on the heterogeneous OH reaction rates of erythritol: implications for atmospheric chemical stability of 2-methyltetrols R. Xu et al. 10.5194/acp-20-3879-2020
- Multifunctional Products of Isoprene Oxidation in Polluted Atmosphere and Their Contribution to SOA Z. Xu et al. 10.1029/2020GL089276
- Chamber-based insights into the factors controlling epoxydiol (IEPOX) secondary organic aerosol (SOA) yield, composition, and volatility E. D'Ambro et al. 10.5194/acp-19-11253-2019
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application T. Bannan et al. 10.5194/amt-12-1429-2019
- Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol Y. Chen et al. 10.1021/acs.est.3c03532
- Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest R. Zaveri et al. 10.1126/sciadv.abj0329
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al. 10.1080/02786826.2022.2133593
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
2 citations as recorded by crossref.
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
- Impact of Thermal Decomposition on Thermal Desorption Instruments: Advantage of Thermogram Analysis for Quantifying Volatility Distributions of Organic Species H. Stark et al. 10.1021/acs.est.7b00160
Saved (final revised paper)
Latest update: 22 Apr 2024
Short summary
We studied the formation and properties of secondary organic aerosol produced from isoprene. We find that a significant fraction (~50 %) of the mass is composed of low-volatility, highly oxidized compounds such as C5H12O6. A significant fraction of the remainder appears to be in the form of oligomeric material. Adding NOx maintained or decreased SOA yields while increasing the fraction of low-volatility material, possibly due to oligomers.
We studied the formation and properties of secondary organic aerosol produced from isoprene. We...
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