Articles | Volume 16, issue 6
https://doi.org/10.5194/acp-16-4023-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-4023-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
29 Mar 2016
Research article |
| 29 Mar 2016
Direct measurements of OH and other product yields from the HO2 + CH3C(O)O2 reaction
Frank A. F. Winiberg
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
now at: JPL, Pasadena, CA 91106, USA
Terry J. Dillon
Max Planck Institute for Chemistry, Division of Atmospheric Chemistry,
55128 Mainz, Germany
Wolfson Atmospheric Chemistry Laboratories, Dept. of Chemistry,
University of York, York, YO10 5DD, UK
Stephanie C. Orr
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Christoph B. M Groß
Max Planck Institute for Chemistry, Division of Atmospheric Chemistry,
55128 Mainz, Germany
now at: SCHOTT AG, Physical Analytics, Hattenbergstraße 10, 55122,
Mainz, Germany
Iustinian Bejan
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Faculty of Chemistry and Integrated Centre for Environmental
Science Studies in the North-East Development Region – CERNESIM, University
Al. I. Cuza, Iasi, Romania
Charlotte A. Brumby
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Matthew J. Evans
Wolfson Atmospheric Chemistry Laboratories, Dept. of Chemistry,
University of York, York, YO10 5DD, UK
National Centre for Atmospheric Science, University of York, YO10, 5DD,
UK
Shona C. Smith
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Dwayne E. Heard
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, LS2
9JT, UK
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, LS2
9JT, UK
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45 citations as recorded by crossref.
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- Kinetics and Product Branching Ratio Study of the CH3O2 Self-Reaction in the Highly Instrumented Reactor for Atmospheric Chemistry L. Onel et al. 10.1021/acs.jpca.2c04968
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- Temperature-Dependent, Site-Specific Rate Coefficients for the Reaction of OH (OD) with Methyl Formate Isotopologues via Experimental and Theoretical Studies N. Robertson et al. 10.1021/acs.jpca.4c02524
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al. 10.1021/acs.est.4c00742
- Atmospheric fate of two relevant unsaturated ketoethers: kinetics, products and mechanisms for the reaction of hydroxyl radicals with (<i>E</i>)-4-methoxy-3-buten-2-one and (1<i>E</i>)-1-methoxy-2-methyl-1-penten-3-one R. Gibilisco et al. 10.5194/acp-20-8939-2020
- Liquid-phase oxidation of cyclohexane. Elementary steps in the developed process, reactivity, catalysis, and problems of conversion and selectivity A. Perkel et al. 10.1007/s11172-018-2288-z
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- Endogenous ozone as a regular reactive oxygen species in (patho) physiology A. Onyango 10.1016/j.arres.2023.100075
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- Computational and Experimental Investigation of the Detection of HO2 Radical and the Products of Its Reaction with Cyclohexene Ozonolysis Derived RO2 Radicals by an Iodide-Based Chemical Ionization Mass Spectrometer S. Iyer et al. 10.1021/acs.jpca.7b01588
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- Kinetics of the photolysis and OH reaction of 4-hydroxy-4-methyl-2-pentanone: Atmospheric implications L. Aslan et al. 10.1016/j.atmosenv.2016.11.059
- The absorption spectrum and absolute absorption cross sections of acetylperoxy radicals, CH3C(O)O2 in the near IR M. Rolletter et al. 10.1016/j.jqsrt.2020.106877
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Saved (preprint)
Latest update: 13 Dec 2024
Short summary
OH radicals are important intermediates in the atmosphere, and the high concentrations observed in tropical regions are yet to be fully explained. Radical-radical reactions such as the title reaction can contribute to OH formation. This is the most fully comprehensive study of the CH3C(O)O2 + HO2 reaction with direct observation of products in all reaction channels. The implications of the new measurements on OH, PAN and NOx concentrations are considered via global models.
OH radicals are important intermediates in the atmosphere, and the high concentrations observed...
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