Articles | Volume 17, issue 23
https://doi.org/10.5194/acp-17-14415-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-14415-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
05 Dec 2017
Research article |
| 05 Dec 2017
Compositional evolution of particle-phase reaction products and water in the heterogeneous OH oxidation of model aqueous organic aerosols
Man Mei Chim
Earth System Science Programme, Faculty of Science, The Chinese University of Hong Kong, Hong Kong, China
Chiu Tung Cheng
Earth System Science Programme, Faculty of Science, The Chinese University of Hong Kong, Hong Kong, China
present address: Atmosphere and Ocean Research Institute, The University of Tokyo, Tokyo, Japan
James F. Davies
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California, USA
Thomas Berkemeier
School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia, USA
Manabu Shiraiwa
Department of Chemistry, School of Physical Sciences, University of California, Irvine, California, USA
Andreas Zuend
Department of Atmospheric and Oceanic Sciences, McGill University, Montreal, Québec, Canada
Man Nin Chan
CORRESPONDING AUTHOR
Earth System Science Programme, Faculty of Science, The Chinese University of Hong Kong, Hong Kong, China
The Institute of Environment, Energy and Sustainability, The Chinese University of Hong Kong, Hong Kong, China
Viewed
Total article views: 3,144 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 13 Jun 2017)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,862 | 1,081 | 201 | 3,144 | 330 | 69 | 97 |
- HTML: 1,862
- PDF: 1,081
- XML: 201
- Total: 3,144
- Supplement: 330
- BibTeX: 69
- EndNote: 97
Total article views: 2,447 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 05 Dec 2017)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,450 | 809 | 188 | 2,447 | 198 | 64 | 85 |
- HTML: 1,450
- PDF: 809
- XML: 188
- Total: 2,447
- Supplement: 198
- BibTeX: 64
- EndNote: 85
Total article views: 697 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 13 Jun 2017)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 412 | 272 | 13 | 697 | 132 | 5 | 12 |
- HTML: 412
- PDF: 272
- XML: 13
- Total: 697
- Supplement: 132
- BibTeX: 5
- EndNote: 12
Viewed (geographical distribution)
Total article views: 3,144 (including HTML, PDF, and XML)
Thereof 3,120 with geography defined
and 24 with unknown origin.
Total article views: 2,447 (including HTML, PDF, and XML)
Thereof 2,429 with geography defined
and 18 with unknown origin.
Total article views: 697 (including HTML, PDF, and XML)
Thereof 691 with geography defined
and 6 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
17 citations as recorded by crossref.
- Relative humidity-dependent evolution of molecular composition of α-pinene secondary organic aerosol upon heterogeneous oxidation by hydroxyl radicals W. Wang et al. 10.1016/j.jes.2023.08.021
- Atmospheric oxidation impact on sea spray produced ice nucleating particles P. DeMott et al. 10.1039/D3EA00060E
- Heterogeneous OH oxidation of isoprene-epoxydiol-derived organosulfates: kinetics, chemistry and formation of inorganic sulfate H. Lam et al. 10.5194/acp-19-2433-2019
- Size Distribution and Secondary Formation of Particulate Organic Nitrates in Winter in a Coastal Area A. Shakoor et al. 10.3390/su152416776
- Effect of inorganic-to-organic mass ratio on the heterogeneous OH reaction rates of erythritol: implications for atmospheric chemical stability of 2-methyltetrols R. Xu et al. 10.5194/acp-20-3879-2020
- Visualizing reaction and diffusion in xanthan gum aerosol particles exposed to ozone P. Alpert et al. 10.1039/C9CP03731D
- Size distributions of nitrated phenols in winter at a coastal site in north China and the impacts from primary sources and secondary formation Y. Liang et al. 10.1016/j.chemosphere.2020.126256
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Tracer-based characterization of source variations of PM2.5 and organic carbon in Shanghai influenced by the COVID-19 lockdown S. Zhu et al. 10.1039/D0FD00091D
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Molecular characteristics of sea spray aerosols during aging with the participation of marine volatile organic compounds X. Ma et al. 10.1016/j.scitotenv.2024.176380
- Evolution in the Reactivity of Citric Acid toward Heterogeneous Oxidation by Gas-Phase OH Radicals M. Chim et al. 10.1021/acsearthspacechem.8b00118
- Influence of relative humidity on the heterogeneous oxidation of secondary organic aerosol Z. Li et al. 10.5194/acp-18-14585-2018
- Organic Surfactants Protect Dissolved Aerosol Components against Heterogeneous Oxidation J. Faust & J. Abbatt 10.1021/acs.jpca.9b00167
- Effects of inorganic salts on the heterogeneous OH oxidation of organic compounds: insights from methylglutaric acid–ammonium sulfate H. Lam et al. 10.5194/acp-19-9581-2019
- Effects of Atmospheric Aging Processes on Nascent Sea Spray Aerosol Physicochemical Properties C. Kaluarachchi et al. 10.1021/acsearthspacechem.2c00258
- Hourly organic tracers-based source apportionment of PM2.5 before and during the Covid-19 lockdown in suburban Shanghai, China: Insights into regional transport influences and response to urban emission reductions S. Wang et al. 10.1016/j.atmosenv.2022.119308
17 citations as recorded by crossref.
- Relative humidity-dependent evolution of molecular composition of α-pinene secondary organic aerosol upon heterogeneous oxidation by hydroxyl radicals W. Wang et al. 10.1016/j.jes.2023.08.021
- Atmospheric oxidation impact on sea spray produced ice nucleating particles P. DeMott et al. 10.1039/D3EA00060E
- Heterogeneous OH oxidation of isoprene-epoxydiol-derived organosulfates: kinetics, chemistry and formation of inorganic sulfate H. Lam et al. 10.5194/acp-19-2433-2019
- Size Distribution and Secondary Formation of Particulate Organic Nitrates in Winter in a Coastal Area A. Shakoor et al. 10.3390/su152416776
- Effect of inorganic-to-organic mass ratio on the heterogeneous OH reaction rates of erythritol: implications for atmospheric chemical stability of 2-methyltetrols R. Xu et al. 10.5194/acp-20-3879-2020
- Visualizing reaction and diffusion in xanthan gum aerosol particles exposed to ozone P. Alpert et al. 10.1039/C9CP03731D
- Size distributions of nitrated phenols in winter at a coastal site in north China and the impacts from primary sources and secondary formation Y. Liang et al. 10.1016/j.chemosphere.2020.126256
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Tracer-based characterization of source variations of PM2.5 and organic carbon in Shanghai influenced by the COVID-19 lockdown S. Zhu et al. 10.1039/D0FD00091D
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Molecular characteristics of sea spray aerosols during aging with the participation of marine volatile organic compounds X. Ma et al. 10.1016/j.scitotenv.2024.176380
- Evolution in the Reactivity of Citric Acid toward Heterogeneous Oxidation by Gas-Phase OH Radicals M. Chim et al. 10.1021/acsearthspacechem.8b00118
- Influence of relative humidity on the heterogeneous oxidation of secondary organic aerosol Z. Li et al. 10.5194/acp-18-14585-2018
- Organic Surfactants Protect Dissolved Aerosol Components against Heterogeneous Oxidation J. Faust & J. Abbatt 10.1021/acs.jpca.9b00167
- Effects of inorganic salts on the heterogeneous OH oxidation of organic compounds: insights from methylglutaric acid–ammonium sulfate H. Lam et al. 10.5194/acp-19-9581-2019
- Effects of Atmospheric Aging Processes on Nascent Sea Spray Aerosol Physicochemical Properties C. Kaluarachchi et al. 10.1021/acsearthspacechem.2c00258
- Hourly organic tracers-based source apportionment of PM2.5 before and during the Covid-19 lockdown in suburban Shanghai, China: Insights into regional transport influences and response to urban emission reductions S. Wang et al. 10.1016/j.atmosenv.2022.119308
Latest update: 14 Dec 2024
Short summary
In this work, we report that methyl-substituted succinic acid present at or near the surface of aqueous organic droplets can be efficiently oxidized by gas-phase OH radicals. The alkoxy radical chemistry appears to be an important reaction pathway. In addition, our model simulations reveal the relative importance of functionalization and fragmentation processes, alongside volatilization, in the evolution of the particle-phase reaction, which is largely dependent on the extent of oxidation.
In this work, we report that methyl-substituted succinic acid present at or near the surface of...
Altmetrics
Final-revised paper
Preprint