Articles | Volume 16, issue 9
https://doi.org/10.5194/acp-16-5595-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-5595-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
04 May 2016
Research article |
| 04 May 2016
Photochemical degradation of isoprene-derived 4,1-nitrooxy enal
Fulizi Xiong
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Carlos H. Borca
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Lyudmila V. Slipchenko
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Paul B. Shepson
CORRESPONDING AUTHOR
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Department of Earth, Atmospheric and Planetary Sciences, Purdue
University, West Lafayette, IN, USA
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Cited
24 citations as recorded by crossref.
- The production and hydrolysis of organic nitrates from OH radical oxidation of β-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Photolysis of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.jpca.2c04307
- Gas-Phase Reactions of Isoprene and Its Major Oxidation Products P. Wennberg et al. 10.1021/acs.chemrev.7b00439
- Evaluating the Impact of Chemical Complexity and Horizontal Resolution on Tropospheric Ozone Over the Conterminous US With a Global Variable Resolution Chemistry Model R. Schwantes et al. 10.1029/2021MS002889
- The photolysis of α-hydroperoxycarbonyls Z. Liu et al. 10.1039/C7CP08421H
- Key Role of NO3 Radicals in the Production of Isoprene Nitrates and Nitrooxyorganosulfates in Beijing J. Hamilton et al. 10.1021/acs.est.0c05689
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- Photolysis and oxidation by OH radicals of two carbonyl nitrates: 4-nitrooxy-2-butanone and 5-nitrooxy-2-pentanone B. Picquet-Varrault et al. 10.5194/acp-20-487-2020
- Differences in BVOC oxidation and SOA formation above and below the forest canopy B. Schulze et al. 10.5194/acp-17-1805-2017
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
- Chemistry and deposition in the Model of Atmospheric composition at Global and Regional scales using Inversion Techniques for Trace gas Emissions (MAGRITTE v1.1) – Part 1: Chemical mechanism J. Müller et al. 10.5194/gmd-12-2307-2019
- A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates A. Zare et al. 10.5194/acp-18-15419-2018
- The lifetime of nitrogen oxides in an isoprene-dominated forest P. Romer et al. 10.5194/acp-16-7623-2016
- Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol N. Ng et al. 10.5194/acp-17-2103-2017
- The acid-catalyzed hydrolysis of an α-pinene-derived organic nitrate: kinetics, products, reaction mechanisms, and atmospheric impact J. Rindelaub et al. 10.5194/acp-16-15425-2016
- Alkyl nitrates in the boreal forest: formation via the NO3-, OH- and O3-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Gas-Phase Photolysis and Photo-Oxidation of Isoprene-Derived Atmospherically Relevant Hydroxy Nitrates R. Verma et al. 10.1021/acsestair.4c00010
- The changing role of organic nitrates in the removal and transport of NOx P. Romer Present et al. 10.5194/acp-20-267-2020
- Decadal changes in summertime reactive oxidized nitrogen and surface ozone over the Southeast United States J. Li et al. 10.5194/acp-18-2341-2018
- Nitrate radical oxidation of γ-terpinene: hydroxy nitrate, total organic nitrate, and secondary organic aerosol yields J. Slade et al. 10.5194/acp-17-8635-2017
- Measurement of isoprene nitrates by GCMS G. Mills et al. 10.5194/amt-9-4533-2016
24 citations as recorded by crossref.
- The production and hydrolysis of organic nitrates from OH radical oxidation of β-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Photolysis of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.jpca.2c04307
- Gas-Phase Reactions of Isoprene and Its Major Oxidation Products P. Wennberg et al. 10.1021/acs.chemrev.7b00439
- Evaluating the Impact of Chemical Complexity and Horizontal Resolution on Tropospheric Ozone Over the Conterminous US With a Global Variable Resolution Chemistry Model R. Schwantes et al. 10.1029/2021MS002889
- The photolysis of α-hydroperoxycarbonyls Z. Liu et al. 10.1039/C7CP08421H
- Key Role of NO3 Radicals in the Production of Isoprene Nitrates and Nitrooxyorganosulfates in Beijing J. Hamilton et al. 10.1021/acs.est.0c05689
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- Photolysis and oxidation by OH radicals of two carbonyl nitrates: 4-nitrooxy-2-butanone and 5-nitrooxy-2-pentanone B. Picquet-Varrault et al. 10.5194/acp-20-487-2020
- Differences in BVOC oxidation and SOA formation above and below the forest canopy B. Schulze et al. 10.5194/acp-17-1805-2017
- Synthetic strategies for oxidation products from biogenic volatile organic compounds in the atmosphere: A review S. Gagan et al. 10.1016/j.atmosenv.2023.120017
- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
- Chemistry and deposition in the Model of Atmospheric composition at Global and Regional scales using Inversion Techniques for Trace gas Emissions (MAGRITTE v1.1) – Part 1: Chemical mechanism J. Müller et al. 10.5194/gmd-12-2307-2019
- A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates A. Zare et al. 10.5194/acp-18-15419-2018
- The lifetime of nitrogen oxides in an isoprene-dominated forest P. Romer et al. 10.5194/acp-16-7623-2016
- Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol N. Ng et al. 10.5194/acp-17-2103-2017
- The acid-catalyzed hydrolysis of an α-pinene-derived organic nitrate: kinetics, products, reaction mechanisms, and atmospheric impact J. Rindelaub et al. 10.5194/acp-16-15425-2016
- Alkyl nitrates in the boreal forest: formation via the NO3-, OH- and O3-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Gas-Phase Photolysis and Photo-Oxidation of Isoprene-Derived Atmospherically Relevant Hydroxy Nitrates R. Verma et al. 10.1021/acsestair.4c00010
- The changing role of organic nitrates in the removal and transport of NOx P. Romer Present et al. 10.5194/acp-20-267-2020
- Decadal changes in summertime reactive oxidized nitrogen and surface ozone over the Southeast United States J. Li et al. 10.5194/acp-18-2341-2018
- Nitrate radical oxidation of γ-terpinene: hydroxy nitrate, total organic nitrate, and secondary organic aerosol yields J. Slade et al. 10.5194/acp-17-8635-2017
- Measurement of isoprene nitrates by GCMS G. Mills et al. 10.5194/amt-9-4533-2016
Saved (final revised paper)
Latest update: 13 Jul 2025
Short summary
Here we report on a detailed study of the photochemistry and fate of a nitrooxy enal that is produced from the reaction of NO3 with isoprene. We synthesized the 4,1-nitrooxy enal, purified it, and measured the O3 and OH reaction rate constants, and determined the atmospheric photodissociation rate constant for specified radiation conditions. The determined fast photolysis rate and high reactivity toward OH lead to a lifetime of less than 1 hour, with photolysis being a dominant daytime sink.
Here we report on a detailed study of the photochemistry and fate of a nitrooxy enal that is...
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