Articles | Volume 17, issue 2
Atmos. Chem. Phys., 17, 1401–1415, 2017
Atmos. Chem. Phys., 17, 1401–1415, 2017

Research article 31 Jan 2017

Research article | 31 Jan 2017

Atmospheric processes of organic pollutants over a remote lake on the central Tibetan Plateau: implications for regional cycling

Jiao Ren1,3, Xiaoping Wang1,2, Chuanfei Wang1,2, Ping Gong1,2, and Tandong Yao1,2 Jiao Ren et al.
  • 1Key Laboratory of Tibetan Environment Changes and Land Surface Processes, Institute of Tibetan Plateau Research, Chinese Academy of Sciences, Beijing, 100101, China
  • 2CAS Center for Excellence in Tibetan Plateau Earth Sciences, Beijing, 100101, China
  • 3University of Chinese Academy of Sciences, Beijing 100049, China

Abstract. Atmospheric processes (air–surface exchange, and atmospheric deposition and degradation) are crucial for understanding the global cycling and fate of organic pollutants (OPs). However, such assessments over the Tibetan Plateau (TP) remain uncertain. More than 50 % of Chinese lakes are located on the TP, which exerts a remarkable influence on the regional water, energy, and chemical cycling. In this study, air and water samples were simultaneously collected in Nam Co, a large lake on the TP, to test whether the lake is a secondary source or sink of OPs. Lower concentrations of organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) were observed in the atmosphere and lake water of Nam Co, while the levels of polycyclic aromatic hydrocarbons (PAHs) were relatively higher. Results of fugacity ratios and chiral signatures both suggest that the lake acted as the net sink of atmospheric hexachlorocyclohexanes (HCHs), following their long-range transport driven by the Indian monsoon. Different behaviours were observed in the PAHs, which primarily originated from local biomass burning. Acenaphthylene, acenaphthene, and fluorene showed volatilization from the lake to the atmosphere, while other PAHs were deposited into the lake due to the integrated deposition process (wet/dry and air–water gas deposition) and limited atmospheric degradation. As the dominant PAH compound, phenanthrene exhibited a seasonal reversal of air–water gas exchange, which was likely related to the melting of the lake ice in May. The annual input of HCHs from the air to the entire lake area (2015 km2) was estimated as 1.9 kg yr−1, while input estimated for  15PAHs can potentially reach up to 550 kg yr−1. This study highlights the significance of PAH deposition on the regional carbon cycling in the oligotrophic lakes of the TP.

Short summary
Do the water bodies in the Tibetan Plateau (TP) act as a sink or secondary source of organic pollutants (OPs)? To answer this question, atmospheric processes of OPs over a large lake on the TP were quantified. We found that the lake was a net sink of hexachlorocyclohexanes (HCHs) and most polycyclic aromatic hydrocarbons (PAHs), but it turned into a secondary source of phenanthrene, coinciding with the melting of lake ice.
Final-revised paper