Articles | Volume 16, issue 2
https://doi.org/10.5194/acp-16-573-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-573-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
19 Jan 2016
Research article |
| 19 Jan 2016
Reactive nitrogen partitioning and its relationship to winter ozone events in Utah
R. J. Wild
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
P. M. Edwards
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
now at: Department of Chemistry, University of York, York, YO10 5DD, UK
T. S. Bates
Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration, Seattle, Washington 98115, USA
Joint Institute for the Study of the Atmosphere and Oceans, University of Washington, Seattle, Washington 98195, USA
R. C. Cohen
Department of Chemistry, University of California, Berkeley, California 94720, USA
J. A. de Gouw
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
W. P. Dubé
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
J. B. Gilman
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
J. Holloway
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
J. Kercher
Department of Chemistry, Hiram College, Hiram, Ohio 44234, USA
A. R. Koss
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
L. Lee
Department of Chemistry, University of California, Berkeley, California 94720, USA
B. M. Lerner
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
R. McLaren
Centre for Atmospheric Chemistry and Chemistry Department, York University, Toronto, Ontario, M3J 1P3, Canada
P. K. Quinn
Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration, Seattle, Washington 98115, USA
J. M. Roberts
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
Department of Atmospheric and Oceanic Sciences, University of California, Los Angeles, California 90095, USA
J. A. Thornton
Department of Atmospheric Sciences, University of Washington, Seattle, Washington 98195, USA
P. R. Veres
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
C. Warneke
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
E. Williams
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
C. J. Young
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
now at: Department of Chemistry, Memorial University of Newfoundland, St. John's, Newfoundland, A1B 3X7, Canada
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
K. J. Zarzana
Cooperative Institute for Research in the Environmental Sciences, University of Colorado, Boulder, Colorado 80309, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, Colorado 80305, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309 USA
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Cited
23 citations as recorded by crossref.
- Bioavailable iron production in airborne mineral dust: Controls by chemical composition and solar flux E. Hettiarachchi et al. 10.1016/j.atmosenv.2019.02.037
- ClNO2 Yields From Aircraft Measurements During the 2015 WINTER Campaign and Critical Evaluation of the Current Parameterization E. McDuffie et al. 10.1029/2018JD029358
- Twenty-Year Review of Outdoor Air Quality in Utah, USA C. Flowerday et al. 10.3390/atmos14101496
- NOx Lifetime and NOy Partitioning During WINTER H. Kenagy et al. 10.1029/2018JD028736
- Reactive nitrogen around the Arabian Peninsula and in the Mediterranean Sea during the 2017 AQABA ship campaign N. Friedrich et al. 10.5194/acp-21-7473-2021
- The magnitude of the snow-sourced reactive nitrogen flux to the boundary layer in the Uintah Basin, Utah, USA M. Zatko et al. 10.5194/acp-16-13837-2016
- Reactive oxidized nitrogen speciation and partitioning in urban and rural New York State M. Ninneman et al. 10.1080/10962247.2020.1837289
- Wintertime haze and ozone at Dinosaur National Monument A. Prenni et al. 10.1080/10962247.2022.2048922
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Kinetics of the reactions of NO3 radical with alkanes L. Zhou et al. 10.1039/C8CP07675H
- Local and Regional Contributions to Tropospheric Ozone Concentrations C. Flowerday et al. 10.3390/atmos14081262
- Evaluation of the accuracy of thermal dissociation CRDS and LIF techniques for atmospheric measurement of reactive nitrogen species C. Womack et al. 10.5194/amt-10-1911-2017
- An Odd Oxygen Framework for Wintertime Ammonium Nitrate Aerosol Pollution in Urban Areas: NOx and VOC Control as Mitigation Strategies C. Womack et al. 10.1029/2019GL082028
- Wintertime N2O5 uptake coefficients over the North China Plain H. Wang et al. 10.1016/j.scib.2020.02.006
- Winter ClNO2 formation in the region of fresh anthropogenic emissions: seasonal variability and insights into daytime peaks in northern China M. Xia et al. 10.5194/acp-21-15985-2021
- Stronger secondary pollution processes despite decrease in gaseous precursors: A comparative analysis of summer 2020 and 2019 in Beijing H. Li et al. 10.1016/j.envpol.2021.116923
- Observational assessment of the role of nocturnal residual-layer chemistry in determining daytime surface particulate nitrate concentrations G. Prabhakar et al. 10.5194/acp-17-14747-2017
- Simulating indoor inorganic aerosols of outdoor origin with the inorganic aerosol thermodynamic equilibrium model ISORROPIA B. Berman et al. 10.1111/ina.13075
- Local Arctic Air Pollution: A Neglected but Serious Problem J. Schmale et al. 10.1029/2018EF000952
- Cavity enhanced spectroscopy for measurement of nitrogen oxides in the Anthropocene: results from the Seoul tower during MAPS 2015 S. Brown et al. 10.1039/C7FD00001D
- Heterogeneous N2O5 Uptake During Winter: Aircraft Measurements During the 2015 WINTER Campaign and Critical Evaluation of Current Parameterizations E. McDuffie et al. 10.1002/2018JD028336
- Characterization of haze pollution in Zibo, China: Temporal series, secondary species formation, and PMx distribution H. Li et al. 10.1016/j.chemosphere.2021.131807
- Absolute determination of chemical kinetic rate constants by optical tracking the reaction on the second timescale using cavity-enhanced absorption spectroscopy H. Yi et al. 10.1039/D2CP00206J
23 citations as recorded by crossref.
- Bioavailable iron production in airborne mineral dust: Controls by chemical composition and solar flux E. Hettiarachchi et al. 10.1016/j.atmosenv.2019.02.037
- ClNO2 Yields From Aircraft Measurements During the 2015 WINTER Campaign and Critical Evaluation of the Current Parameterization E. McDuffie et al. 10.1029/2018JD029358
- Twenty-Year Review of Outdoor Air Quality in Utah, USA C. Flowerday et al. 10.3390/atmos14101496
- NOx Lifetime and NOy Partitioning During WINTER H. Kenagy et al. 10.1029/2018JD028736
- Reactive nitrogen around the Arabian Peninsula and in the Mediterranean Sea during the 2017 AQABA ship campaign N. Friedrich et al. 10.5194/acp-21-7473-2021
- The magnitude of the snow-sourced reactive nitrogen flux to the boundary layer in the Uintah Basin, Utah, USA M. Zatko et al. 10.5194/acp-16-13837-2016
- Reactive oxidized nitrogen speciation and partitioning in urban and rural New York State M. Ninneman et al. 10.1080/10962247.2020.1837289
- Wintertime haze and ozone at Dinosaur National Monument A. Prenni et al. 10.1080/10962247.2022.2048922
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Kinetics of the reactions of NO3 radical with alkanes L. Zhou et al. 10.1039/C8CP07675H
- Local and Regional Contributions to Tropospheric Ozone Concentrations C. Flowerday et al. 10.3390/atmos14081262
- Evaluation of the accuracy of thermal dissociation CRDS and LIF techniques for atmospheric measurement of reactive nitrogen species C. Womack et al. 10.5194/amt-10-1911-2017
- An Odd Oxygen Framework for Wintertime Ammonium Nitrate Aerosol Pollution in Urban Areas: NOx and VOC Control as Mitigation Strategies C. Womack et al. 10.1029/2019GL082028
- Wintertime N2O5 uptake coefficients over the North China Plain H. Wang et al. 10.1016/j.scib.2020.02.006
- Winter ClNO2 formation in the region of fresh anthropogenic emissions: seasonal variability and insights into daytime peaks in northern China M. Xia et al. 10.5194/acp-21-15985-2021
- Stronger secondary pollution processes despite decrease in gaseous precursors: A comparative analysis of summer 2020 and 2019 in Beijing H. Li et al. 10.1016/j.envpol.2021.116923
- Observational assessment of the role of nocturnal residual-layer chemistry in determining daytime surface particulate nitrate concentrations G. Prabhakar et al. 10.5194/acp-17-14747-2017
- Simulating indoor inorganic aerosols of outdoor origin with the inorganic aerosol thermodynamic equilibrium model ISORROPIA B. Berman et al. 10.1111/ina.13075
- Local Arctic Air Pollution: A Neglected but Serious Problem J. Schmale et al. 10.1029/2018EF000952
- Cavity enhanced spectroscopy for measurement of nitrogen oxides in the Anthropocene: results from the Seoul tower during MAPS 2015 S. Brown et al. 10.1039/C7FD00001D
- Heterogeneous N2O5 Uptake During Winter: Aircraft Measurements During the 2015 WINTER Campaign and Critical Evaluation of Current Parameterizations E. McDuffie et al. 10.1002/2018JD028336
- Characterization of haze pollution in Zibo, China: Temporal series, secondary species formation, and PMx distribution H. Li et al. 10.1016/j.chemosphere.2021.131807
- Absolute determination of chemical kinetic rate constants by optical tracking the reaction on the second timescale using cavity-enhanced absorption spectroscopy H. Yi et al. 10.1039/D2CP00206J
Saved (preprint)
Latest update: 30 Jun 2025
Short summary
High wintertime ozone levels have been observed in the Uintah Basin, Utah, a sparsely populated rural region with intensive oil and gas operations. The reactive nitrogen budget plays an important role in tropospheric ozone formation, and we find that nighttime chemistry has a large effect on its partitioning. Much of the oxidation of reactive nitrogen during a high-ozone year occurred via heterogeneous uptake onto aerosol at night, keeping NOx at concentrations comparable to a low-ozone year.
High wintertime ozone levels have been observed in the Uintah Basin, Utah, a sparsely populated...
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