Articles | Volume 16, issue 15
Atmos. Chem. Phys., 16, 9831–9845, 2016
https://doi.org/10.5194/acp-16-9831-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 16, 9831–9845, 2016
https://doi.org/10.5194/acp-16-9831-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
04 Aug 2016
Research article
| 04 Aug 2016
Different pathways of the formation of highly oxidized multifunctional organic compounds (HOMs) from the gas-phase ozonolysis of β-caryophyllene
Stefanie Richters et al.
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Cited
14 citations as recorded by crossref.
- Oxygenated products formed from OH-initiated reactions of trimethylbenzene: autoxidation and accretion Y. Wang et al. 10.5194/acp-20-9563-2020
- Effects of flask configuration on biofilm growth and metabolites of intertidal Cyanobacteria isolated from a mangrove forest M. Veerabadhran et al. 10.1111/jam.13761
- Highly Oxygenated Molecules from Atmospheric Autoxidation of Hydrocarbons: A Prominent Challenge for Chemical Kinetics Studies M. Ehn et al. 10.1002/kin.21130
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- endo-Cyclization of unsaturated RO2 radicals from the gas-phase ozonolysis of cyclohexadienes S. Richters et al. 10.1039/C7CC01350G
- Computational Comparison of Different Reagent Ions in the Chemical Ionization of Oxidized Multifunctional Compounds N. Hyttinen et al. 10.1021/acs.jpca.7b10015
- Theoretical insights into the gas/heterogeneous phase reactions of hydroxyl radicals with chlorophenols: Mechanism, kinetic and toxicity assessment B. Tang et al. 10.1016/j.scitotenv.2021.150974
- Experimental and theoretical study of the reactivity of a series of epoxides with chlorine atoms at 298 K C. Tovar et al. 10.1039/D0CP06033J
- Computational Comparison of Acetate and Nitrate Chemical Ionization of Highly Oxidized Cyclohexene Ozonolysis Intermediates and Products N. Hyttinen et al. 10.1021/acs.jpca.6b12654
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol F. Bianchi et al. 10.1021/acs.chemrev.8b00395
- Reactivity and Free Radical Chemistry of Lilac (Syringa vulgaris) Charcoal A. Nyombi et al. 10.1021/acs.energyfuels.8b03665
- Isomerization of Second-Generation Isoprene Peroxy Radicals: Epoxide Formation and Implications for Secondary Organic Aerosol Yields E. D’Ambro et al. 10.1021/acs.est.7b00460
- Connecting the Elementary Reaction Pathways of Criegee Intermediates to the Chemical Erosion of Squalene Interfaces during Ozonolysis N. Heine et al. 10.1021/acs.est.7b04197
13 citations as recorded by crossref.
- Oxygenated products formed from OH-initiated reactions of trimethylbenzene: autoxidation and accretion Y. Wang et al. 10.5194/acp-20-9563-2020
- Effects of flask configuration on biofilm growth and metabolites of intertidal Cyanobacteria isolated from a mangrove forest M. Veerabadhran et al. 10.1111/jam.13761
- Highly Oxygenated Molecules from Atmospheric Autoxidation of Hydrocarbons: A Prominent Challenge for Chemical Kinetics Studies M. Ehn et al. 10.1002/kin.21130
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- endo-Cyclization of unsaturated RO2 radicals from the gas-phase ozonolysis of cyclohexadienes S. Richters et al. 10.1039/C7CC01350G
- Computational Comparison of Different Reagent Ions in the Chemical Ionization of Oxidized Multifunctional Compounds N. Hyttinen et al. 10.1021/acs.jpca.7b10015
- Theoretical insights into the gas/heterogeneous phase reactions of hydroxyl radicals with chlorophenols: Mechanism, kinetic and toxicity assessment B. Tang et al. 10.1016/j.scitotenv.2021.150974
- Experimental and theoretical study of the reactivity of a series of epoxides with chlorine atoms at 298 K C. Tovar et al. 10.1039/D0CP06033J
- Computational Comparison of Acetate and Nitrate Chemical Ionization of Highly Oxidized Cyclohexene Ozonolysis Intermediates and Products N. Hyttinen et al. 10.1021/acs.jpca.6b12654
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol F. Bianchi et al. 10.1021/acs.chemrev.8b00395
- Reactivity and Free Radical Chemistry of Lilac (Syringa vulgaris) Charcoal A. Nyombi et al. 10.1021/acs.energyfuels.8b03665
- Isomerization of Second-Generation Isoprene Peroxy Radicals: Epoxide Formation and Implications for Secondary Organic Aerosol Yields E. D’Ambro et al. 10.1021/acs.est.7b00460
Saved (preprint)
Latest update: 02 Dec 2022
Short summary
New reaction pathways of highly oxidized multifunctional organic compounds (HOMs) from the ozonolysis of the sesquiterpene (C15H24) beta-caryophyllene were elucidated based on experiments using isotopically labelled ozone and H/D exchange experiments. These new insights in reaction pathways of unsaturated RO2 radicals are responsible for the production of about two-thirds of the detected HOMs from beta-caryophyllene and extend the knowledge of HOM formation mechanisms in the atmosphere.
New reaction pathways of highly oxidized multifunctional organic compounds (HOMs) from the...
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