Articles | Volume 17, issue 1
https://doi.org/10.5194/acp-17-159-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-159-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
04 Jan 2017
Research article |
| 04 Jan 2017
Molecular composition and volatility of isoprene photochemical oxidation secondary organic aerosol under low- and high-NOx conditions
Emma L. D'Ambro
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
Department of Chemistry, University of Washington, Seattle, WA 98195, USA
Ben H. Lee
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
Jiumeng Liu
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, WA 99352, USA
John E. Shilling
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, WA 99352, USA
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA 99352, USA
Cassandra J. Gaston
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
now at: Rosenstiel School of Marine & Atmospheric Science, University of Miami, FL 33149, USA
Felipe D. Lopez-Hilfiker
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
now at: Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Zurich, Switzerland
Siegfried Schobesberger
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
Rahul A. Zaveri
Atmospheric Sciences and Global Change Division, Pacific Northwest National Laboratory, Richland, WA 99352, USA
Claudia Mohr
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
now at: Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Karlsruhe, Germany
Anna Lutz
Department of Chemistry, Atmospheric Science, University of Gothenburg, Gothenburg, Sweden
Zhenfa Zhang
Department of Environmental Sciences and Engineering, Gillings School of Global and Public Health, University of North Carolina, Chapel Hill, NC 27599, USA
Avram Gold
Department of Environmental Sciences and Engineering, Gillings School of Global and Public Health, University of North Carolina, Chapel Hill, NC 27599, USA
Jason D. Surratt
Department of Environmental Sciences and Engineering, Gillings School of Global and Public Health, University of North Carolina, Chapel Hill, NC 27599, USA
Jean C. Rivera-Rios
John A. Paulson School of Engineering and Applied Sciences and Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
Frank N. Keutsch
John A. Paulson School of Engineering and Applied Sciences and Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
Joel A. Thornton
CORRESPONDING AUTHOR
Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
Department of Chemistry, University of Washington, Seattle, WA 98195, USA
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58 citations as recorded by crossref.
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- Semi-volatile and highly oxygenated gaseous and particulate organic compounds observed above a boreal forest canopy B. Lee et al. 10.5194/acp-18-11547-2018
- Estimating the saturation vapor pressures of isoprene oxidation products C<sub>5</sub>H<sub>12</sub>O<sub>6</sub> and C<sub>5</sub>H<sub>10</sub>O<sub>6</sub> using COSMO-RS T. Kurtén et al. 10.5194/acp-18-17589-2018
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- Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol Y. Chen et al. 10.1021/acs.est.3c03532
- Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest R. Zaveri et al. 10.1126/sciadv.abj0329
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al. 10.1080/02786826.2022.2133593
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
2 citations as recorded by crossref.
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
- Impact of Thermal Decomposition on Thermal Desorption Instruments: Advantage of Thermogram Analysis for Quantifying Volatility Distributions of Organic Species H. Stark et al. 10.1021/acs.est.7b00160
Saved (final revised paper)
Latest update: 16 Jul 2024
Short summary
We studied the formation and properties of secondary organic aerosol produced from isoprene. We find that a significant fraction (~50 %) of the mass is composed of low-volatility, highly oxidized compounds such as C5H12O6. A significant fraction of the remainder appears to be in the form of oligomeric material. Adding NOx maintained or decreased SOA yields while increasing the fraction of low-volatility material, possibly due to oligomers.
We studied the formation and properties of secondary organic aerosol produced from isoprene. We...
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