Different pathways of the formation of highly oxidized multifunctional
organic compounds (HOMs) from the gas-phase ozonolysis of <i>β</i>-caryophyllene

Richters, Stefanie; Herrmann, Hartmut; Berndt, Torsten

doi:10.5194/acp-16-9831-2016

Articles | Volume 16, issue 15

https://doi.org/10.5194/acp-16-9831-2016

© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

https://doi.org/10.5194/acp-16-9831-2016

© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Articles | Volume 16, issue 15

Research article

|

04 Aug 2016

Research article |

| 04 Aug 2016

Different pathways of the formation of highly oxidized multifunctional organic compounds (HOMs) from the gas-phase ozonolysis of β-caryophyllene

Stefanie Richters, Hartmut Herrmann, and Torsten Berndt

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Cumulative views and downloads (calculated since 14 Mar 2016)

Month	HTML	PDF	XML	Total
Mar 2016	130	58	0	188
Apr 2016	38	19	1	58
May 2016	22	8	0	30
Jun 2016	16	3	1	20
Jul 2016	15	8	0	23
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Apr 2026	0

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Short summary

New reaction pathways of highly oxidized multifunctional organic compounds (HOMs) from the ozonolysis of the sesquiterpene (C₁₅H₂₄) beta-caryophyllene were elucidated based on experiments using isotopically labelled ozone and H/D exchange experiments. These new insights in reaction pathways of unsaturated RO₂ radicals are responsible for the production of about two-thirds of the detected HOMs from beta-caryophyllene and extend the knowledge of HOM formation mechanisms in the atmosphere.