Articles | Volume 17, issue 2
https://doi.org/10.5194/acp-17-1557-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-1557-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| Highlight paper
| 
31 Jan 2017
Research article | Highlight paper |
| 31 Jan 2017
Halogen chemistry reduces tropospheric O3 radiative forcing
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, YO10 5DD, UK
Mat J. Evans
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, YO10 5DD, UK
National Centre for Atmospheric Science, University of York, York, YO10 5DD, UK
Lucy J. Carpenter
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, YO10 5DD, UK
Johan A. Schmidt
Department of Chemistry, Copenhagen University, Universitetsparken, 2100 Copenhagen O, Denmark
Loretta J. Mickley
John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts, USA
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42 citations as recorded by crossref.
- BrO and inferred Br<sub><i>y</i></sub> profiles over the western Pacific: relevance of inorganic bromine sources and a Br<sub><i>y</i></sub> minimum in the aged tropical tropopause layer T. Koenig et al. 10.5194/acp-17-15245-2017
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- Natural short-lived halogens exert an indirect cooling effect on climate A. Saiz-Lopez et al. 10.1038/s41586-023-06119-z
- Climate changes modulated the history of Arctic iodine during the Last Glacial Cycle J. Corella et al. 10.1038/s41467-021-27642-5
- Alpine ice evidence of a three-fold increase in atmospheric iodine deposition since 1950 in Europe due to increasing oceanic emissions M. Legrand et al. 10.1073/pnas.1809867115
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- Photochemistry of CH3I···(H2O)n Complexes: From CH3I···H2O to CH3I in Interaction with Water Ices and Atmospheric Implications S. Sobanska et al. 10.1021/acsearthspacechem.3c00351
- Causes of Enhanced Bromine Levels in Alpine Ice Cores During the 20th Century: Implications for Bromine in the Free European Troposphere M. Legrand et al. 10.1029/2020JD034246
- Scientific assessment of background ozone over the U.S.: Implications for air quality management D. Jaffe et al. 10.1525/elementa.309
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- The opposing effect of butanol and butyric acid on the abundance of bromide and iodide at the aqueous solution–air interface M. Lee et al. 10.1039/C8CP07448H
- Multidecadal increases in global tropospheric ozone derived from ozonesonde and surface site observations: can models reproduce ozone trends? A. Christiansen et al. 10.5194/acp-22-14751-2022
- Impact of Tetrabutylammonium on the Oxidation of Bromide by Ozone S. Chen et al. 10.1021/acsearthspacechem.1c00233
- Midlatitude Ozone Depletion and Air Quality Impacts from Industrial Halogen Emissions in the Great Salt Lake Basin C. Womack et al. 10.1021/acs.est.2c05376
- Holocene atmospheric iodine evolution over the North Atlantic J. Corella et al. 10.5194/cp-15-2019-2019
- A kinetic model for ozone uptake by solutions and aqueous particles containing I−and Br−, including seawater and sea-salt aerosol C. Moreno & M. Baeza-Romero 10.1039/C9CP03430G
- Intercomparison Between Surrogate, Explicit, and Full Treatments of VSL Bromine Chemistry Within the CAM‐Chem Chemistry‐Climate Model R. Fernandez et al. 10.1029/2020GL091125
- Sensitivity of tropospheric ozone to halogen chemistry in the chemistry–climate model LMDZ-INCA vNMHC C. Caram et al. 10.5194/gmd-16-4041-2023
- Impacts of global NO<sub><i>x</i></sub> inversions on NO<sub>2</sub> and ozone simulations Z. Qu et al. 10.5194/acp-20-13109-2020
- Global sea-surface iodide observations, 1967–2018 R. Chance et al. 10.1038/s41597-019-0288-y
- Formation of Chlorine in the Atmosphere by Reaction of Hypochlorous Acid with Seawater I. Mandal et al. 10.1021/acs.jpclett.3c03035
- Understanding Iodine Chemistry Over the Northern and Equatorial Indian Ocean A. Mahajan et al. 10.1029/2018JD029063
- Influence of the Sea Surface Microlayer on Oceanic Iodine Emissions L. Tinel et al. 10.1021/acs.est.0c02736
- Tropospheric Ozone Assessment Report A. Archibald et al. 10.1525/elementa.2020.034
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- Surface Propensity of Aqueous Atmospheric Bromine at the Liquid–Gas Interface I. Gladich et al. 10.1021/acs.jpclett.0c00633
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- Isotopic constraint on the twentieth-century increase in tropospheric ozone L. Yeung et al. 10.1038/s41586-019-1277-1
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- The novel HALO mini-DOAS instrument: inferring trace gas concentrations from airborne UV/visible limb spectroscopy under all skies using the scaling method T. Hüneke et al. 10.5194/amt-10-4209-2017
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Latest update: 08 Nov 2024
Short summary
We model pre-industrial to present day changes using the GEOS-Chem global chemical transport model with halogens (Cl, Br, I). The model better captures pre-industrial O3 observations with halogens included. Halogens buffer the tropospheric forcing of O3 (RFTO3) from pre-industrial to present day, reducing RFTO3 by 0.087 Wm−2. This reduction is greater than that from halogens on stratospheric O3 (−0.05 Wm−2). This suggests that models that do not include halogens will overestimate RFTO3by ~ 25%.
We model pre-industrial to present day changes using the GEOS-Chem global chemical transport...
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