Articles | Volume 16, issue 1
https://doi.org/10.5194/acp-16-293-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-16-293-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
18 Jan 2016
Research article |
| 18 Jan 2016
Hygroscopicity of nanoparticles produced from homogeneous nucleation in the CLOUD experiments
J. Kim
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
now at: Arctic research center, Korea Polar Research Institute, Incheon, South Korea
L. Ahlm
Department of Applied Environmental Science, Stockholm University, Stockholm, Sweden
T. Yli-Juuti
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
M. Lawler
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
National Centre for Atmospheric Research, Boulder, CO 80305, USA
H. Keskinen
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
now at: Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
J. Tröstl
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
S. Schobesberger
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
now at: Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA
J. Duplissy
Helsinki Institute of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
A. Amorim
CENTRA-SIM, University of Lisbon, Lisbon, Portugal
F. Bianchi
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
N. M. Donahue
Carnegie Mellon University, Center for Atmospheric Particle Studies, 5000 Forbes Avenue, Pittsburgh, PA 15213, USA
R. C. Flagan
California Institute of Technology, 210-41, Pasadena, CA 91125, USA
J. Hakala
Division of Atmospheric Sciences, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
M. Heinritzi
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
University of Innsbruck, Institute for Ion and Applied Physics, 6020 Innsbruck, Austria
T. Jokinen
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
A. Kürten
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
A. Laaksonen
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Finnish Meteorological Institute, PL 501, 00101 Helsinki, Finland
K. Lehtipalo
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
P. Miettinen
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
T. Petäjä
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
M. P. Rissanen
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
L. Rondo
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
K. Sengupta
University of Leeds, School of Earth and Environment, Leeds LS2 9JT, UK
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
A. Tomé
CENTRA-SIM, University of Lisbon, Lisbon, Portugal
University of Beira Interior, Beira, Portugal
C. Williamson
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
D. Wimmer
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
P. M. Winkler
Faculty of Physics, University of Vienna, Boltzmanngasse 5, 1090 Vienna, Austria
S. Ehrhart
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
CERN, 1211 Geneva, Switzerland
P. Ye
Carnegie Mellon University, Center for Atmospheric Particle Studies, 5000 Forbes Avenue, Pittsburgh, PA 15213, USA
J. Kirkby
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
CERN, 1211 Geneva, Switzerland
J. Curtius
Goethe University of Frankfurt, Institute for Atmospheric and Environmental Sciences, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
U. Baltensperger
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
M. Kulmala
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
K. E. J. Lehtinen
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Finnish Meteorological Institute, Kuopio Unit, Kuopio, Finland
J. N. Smith
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
National Centre for Atmospheric Research, Boulder, CO 80305, USA
I. Riipinen
Department of Applied Environmental Science, Stockholm University, Stockholm, Sweden
A. Virtanen
CORRESPONDING AUTHOR
Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
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Cited
29 citations as recorded by crossref.
- Electrospray Ionization–Based Synthesis and Validation of Amine-Sulfuric Acid Clusters of Relevance to Atmospheric New Particle Formation S. Waller et al. 10.1007/s13361-019-02322-3
- Enhanced growth rate of atmospheric particles from sulfuric acid D. Stolzenburg et al. 10.5194/acp-20-7359-2020
- Establishing the structural motifs present in small ammonium and aminium bisulfate clusters of relevance to atmospheric new particle formation J. Kreinbihl et al. 10.1063/5.0015094
- Hygroscopicity of ultrafine particles containing ammonium/alkylaminium sulfates: A Köhler model investigation with correction of surface tension L. Liu & H. Li 10.1016/j.atmosenv.2022.119500
- Size-Resolved Chemical Composition of Sub-20 nm Particles from Methanesulfonic Acid Reactions with Methylamine and Ammonia V. Perraud et al. 10.1021/acsearthspacechem.0c00120
- Contribution of reaction of atmospheric amine with sulfuric acid to mixing particle formation from clay mineral W. Zhang et al. 10.1016/j.scitotenv.2022.153336
- Unexpectedly acidic nanoparticles formed in dimethylamine–ammonia–sulfuric-acid nucleation experiments at CLOUD M. Lawler et al. 10.5194/acp-16-13601-2016
- Size- and Composition-Dependent Hygroscopic Growth of Sub-20 nm Atmospherically Relevant Particles: Implications for New Particle Survival J. Yishake et al. 10.1021/acs.est.5c00068
- Measurement of atmospheric nanoparticles: Bridging the gap between gas-phase molecules and larger particles C. Peng et al. 10.1016/j.jes.2022.03.006
- Review of online measurement techniques for chemical composition of atmospheric clusters and sub-20 nm particles K. Zhang et al. 10.3389/fenvs.2022.937006
- 100 Years of Progress in Cloud Physics, Aerosols, and Aerosol Chemistry Research S. Kreidenweis et al. 10.1175/AMSMONOGRAPHS-D-18-0024.1
- Molecular-level insight into uptake of dimethylamine on hydrated nitric acid clusters A. Pysanenko et al. 10.1039/D2EA00094F
- The hygroscopic properties of biomass burning aerosol from Eucalyptus and cow dung under different combustion conditions M. Mouton et al. 10.1080/02786826.2023.2198587
- Hygroscopicity of organic surrogate compounds from biomass burning and their effect on the efflorescence of ammonium sulfate in mixed aerosol particles T. Lei et al. 10.5194/acp-18-1045-2018
- Microscopic Insights Into the Formation of Methanesulfonic Acid–Methylamine–Ammonia Particles Under Acid-Rich Conditions M. Liu et al. 10.3389/fevo.2022.875585
- Unexpected Hygroscopic Behaviors of Individual Sub-50 Nm Nano3 Nanoparticles Observed by in Situ Atomic Force Microscopy Z. Ying et al. 10.2139/ssrn.4118444
- Space‐Borne Estimation of Volcanic Sulfate Aerosol Lifetime C. Li & R. Cohen 10.1029/2020JD033883
- An Experimental and Modeling Study of Nanoparticle Formation and Growth from Dimethylamine and Nitric Acid S. Chee et al. 10.1021/acs.jpca.9b03326
- Application of remote sensing techniques to study aerosol water vapour uptake in a real atmosphere A. Fernández et al. 10.1016/j.atmosres.2017.11.020
- New particle formation and its effect on cloud condensation nuclei abundance in the summer Arctic: a case study in the Fram Strait and Barents Sea S. Kecorius et al. 10.5194/acp-19-14339-2019
- Modeling the thermodynamics and kinetics of sulfuric acid-dimethylamine-water nanoparticle growth in the CLOUD chamber L. Ahlm et al. 10.1080/02786826.2016.1223268
- Size resolved chemical composition of nanoparticles from reactions of sulfuric acid with ammonia and dimethylamine H. Chen et al. 10.1080/02786826.2018.1490005
- Hygroscopicity of dimethylaminium-, sulfate-, and ammonium-containing nanoparticles O. Tikkanen et al. 10.1080/02786826.2018.1484071
- Unexpected hygroscopic behaviors of individual sub-50 nm NaNO3 nanoparticles observed by in situ atomic force microscopy Z. Ying et al. 10.1016/j.scitotenv.2022.158441
- Quantitative description of surface tension for nanodroplets containing ammonium sulfate and its application to the particle hygroscopicity prediction C. Zhang et al. 10.1063/5.0245540
- Hydration motifs of ammonium bisulfate clusters show complex temperature dependence J. Kreinbihl et al. 10.1063/5.0037965
- Effect of size and concentration corrections for surface tension on the hygroscopicity prediction of nano-aerosols C. Zhang et al. 10.1016/j.powtec.2023.119278
- libcloudph++ 2.0: aqueous-phase chemistry extension of the particle-based cloud microphysics scheme A. Jaruga & H. Pawlowska 10.5194/gmd-11-3623-2018
- Nano-hygroscopicity tandem differential mobility analyzer (nano-HTDMA) for investigating hygroscopic properties of sub-10 nm aerosol nanoparticles T. Lei et al. 10.5194/amt-13-5551-2020
29 citations as recorded by crossref.
- Electrospray Ionization–Based Synthesis and Validation of Amine-Sulfuric Acid Clusters of Relevance to Atmospheric New Particle Formation S. Waller et al. 10.1007/s13361-019-02322-3
- Enhanced growth rate of atmospheric particles from sulfuric acid D. Stolzenburg et al. 10.5194/acp-20-7359-2020
- Establishing the structural motifs present in small ammonium and aminium bisulfate clusters of relevance to atmospheric new particle formation J. Kreinbihl et al. 10.1063/5.0015094
- Hygroscopicity of ultrafine particles containing ammonium/alkylaminium sulfates: A Köhler model investigation with correction of surface tension L. Liu & H. Li 10.1016/j.atmosenv.2022.119500
- Size-Resolved Chemical Composition of Sub-20 nm Particles from Methanesulfonic Acid Reactions with Methylamine and Ammonia V. Perraud et al. 10.1021/acsearthspacechem.0c00120
- Contribution of reaction of atmospheric amine with sulfuric acid to mixing particle formation from clay mineral W. Zhang et al. 10.1016/j.scitotenv.2022.153336
- Unexpectedly acidic nanoparticles formed in dimethylamine–ammonia–sulfuric-acid nucleation experiments at CLOUD M. Lawler et al. 10.5194/acp-16-13601-2016
- Size- and Composition-Dependent Hygroscopic Growth of Sub-20 nm Atmospherically Relevant Particles: Implications for New Particle Survival J. Yishake et al. 10.1021/acs.est.5c00068
- Measurement of atmospheric nanoparticles: Bridging the gap between gas-phase molecules and larger particles C. Peng et al. 10.1016/j.jes.2022.03.006
- Review of online measurement techniques for chemical composition of atmospheric clusters and sub-20 nm particles K. Zhang et al. 10.3389/fenvs.2022.937006
- 100 Years of Progress in Cloud Physics, Aerosols, and Aerosol Chemistry Research S. Kreidenweis et al. 10.1175/AMSMONOGRAPHS-D-18-0024.1
- Molecular-level insight into uptake of dimethylamine on hydrated nitric acid clusters A. Pysanenko et al. 10.1039/D2EA00094F
- The hygroscopic properties of biomass burning aerosol from Eucalyptus and cow dung under different combustion conditions M. Mouton et al. 10.1080/02786826.2023.2198587
- Hygroscopicity of organic surrogate compounds from biomass burning and their effect on the efflorescence of ammonium sulfate in mixed aerosol particles T. Lei et al. 10.5194/acp-18-1045-2018
- Microscopic Insights Into the Formation of Methanesulfonic Acid–Methylamine–Ammonia Particles Under Acid-Rich Conditions M. Liu et al. 10.3389/fevo.2022.875585
- Unexpected Hygroscopic Behaviors of Individual Sub-50 Nm Nano3 Nanoparticles Observed by in Situ Atomic Force Microscopy Z. Ying et al. 10.2139/ssrn.4118444
- Space‐Borne Estimation of Volcanic Sulfate Aerosol Lifetime C. Li & R. Cohen 10.1029/2020JD033883
- An Experimental and Modeling Study of Nanoparticle Formation and Growth from Dimethylamine and Nitric Acid S. Chee et al. 10.1021/acs.jpca.9b03326
- Application of remote sensing techniques to study aerosol water vapour uptake in a real atmosphere A. Fernández et al. 10.1016/j.atmosres.2017.11.020
- New particle formation and its effect on cloud condensation nuclei abundance in the summer Arctic: a case study in the Fram Strait and Barents Sea S. Kecorius et al. 10.5194/acp-19-14339-2019
- Modeling the thermodynamics and kinetics of sulfuric acid-dimethylamine-water nanoparticle growth in the CLOUD chamber L. Ahlm et al. 10.1080/02786826.2016.1223268
- Size resolved chemical composition of nanoparticles from reactions of sulfuric acid with ammonia and dimethylamine H. Chen et al. 10.1080/02786826.2018.1490005
- Hygroscopicity of dimethylaminium-, sulfate-, and ammonium-containing nanoparticles O. Tikkanen et al. 10.1080/02786826.2018.1484071
- Unexpected hygroscopic behaviors of individual sub-50 nm NaNO3 nanoparticles observed by in situ atomic force microscopy Z. Ying et al. 10.1016/j.scitotenv.2022.158441
- Quantitative description of surface tension for nanodroplets containing ammonium sulfate and its application to the particle hygroscopicity prediction C. Zhang et al. 10.1063/5.0245540
- Hydration motifs of ammonium bisulfate clusters show complex temperature dependence J. Kreinbihl et al. 10.1063/5.0037965
- Effect of size and concentration corrections for surface tension on the hygroscopicity prediction of nano-aerosols C. Zhang et al. 10.1016/j.powtec.2023.119278
- libcloudph++ 2.0: aqueous-phase chemistry extension of the particle-based cloud microphysics scheme A. Jaruga & H. Pawlowska 10.5194/gmd-11-3623-2018
- Nano-hygroscopicity tandem differential mobility analyzer (nano-HTDMA) for investigating hygroscopic properties of sub-10 nm aerosol nanoparticles T. Lei et al. 10.5194/amt-13-5551-2020
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Saved (preprint)
Latest update: 23 Jul 2025
Short summary
The hygroscopicity of nucleated nanoparticles was measured in the presence of sulfuric acid, sulfuric acid-dimethylamine, and sulfuric acid-organics derived from α-pinene oxidation during CLOUD7 at CERN in 2012. The hygroscopicity parameter κ decreased with increasing particle size, indicating decreasing acidity of particles.
The hygroscopicity of nucleated nanoparticles was measured in the presence of sulfuric acid,...
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