Different pathways of the formation of highly oxidized multifunctional
organic compounds (HOMs) from the gas-phase ozonolysis of <i>β</i>-caryophyllene

Richters, Stefanie; Herrmann, Hartmut; Berndt, Torsten

doi:10.5194/acp-16-9831-2016

Articles | Volume 16, issue 15

https://doi.org/10.5194/acp-16-9831-2016

© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

https://doi.org/10.5194/acp-16-9831-2016

© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Articles | Volume 16, issue 15

Research article

|

04 Aug 2016

Research article |

| 04 Aug 2016

Different pathways of the formation of highly oxidized multifunctional organic compounds (HOMs) from the gas-phase ozonolysis of β-caryophyllene

Stefanie Richters, Hartmut Herrmann, and Torsten Berndt

Viewed

Total article views: 3,308 (including HTML, PDF, and XML)

HTML	PDF	XML	Total	Supplement	BibTeX	EndNote
2,054	1,154	100	3,308	559	112	166

HTML: 2,054
PDF: 1,154
XML: 100
Total: 3,308
Supplement: 559
BibTeX: 112
EndNote: 166

Views and downloads (calculated since 14 Mar 2016)

Month	HTML	PDF	XML	Total
Mar 2016	130	58	0	188
Apr 2016	38	19	1	58
May 2016	22	8	0	30
Jun 2016	16	3	1	20
Jul 2016	15	8	0	23
Aug 2016	114	55	5	174
Sep 2016	18	11	0	29
Oct 2016	11	6	0	17
Nov 2016	9	5	0	14
Dec 2016	7	4	0	11
Jan 2017	17	16	1	34
Feb 2017	18	13	1	32
Mar 2017	21	9	2	32
Apr 2017	22	17	1	40
May 2017	25	15	2	42
Jun 2017	14	8	2	24
Jul 2017	17	9	0	26
Aug 2017	16	14	2	32
Sep 2017	8	8	0	16
Oct 2017	13	10	0	23
Nov 2017	13	15	1	29
Dec 2017	21	18	0	39
Jan 2018	12	14	0	26
Feb 2018	11	6	0	17
Mar 2018	9	12	0	21
Apr 2018	11	7	0	18
May 2018	15	11	1	27
Jun 2018	10	24	0	34
Jul 2018	14	12	1	27
Aug 2018	15	6	0	21
Sep 2018	9	9	3	21
Oct 2018	17	12	3	32
Nov 2018	25	13	0	38
Dec 2018	5	5	0	10
Jan 2019	6	7	1	14
Feb 2019	4	3	0	7
Mar 2019	4	13	0	17
Apr 2019	4	2	0	6
May 2019	7	5	0	12
Jun 2019	12	9	0	21
Jul 2019	8	13	0	21
Aug 2019	5	8	1	14
Sep 2019	3	6	0	9
Oct 2019	3	5	1	9
Nov 2019	3	3	0	6
Dec 2019	3	6	0	9
Jan 2020	10	12	0	22
Feb 2020	9	4	1	14
Mar 2020	3	9	0	12
Apr 2020	3	7	1	11
May 2020	4	1	0	5
Jun 2020	14	11	0	25
Jul 2020	17	12	6	35
Aug 2020	8	4	1	13
Sep 2020	10	6	0	16
Oct 2020	5	7	0	12
Nov 2020	10	9	1	20
Dec 2020	12	6	0	18
Jan 2021	16	10	0	26
Feb 2021	7	7	0	14
Mar 2021	10	12	0	22
Apr 2021	7	8	1	16
May 2021	9	10	1	20
Jun 2021	6	2	0	8
Jul 2021	9	8	0	17
Aug 2021	15	12	0	27
Sep 2021	10	11	0	21
Oct 2021	9	27	1	37
Nov 2021	17	23	2	42
Dec 2021	8	6	0	14
Jan 2022	17	13	0	30
Feb 2022	7	7	1	15
Mar 2022	10	9	0	19
Apr 2022	11	7	1	19
May 2022	14	8	0	22
Jun 2022	7	3	0	10
Jul 2022	5	3	0	8
Aug 2022	9	5	0	14
Sep 2022	6	8	0	14
Oct 2022	4	2	1	7
Nov 2022	11	8	0	19
Dec 2022	5	5	0	10
Jan 2023	7	12	1	20
Feb 2023	14	9	0	23
Mar 2023	8	12	0	20
Apr 2023	6	2	0	8
May 2023	31	7	0	38
Jun 2023	36	7	3	46
Jul 2023	35	5	1	41
Aug 2023	35	7	2	44
Sep 2023	42	4	0	46
Oct 2023	42	12	2	56
Nov 2023	25	1	0	26
Dec 2023	49	14	1	64
Jan 2024	38	11	1	50
Feb 2024	33	3	1	37
Mar 2024	39	10	1	50
Apr 2024	39	10	4	53
May 2024	13	12	3	28
Jun 2024	19	11	1	31
Jul 2024	16	6	2	24
Aug 2024	20	8	2	30
Sep 2024	15	8	0	23
Oct 2024	14	8	0	22
Nov 2024	10	4	2	16
Dec 2024	24	5	3	32
Jan 2025	18	5	3	26
Feb 2025	19	11	6	36
Mar 2025	19	9	0	28
Apr 2025	10	8	1	19
May 2025	23	5	0	28
Jun 2025	55	11	4	70
Jul 2025	33	15	1	49
Aug 2025	36	16	2	54
Sep 2025	56	14	2	72
Oct 2025	22	12	0	34
Nov 2025	19	18	3	40

Cumulative views and downloads (calculated since 14 Mar 2016)

Month	HTML	PDF	XML	Total
Mar 2016	130	58	0	188
Apr 2016	38	19	1	58
May 2016	22	8	0	30
Jun 2016	16	3	1	20
Jul 2016	15	8	0	23
Aug 2016	114	55	5	174
Sep 2016	18	11	0	29
Oct 2016	11	6	0	17
Nov 2016	9	5	0	14
Dec 2016	7	4	0	11
Jan 2017	17	16	1	34
Feb 2017	18	13	1	32
Mar 2017	21	9	2	32
Apr 2017	22	17	1	40
May 2017	25	15	2	42
Jun 2017	14	8	2	24
Jul 2017	17	9	0	26
Aug 2017	16	14	2	32
Sep 2017	8	8	0	16
Oct 2017	13	10	0	23
Nov 2017	13	15	1	29
Dec 2017	21	18	0	39
Jan 2018	12	14	0	26
Feb 2018	11	6	0	17
Mar 2018	9	12	0	21
Apr 2018	11	7	0	18
May 2018	15	11	1	27
Jun 2018	10	24	0	34
Jul 2018	14	12	1	27
Aug 2018	15	6	0	21
Sep 2018	9	9	3	21
Oct 2018	17	12	3	32
Nov 2018	25	13	0	38
Dec 2018	5	5	0	10
Jan 2019	6	7	1	14
Feb 2019	4	3	0	7
Mar 2019	4	13	0	17
Apr 2019	4	2	0	6
May 2019	7	5	0	12
Jun 2019	12	9	0	21
Jul 2019	8	13	0	21
Aug 2019	5	8	1	14
Sep 2019	3	6	0	9
Oct 2019	3	5	1	9
Nov 2019	3	3	0	6
Dec 2019	3	6	0	9
Jan 2020	10	12	0	22
Feb 2020	9	4	1	14
Mar 2020	3	9	0	12
Apr 2020	3	7	1	11
May 2020	4	1	0	5
Jun 2020	14	11	0	25
Jul 2020	17	12	6	35
Aug 2020	8	4	1	13
Sep 2020	10	6	0	16
Oct 2020	5	7	0	12
Nov 2020	10	9	1	20
Dec 2020	12	6	0	18
Jan 2021	16	10	0	26
Feb 2021	7	7	0	14
Mar 2021	10	12	0	22
Apr 2021	7	8	1	16
May 2021	9	10	1	20
Jun 2021	6	2	0	8
Jul 2021	9	8	0	17
Aug 2021	15	12	0	27
Sep 2021	10	11	0	21
Oct 2021	9	27	1	37
Nov 2021	17	23	2	42
Dec 2021	8	6	0	14
Jan 2022	17	13	0	30
Feb 2022	7	7	1	15
Mar 2022	10	9	0	19
Apr 2022	11	7	1	19
May 2022	14	8	0	22
Jun 2022	7	3	0	10
Jul 2022	5	3	0	8
Aug 2022	9	5	0	14
Sep 2022	6	8	0	14
Oct 2022	4	2	1	7
Nov 2022	11	8	0	19
Dec 2022	5	5	0	10
Jan 2023	7	12	1	20
Feb 2023	14	9	0	23
Mar 2023	8	12	0	20
Apr 2023	6	2	0	8
May 2023	31	7	0	38
Jun 2023	36	7	3	46
Jul 2023	35	5	1	41
Aug 2023	35	7	2	44
Sep 2023	42	4	0	46
Oct 2023	42	12	2	56
Nov 2023	25	1	0	26
Dec 2023	49	14	1	64
Jan 2024	38	11	1	50
Feb 2024	33	3	1	37
Mar 2024	39	10	1	50
Apr 2024	39	10	4	53
May 2024	13	12	3	28
Jun 2024	19	11	1	31
Jul 2024	16	6	2	24
Aug 2024	20	8	2	30
Sep 2024	15	8	0	23
Oct 2024	14	8	0	22
Nov 2024	10	4	2	16
Dec 2024	24	5	3	32
Jan 2025	18	5	3	26
Feb 2025	19	11	6	36
Mar 2025	19	9	0	28
Apr 2025	10	8	1	19
May 2025	23	5	0	28
Jun 2025	55	11	4	70
Jul 2025	33	15	1	49
Aug 2025	36	16	2	54
Sep 2025	56	14	2	72
Oct 2025	22	12	0	34
Nov 2025	19	18	3	40

Latest update: 28 Nov 2025

Download

Article (684 KB)
Full-text XML

Short summary

New reaction pathways of highly oxidized multifunctional organic compounds (HOMs) from the ozonolysis of the sesquiterpene (C₁₅H₂₄) beta-caryophyllene were elucidated based on experiments using isotopically labelled ozone and H/D exchange experiments. These new insights in reaction pathways of unsaturated RO₂ radicals are responsible for the production of about two-thirds of the detected HOMs from beta-caryophyllene and extend the knowledge of HOM formation mechanisms in the atmosphere.