Research article 04 Mar 2016
Research article | 04 Mar 2016
SOA formation from the photooxidation of α-pinene: systematic exploration of the simulation of chamber data
Renee C. McVay et al.
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Cited
36 citations as recorded by crossref.
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- Molecular characterization of alkyl nitrates in atmospheric aerosols by ion mobility mass spectrometry X. Zhang et al. 10.5194/amt-12-5535-2019
- Modeling organic aerosol over Europe in summer conditions with the VBS-GECKO parameterization: sensitivity to secondary organic compound properties and IVOC (intermediate-volatility organic compound) emissions V. Lannuque et al. 10.5194/acp-20-4905-2020
- An omnipresent diversity and variability in the chemical composition of atmospheric functionalized organic aerosol J. Ditto et al. 10.1038/s42004-018-0074-3
- Wall effects in smog chamber experiments: A model study E. Trump et al. 10.1080/02786826.2016.1232858
- Influence of Particle Surface Area Concentration on the Production of Organic Particulate Matter in a Continuously Mixed Flow Reactor Y. Han et al. 10.1021/acs.est.8b07302
- Atmospheric Processing of Nitrophenols and Nitrocresols From Biomass Burning Emissions H. Wang et al. 10.1029/2020JD033401
- Model–measurement comparison of functional group abundance in <i>α</i>-pinene and 1,3,5-trimethylbenzene secondary organic aerosol formation G. Ruggeri et al. 10.5194/acp-16-8729-2016
- Perspective on Mechanism Development and Structure-Activity Relationships for Gas-Phase Atmospheric Chemistry L. Vereecken et al. 10.1002/kin.21172
- Anthropogenic enhancements to production of highly oxygenated molecules from autoxidation H. Pye et al. 10.1073/pnas.1810774116
- Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis Y. Gong & Z. Chen 10.5194/acp-21-813-2021
- A note on the effects of inorganic seed aerosol on the oxidation state of secondary organic aerosol-α -Pinene ozonolysis D. Huang et al. 10.1002/2016JD025999
- Secondary organic aerosol formation from α-methylstyrene atmospheric degradation: Role of NO level, relative humidity and inorganic seed aerosol M. Tajuelo et al. 10.1016/j.atmosres.2019.104631
- Hydroxyl radical-induced formation of highly oxidized organic compounds T. Berndt et al. 10.1038/ncomms13677
- Highly Oxygenated Multifunctional Compounds in α-Pinene Secondary Organic Aerosol X. Zhang et al. 10.1021/acs.est.6b06588
- Effect of NOx and SO2 on the photooxidation of methylglyoxal: Implications in secondary aerosol formation S. Wang et al. 10.1016/j.jes.2020.02.011
- Development of a protocol for the auto-generation of explicit aqueous-phase oxidation schemes of organic compounds P. Bräuer et al. 10.5194/acp-19-9209-2019
- Evaluating the mutagenic potential of aerosol organic compounds using informatics-based screening S. Decesari et al. 10.5194/acp-18-2329-2018
- <i>α</i>-Pinene secondary organic aerosol at low temperature: chemical composition and implications for particle viscosity W. Huang et al. 10.5194/acp-18-2883-2018
- Relative humidity effect on the formation of highly oxidized molecules and new particles during monoterpene oxidation X. Li et al. 10.5194/acp-19-1555-2019
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- A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application T. Bannan et al. 10.5194/amt-12-1429-2019
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- Measured Saturation Vapor Pressures of Phenolic and Nitro-aromatic Compounds T. Bannan et al. 10.1021/acs.est.6b06364
- Comparison of Atmospheric Monocarboxylic and Dicarboxylic Acids in Xi’ an, China, for Source Apportionment of Organic Aerosols L. Wu et al. 10.1007/s11270-020-04675-y
- CCN activity of secondary aerosols from terpene ozonolysis under atmospheric relevant conditions C. Yuan et al. 10.1002/2016JD026039
- Constraining uncertainties in particle-wall deposition correction during SOA formation in chamber experiments T. Nah et al. 10.5194/acp-17-2297-2017
- Dynamic consideration of smog chamber experiments W. Chuang & N. Donahue 10.5194/acp-17-10019-2017
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- SOA and gas phase organic acid yields from the sequential photooxidation of seven monoterpenes B. Friedman & D. Farmer 10.1016/j.atmosenv.2018.06.003
- Measurements and Predictions of Binary Component Aerosol Particle Viscosity Y. Song et al. 10.1021/acs.jpca.6b07835
- Influence of seed aerosol surface area and oxidation rate on vapor wall deposition and SOA mass yields: a case study with <i>α</i>-pinene ozonolysis T. Nah et al. 10.5194/acp-16-9361-2016
36 citations as recorded by crossref.
- Technical note: Relating functional group measurements to carbon types for improved model–measurement comparisons of organic aerosol composition S. Takahama & G. Ruggeri 10.5194/acp-17-4433-2017
- Semivolatile POA and parameterized total combustion SOA in CMAQv5.2: impacts on source strength and partitioning B. Murphy et al. 10.5194/acp-17-11107-2017
- Molecular characterization of alkyl nitrates in atmospheric aerosols by ion mobility mass spectrometry X. Zhang et al. 10.5194/amt-12-5535-2019
- Modeling organic aerosol over Europe in summer conditions with the VBS-GECKO parameterization: sensitivity to secondary organic compound properties and IVOC (intermediate-volatility organic compound) emissions V. Lannuque et al. 10.5194/acp-20-4905-2020
- An omnipresent diversity and variability in the chemical composition of atmospheric functionalized organic aerosol J. Ditto et al. 10.1038/s42004-018-0074-3
- Wall effects in smog chamber experiments: A model study E. Trump et al. 10.1080/02786826.2016.1232858
- Influence of Particle Surface Area Concentration on the Production of Organic Particulate Matter in a Continuously Mixed Flow Reactor Y. Han et al. 10.1021/acs.est.8b07302
- Atmospheric Processing of Nitrophenols and Nitrocresols From Biomass Burning Emissions H. Wang et al. 10.1029/2020JD033401
- Model–measurement comparison of functional group abundance in <i>α</i>-pinene and 1,3,5-trimethylbenzene secondary organic aerosol formation G. Ruggeri et al. 10.5194/acp-16-8729-2016
- Perspective on Mechanism Development and Structure-Activity Relationships for Gas-Phase Atmospheric Chemistry L. Vereecken et al. 10.1002/kin.21172
- Anthropogenic enhancements to production of highly oxygenated molecules from autoxidation H. Pye et al. 10.1073/pnas.1810774116
- Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis Y. Gong & Z. Chen 10.5194/acp-21-813-2021
- A note on the effects of inorganic seed aerosol on the oxidation state of secondary organic aerosol-α -Pinene ozonolysis D. Huang et al. 10.1002/2016JD025999
- Secondary organic aerosol formation from α-methylstyrene atmospheric degradation: Role of NO level, relative humidity and inorganic seed aerosol M. Tajuelo et al. 10.1016/j.atmosres.2019.104631
- Hydroxyl radical-induced formation of highly oxidized organic compounds T. Berndt et al. 10.1038/ncomms13677
- Highly Oxygenated Multifunctional Compounds in α-Pinene Secondary Organic Aerosol X. Zhang et al. 10.1021/acs.est.6b06588
- Effect of NOx and SO2 on the photooxidation of methylglyoxal: Implications in secondary aerosol formation S. Wang et al. 10.1016/j.jes.2020.02.011
- Development of a protocol for the auto-generation of explicit aqueous-phase oxidation schemes of organic compounds P. Bräuer et al. 10.5194/acp-19-9209-2019
- Evaluating the mutagenic potential of aerosol organic compounds using informatics-based screening S. Decesari et al. 10.5194/acp-18-2329-2018
- <i>α</i>-Pinene secondary organic aerosol at low temperature: chemical composition and implications for particle viscosity W. Huang et al. 10.5194/acp-18-2883-2018
- Relative humidity effect on the formation of highly oxidized molecules and new particles during monoterpene oxidation X. Li et al. 10.5194/acp-19-1555-2019
- The Caltech Photooxidation Flow Tube reactor: design, fluid dynamics and characterization Y. Huang et al. 10.5194/amt-10-839-2017
- A steady-state continuous flow chamber for the study of daytime and nighttime chemistry under atmospherically relevant NO levels X. Zhang et al. 10.5194/amt-11-2537-2018
- A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application T. Bannan et al. 10.5194/amt-12-1429-2019
- Effects of NO<sub><i>x</i></sub> and SO<sub>2</sub> on the secondary organic aerosol formation from photooxidation of <i>α</i>-pinene and limonene D. Zhao et al. 10.5194/acp-18-1611-2018
- STRAPS v1.0: evaluating a methodology for predicting electron impact ionisation mass spectra for the aerosol mass spectrometer D. Topping et al. 10.5194/gmd-10-2365-2017
- Organic aerosol source apportionment in Zurich using an extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF-MS) – Part 1: Biogenic influences and day–night chemistry in summer G. Stefenelli et al. 10.5194/acp-19-14825-2019
- Measured Saturation Vapor Pressures of Phenolic and Nitro-aromatic Compounds T. Bannan et al. 10.1021/acs.est.6b06364
- Comparison of Atmospheric Monocarboxylic and Dicarboxylic Acids in Xi’ an, China, for Source Apportionment of Organic Aerosols L. Wu et al. 10.1007/s11270-020-04675-y
- CCN activity of secondary aerosols from terpene ozonolysis under atmospheric relevant conditions C. Yuan et al. 10.1002/2016JD026039
- Constraining uncertainties in particle-wall deposition correction during SOA formation in chamber experiments T. Nah et al. 10.5194/acp-17-2297-2017
- Dynamic consideration of smog chamber experiments W. Chuang & N. Donahue 10.5194/acp-17-10019-2017
- Characteristics, primary sources and secondary formation of water-soluble organic aerosols in downtown Beijing Q. Yu et al. 10.5194/acp-21-1775-2021
- SOA and gas phase organic acid yields from the sequential photooxidation of seven monoterpenes B. Friedman & D. Farmer 10.1016/j.atmosenv.2018.06.003
- Measurements and Predictions of Binary Component Aerosol Particle Viscosity Y. Song et al. 10.1021/acs.jpca.6b07835
- Influence of seed aerosol surface area and oxidation rate on vapor wall deposition and SOA mass yields: a case study with <i>α</i>-pinene ozonolysis T. Nah et al. 10.5194/acp-16-9361-2016
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Latest update: 05 Mar 2021
Short summary
Secondary organic aerosol (SOA) affects climate change, human health, and cloud formation. We examine SOA formation from the biogenic hydrocarbon α-pinene and observe unexpected experimental results that run contrary to model predictions. Various processes are explored via modeling to rationalize the observations. The paper identifies the importance of further constraining via experiments various steps in the chemical mechanism in order to accurately predict SOA worldwide.
Secondary organic aerosol (SOA) affects climate change, human health, and cloud formation. We...
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