Articles | Volume 16, issue 10
https://doi.org/10.5194/acp-16-6355-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-6355-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Formation of reactive nitrogen oxides from urban grime photochemistry
Alyson M. Baergen
Department of Chemistry, University of Toronto, Toronto, M56 3H6,
Canada
D. James Donaldson
CORRESPONDING AUTHOR
Department of Chemistry, University of Toronto, Toronto, M56 3H6,
Canada
Department of Physical and Environmental Science, University of
Toronto at Scarborough, Toronto, M1C 1A4, Canada
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Cited
42 citations as recorded by crossref.
- Comparison of seasonality of urban grime in three southern Ontario cities Y. Huang et al. 10.1139/cjc-2023-0143
- A model system to mimic environmentally active surface film roughness and hydrophobicity J. Grant & S. Shaw 10.1016/j.chemosphere.2017.07.068
- Resolving the Formation Mechanism of HONO via Ammonia-Promoted Photosensitized Conversion of Monomeric NO2 on Urban Glass Surfaces J. Liu et al. 10.1021/jacs.3c02067
- Matrix effect on surface-catalyzed photolysis of nitric acid C. Ye et al. 10.1038/s41598-018-37973-x
- Physical and chemical characterization of urban grime: An impact on the NO2 uptake coefficients and N-containing product compounds J. Liu et al. 10.1016/j.scitotenv.2022.155973
- The riddle of the forbidden UV absorption of aqueous nitrate: the oscillator strength of the n → π* transition in NO3− including second order vibronic coupling P. Pedersen et al. 10.1039/C9CP03774H
- Seasonality patterns and distinctive signature of latitude and population on ozone concentrations in Southern Ontario, Canada K. Leung et al. 10.1016/j.atmosenv.2020.118077
- Evaluation of Novel Routes for NOx Formation in Remote Regions C. Ye et al. 10.1021/acs.est.6b06441
- The unexpected effect of aqueous ion pairs on the forbidden n → π* transition in nitrate P. Pedersen et al. 10.1039/D0CP00958J
- Passively Sampled Environmental Films Show Geographic Variability and Host a Variety of Microorganisms J. Grant et al. 10.1021/acsearthspacechem.9b00234
- Light-Enhanced Heterogeneous Conversion of NO2 to HONO on Solid Films Consisting of Fluorene and Fluorene/Na2SO4: An Impact on Urban and Indoor Atmosphere J. Liu et al. 10.1021/acs.est.0c02627
- Heterogeneous reactions of mineral dust aerosol: implications for tropospheric oxidation capacity M. Tang et al. 10.5194/acp-17-11727-2017
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Physical and Chemical Morphology of Passively Sampled Environmental Films J. Grant et al. 10.1021/acsearthspacechem.8b00158
- Experimental and kinetic model evaluation of HONO production from surface nitrate photolysis Y. Wang et al. 10.1016/j.atmosenv.2022.119568
- Photoenhanced Uptake of NO2 and HONO Formation on Real Urban Grime J. Liu et al. 10.1021/acs.estlett.9b00308
- Combining Chamber Experiments and Model Simulations to Evaluate an Indoor HONO Source with Surface Photochemical Properties Y. Wang et al. 10.1155/2023/3605937
- Organic Composition, Chemistry, and Photochemistry of Urban Film in Leipzig, Germany S. Styler et al. 10.1021/acsearthspacechem.8b00087
- What Are the Differences between Two Environmental Films Sampled 1 km Apart? J. DeYoung et al. 10.1021/acsearthspacechem.1c00257
- Factors Influencing the Formation of Nitrous Acid from Photolysis of Particulate Nitrate R. Sommariva et al. 10.1021/acs.jpca.3c03853
- Urban Grime Photochemistry and Its Interaction with Air Pollutants NO, NO2, and O3: A Source for HONO and NO2 Impacting OH in Urban Areas F. Mothes et al. 10.1021/acsearthspacechem.3c00184
- Simultaneous Measurement of Gaseous HONO and NO2− in Solutions from Aqueous Nitrate Photolysis Mediated by Organics Y. Zhao et al. 10.3390/atmos15111279
- Isotopic evidence for dominant secondary production of HONO in near-ground wildfire plumes J. Chai et al. 10.5194/acp-21-13077-2021
- Seasonality of the Water-Soluble Inorganic Ion Composition and Water Uptake Behavior of Urban Grime A. Baergen & D. Donaldson 10.1021/acs.est.9b00532
- HONO Production from Gypsum Surfaces Following Exposure to NO2 and HNO3: Roles of Relative Humidity and Light Source S. Pandit et al. 10.1021/acs.est.1c01359
- Reduction and Photoreduction of NO2 in Humic Acid Films as a Source of HONO, ClNO, N2O, NOX, and Organic Nitrogen H. Ricker et al. 10.1021/acsearthspacechem.2c00282
- Significant influences of TiO2 crystal structures on NO2 and HONO emissions from the nitrates photolysis W. Xu et al. 10.1016/j.jes.2020.09.016
- Limitations in representation of physical processes prevent successful simulation of PM<sub>2.5</sub> during KORUS-AQ K. Travis et al. 10.5194/acp-22-7933-2022
- Daytime SO 2 chemistry on ubiquitous urban surfaces as a source of organic sulfur compounds in ambient air H. Deng et al. 10.1126/sciadv.abq6830
- Molecular Insights into Dissolved Organic Matter in Natural Dew Water: Biogrime Films on Leaf Surfaces M. Dibley et al. 10.1021/acsearthspacechem.1c00445
- Compilation and evaluation of gas phase diffusion coefficients of halogenated organic compounds W. Gu et al. 10.1098/rsos.171936
- Quantifying Nitrous Acid Formation Mechanisms Using Measured Vertical Profiles During the CalNex 2010 Campaign and 1D Column Modeling K. Tuite et al. 10.1029/2021JD034689
- Sources of nitrous acid (HONO) in the upper boundary layer and lower free troposphere of the North China Plain: insights from the Mount Tai Observatory Y. Jiang et al. 10.5194/acp-20-12115-2020
- Reactive Uptake of Gas-Phase NO2 by Urban Road Dust in the Dark Z. Golay et al. 10.1021/acsearthspacechem.2c00221
- Enhanced wintertime oxidation of VOCs via sustained radical sources in the urban atmosphere R. Sommariva et al. 10.1016/j.envpol.2021.116563
- Homogeneous and heterogeneous photolysis of nitrate in the atmosphere: state of the science, current research needs, and future prospects Y. Cao et al. 10.1007/s11783-023-1648-6
- Indoor Lighting Releases Gas Phase Nitrogen Oxides from Indoor Painted Surfaces H. Schwartz-Narbonne et al. 10.1021/acs.estlett.8b00685
- Physical and Chemical Characterization of Urban Grime Sampled from Two Cities C. Kroptavich et al. 10.1021/acsearthspacechem.0c00192
- Nitrate Photochemistry at the Air–Ice Interface and in Other Ice Reservoirs A. McFall et al. 10.1021/acs.est.8b00095
- Evidence for renoxification in the tropical marine boundary layer C. Reed et al. 10.5194/acp-17-4081-2017
- Measurement of heterogeneous uptake of NO2 on inorganic particles, sea water and urban grime C. Yu et al. 10.1016/j.jes.2021.01.018
- Water uptake by indoor surface films H. Schwartz-Narbonne & D. Donaldson 10.1038/s41598-019-47590-x
42 citations as recorded by crossref.
- Comparison of seasonality of urban grime in three southern Ontario cities Y. Huang et al. 10.1139/cjc-2023-0143
- A model system to mimic environmentally active surface film roughness and hydrophobicity J. Grant & S. Shaw 10.1016/j.chemosphere.2017.07.068
- Resolving the Formation Mechanism of HONO via Ammonia-Promoted Photosensitized Conversion of Monomeric NO2 on Urban Glass Surfaces J. Liu et al. 10.1021/jacs.3c02067
- Matrix effect on surface-catalyzed photolysis of nitric acid C. Ye et al. 10.1038/s41598-018-37973-x
- Physical and chemical characterization of urban grime: An impact on the NO2 uptake coefficients and N-containing product compounds J. Liu et al. 10.1016/j.scitotenv.2022.155973
- The riddle of the forbidden UV absorption of aqueous nitrate: the oscillator strength of the n → π* transition in NO3− including second order vibronic coupling P. Pedersen et al. 10.1039/C9CP03774H
- Seasonality patterns and distinctive signature of latitude and population on ozone concentrations in Southern Ontario, Canada K. Leung et al. 10.1016/j.atmosenv.2020.118077
- Evaluation of Novel Routes for NOx Formation in Remote Regions C. Ye et al. 10.1021/acs.est.6b06441
- The unexpected effect of aqueous ion pairs on the forbidden n → π* transition in nitrate P. Pedersen et al. 10.1039/D0CP00958J
- Passively Sampled Environmental Films Show Geographic Variability and Host a Variety of Microorganisms J. Grant et al. 10.1021/acsearthspacechem.9b00234
- Light-Enhanced Heterogeneous Conversion of NO2 to HONO on Solid Films Consisting of Fluorene and Fluorene/Na2SO4: An Impact on Urban and Indoor Atmosphere J. Liu et al. 10.1021/acs.est.0c02627
- Heterogeneous reactions of mineral dust aerosol: implications for tropospheric oxidation capacity M. Tang et al. 10.5194/acp-17-11727-2017
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Physical and Chemical Morphology of Passively Sampled Environmental Films J. Grant et al. 10.1021/acsearthspacechem.8b00158
- Experimental and kinetic model evaluation of HONO production from surface nitrate photolysis Y. Wang et al. 10.1016/j.atmosenv.2022.119568
- Photoenhanced Uptake of NO2 and HONO Formation on Real Urban Grime J. Liu et al. 10.1021/acs.estlett.9b00308
- Combining Chamber Experiments and Model Simulations to Evaluate an Indoor HONO Source with Surface Photochemical Properties Y. Wang et al. 10.1155/2023/3605937
- Organic Composition, Chemistry, and Photochemistry of Urban Film in Leipzig, Germany S. Styler et al. 10.1021/acsearthspacechem.8b00087
- What Are the Differences between Two Environmental Films Sampled 1 km Apart? J. DeYoung et al. 10.1021/acsearthspacechem.1c00257
- Factors Influencing the Formation of Nitrous Acid from Photolysis of Particulate Nitrate R. Sommariva et al. 10.1021/acs.jpca.3c03853
- Urban Grime Photochemistry and Its Interaction with Air Pollutants NO, NO2, and O3: A Source for HONO and NO2 Impacting OH in Urban Areas F. Mothes et al. 10.1021/acsearthspacechem.3c00184
- Simultaneous Measurement of Gaseous HONO and NO2− in Solutions from Aqueous Nitrate Photolysis Mediated by Organics Y. Zhao et al. 10.3390/atmos15111279
- Isotopic evidence for dominant secondary production of HONO in near-ground wildfire plumes J. Chai et al. 10.5194/acp-21-13077-2021
- Seasonality of the Water-Soluble Inorganic Ion Composition and Water Uptake Behavior of Urban Grime A. Baergen & D. Donaldson 10.1021/acs.est.9b00532
- HONO Production from Gypsum Surfaces Following Exposure to NO2 and HNO3: Roles of Relative Humidity and Light Source S. Pandit et al. 10.1021/acs.est.1c01359
- Reduction and Photoreduction of NO2 in Humic Acid Films as a Source of HONO, ClNO, N2O, NOX, and Organic Nitrogen H. Ricker et al. 10.1021/acsearthspacechem.2c00282
- Significant influences of TiO2 crystal structures on NO2 and HONO emissions from the nitrates photolysis W. Xu et al. 10.1016/j.jes.2020.09.016
- Limitations in representation of physical processes prevent successful simulation of PM<sub>2.5</sub> during KORUS-AQ K. Travis et al. 10.5194/acp-22-7933-2022
- Daytime SO 2 chemistry on ubiquitous urban surfaces as a source of organic sulfur compounds in ambient air H. Deng et al. 10.1126/sciadv.abq6830
- Molecular Insights into Dissolved Organic Matter in Natural Dew Water: Biogrime Films on Leaf Surfaces M. Dibley et al. 10.1021/acsearthspacechem.1c00445
- Compilation and evaluation of gas phase diffusion coefficients of halogenated organic compounds W. Gu et al. 10.1098/rsos.171936
- Quantifying Nitrous Acid Formation Mechanisms Using Measured Vertical Profiles During the CalNex 2010 Campaign and 1D Column Modeling K. Tuite et al. 10.1029/2021JD034689
- Sources of nitrous acid (HONO) in the upper boundary layer and lower free troposphere of the North China Plain: insights from the Mount Tai Observatory Y. Jiang et al. 10.5194/acp-20-12115-2020
- Reactive Uptake of Gas-Phase NO2 by Urban Road Dust in the Dark Z. Golay et al. 10.1021/acsearthspacechem.2c00221
- Enhanced wintertime oxidation of VOCs via sustained radical sources in the urban atmosphere R. Sommariva et al. 10.1016/j.envpol.2021.116563
- Homogeneous and heterogeneous photolysis of nitrate in the atmosphere: state of the science, current research needs, and future prospects Y. Cao et al. 10.1007/s11783-023-1648-6
- Indoor Lighting Releases Gas Phase Nitrogen Oxides from Indoor Painted Surfaces H. Schwartz-Narbonne et al. 10.1021/acs.estlett.8b00685
- Physical and Chemical Characterization of Urban Grime Sampled from Two Cities C. Kroptavich et al. 10.1021/acsearthspacechem.0c00192
- Nitrate Photochemistry at the Air–Ice Interface and in Other Ice Reservoirs A. McFall et al. 10.1021/acs.est.8b00095
- Evidence for renoxification in the tropical marine boundary layer C. Reed et al. 10.5194/acp-17-4081-2017
- Measurement of heterogeneous uptake of NO2 on inorganic particles, sea water and urban grime C. Yu et al. 10.1016/j.jes.2021.01.018
- Water uptake by indoor surface films H. Schwartz-Narbonne & D. Donaldson 10.1038/s41598-019-47590-x
Discussed (final revised paper)
Discussed (preprint)
Latest update: 21 Nov 2024
Short summary
"Urban grime" films form from the deposition of atmospheric constituents on urban surfaces exposed to the atmosphere. An important component is nitrate, which is thought to represent a final loss channel of nitrogen oxides from the atmosphere. In this study we show that nitrate photolysis on grime is a significant loss process and gives rise to gas phase nitrogen oxides, effectively recycling them to the atmosphere and thus impacting local ozone levels.
"Urban grime" films form from the deposition of atmospheric constituents on urban surfaces...
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Final-revised paper
Preprint