Articles | Volume 17, issue 2
https://doi.org/10.5194/acp-17-1557-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-1557-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Halogen chemistry reduces tropospheric O3 radiative forcing
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, YO10 5DD, UK
Mat J. Evans
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, YO10 5DD, UK
National Centre for Atmospheric Science, University of York, York, YO10 5DD, UK
Lucy J. Carpenter
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, YO10 5DD, UK
Johan A. Schmidt
Department of Chemistry, Copenhagen University, Universitetsparken, 2100 Copenhagen O, Denmark
Loretta J. Mickley
John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts, USA
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42 citations as recorded by crossref.
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- Multidecadal increases in global tropospheric ozone derived from ozonesonde and surface site observations: can models reproduce ozone trends? A. Christiansen et al. 10.5194/acp-22-14751-2022
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- Midlatitude Ozone Depletion and Air Quality Impacts from Industrial Halogen Emissions in the Great Salt Lake Basin C. Womack et al. 10.1021/acs.est.2c05376
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- A kinetic model for ozone uptake by solutions and aqueous particles containing I−and Br−, including seawater and sea-salt aerosol C. Moreno & M. Baeza-Romero 10.1039/C9CP03430G
- Intercomparison Between Surrogate, Explicit, and Full Treatments of VSL Bromine Chemistry Within the CAM‐Chem Chemistry‐Climate Model R. Fernandez et al. 10.1029/2020GL091125
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- Impacts of global NO<sub><i>x</i></sub> inversions on NO<sub>2</sub> and ozone simulations Z. Qu et al. 10.5194/acp-20-13109-2020
- Global sea-surface iodide observations, 1967–2018 R. Chance et al. 10.1038/s41597-019-0288-y
- Formation of Chlorine in the Atmosphere by Reaction of Hypochlorous Acid with Seawater I. Mandal et al. 10.1021/acs.jpclett.3c03035
- Understanding Iodine Chemistry Over the Northern and Equatorial Indian Ocean A. Mahajan et al. 10.1029/2018JD029063
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- Isotopic constraint on the twentieth-century increase in tropospheric ozone L. Yeung et al. 10.1038/s41586-019-1277-1
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Latest update: 20 Nov 2024
Short summary
We model pre-industrial to present day changes using the GEOS-Chem global chemical transport model with halogens (Cl, Br, I). The model better captures pre-industrial O3 observations with halogens included. Halogens buffer the tropospheric forcing of O3 (RFTO3) from pre-industrial to present day, reducing RFTO3 by 0.087 Wm−2. This reduction is greater than that from halogens on stratospheric O3 (−0.05 Wm−2). This suggests that models that do not include halogens will overestimate RFTO3by ~ 25%.
We model pre-industrial to present day changes using the GEOS-Chem global chemical transport...
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