Articles | Volume 16, issue 4
https://doi.org/10.5194/acp-16-2659-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-16-2659-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
03 Mar 2016
Research article |
| 03 Mar 2016
Oxygen isotope mass balance of atmospheric nitrate at Dome C, East Antarctica, during the OPALE campaign
Joël Savarino
CORRESPONDING AUTHOR
Université Grenoble Alpes, Laboratoire de Glaciologie et
Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
CNRS, Laboratoire de Glaciologie et Géophysique de l'Environnement
(LGGE), 38000 Grenoble, France
William C. Vicars
Université Grenoble Alpes, Laboratoire de Glaciologie et
Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
CNRS, Laboratoire de Glaciologie et Géophysique de l'Environnement
(LGGE), 38000 Grenoble, France
now at: Technical Services Program, Air Pollution Control
Division, Colorado Department of Public Health and Environment, Denver, CO,
USA
Michel Legrand
Université Grenoble Alpes, Laboratoire de Glaciologie et
Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
CNRS, Laboratoire de Glaciologie et Géophysique de l'Environnement
(LGGE), 38000 Grenoble, France
Suzanne Preunkert
Université Grenoble Alpes, Laboratoire de Glaciologie et
Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
CNRS, Laboratoire de Glaciologie et Géophysique de l'Environnement
(LGGE), 38000 Grenoble, France
Bruno Jourdain
Université Grenoble Alpes, Laboratoire de Glaciologie et
Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
CNRS, Laboratoire de Glaciologie et Géophysique de l'Environnement
(LGGE), 38000 Grenoble, France
Markus M. Frey
British Antarctic Survey, Natural Environment Research Council,
Cambridge, UK
Alexandre Kukui
Laboratoire Atmosphère, Milieux et Observations Spatiales
(LATMOS), UMR8190, CNRS-Université de Versailles Saint Quentin,
Université Pierre et Marie Curie, Paris, France
Laboratoire de Physique et Chimie de l'Environnement et de l'Espace
(LPC2E), UMR6115 CNRS-Université d'Orléans, 45071 Orléans CEDEX
2, France
Nicolas Caillon
Université Grenoble Alpes, Laboratoire de Glaciologie et
Géophysique de l'Environnement (LGGE), 38000 Grenoble, France
CNRS, Laboratoire de Glaciologie et Géophysique de l'Environnement
(LGGE), 38000 Grenoble, France
Jaime Gil Roca
Laboratoire Atmosphère, Milieux et Observations Spatiales
(LATMOS), UMR8190, CNRS-Université de Versailles Saint Quentin,
Université Pierre et Marie Curie, Paris, France
Laboratoire de Physique et Chimie de l'Environnement et de l'Espace
(LPC2E), UMR6115 CNRS-Université d'Orléans, 45071 Orléans CEDEX
2, France
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Cited
28 citations as recorded by crossref.
- Importance of NO3 radical in particulate nitrate formation in a southeast Chinese urban city: New constraints by δ15N-δ18O space of NO3- Z. Zhang et al. 10.1016/j.atmosenv.2021.118387
- Using stable isotopes to distinguish atmospheric nitrate production and its contribution to the surface ocean across hemispheres G. Shi et al. 10.1016/j.epsl.2021.116914
- The mass-independent oxygen isotopic composition in sulfate aerosol-a useful tool to identify sulfate formation: a review Y. Zhao et al. 10.1016/j.atmosres.2020.105447
- Isotopic evidence for acidity-driven enhancement of sulfate formation after SO 2 emission control S. Hattori et al. 10.1126/sciadv.abd4610
- The observation of isotopic compositions of atmospheric nitrate in Shanghai China and its implication for reactive nitrogen chemistry P. He et al. 10.1016/j.scitotenv.2020.136727
- Diurnal variations in oxygen and nitrogen isotopes of atmospheric nitrogen dioxide and nitrate: implications for tracing NOx oxidation pathways and emission sources S. Albertin et al. 10.5194/acp-24-1361-2024
- Incorporating Oxygen Isotopes of Oxidized Reactive Nitrogen in the Regional Atmospheric Chemistry Mechanism, version 2 (ICOIN-RACM2) W. Walters et al. 10.5194/gmd-17-4673-2024
- A diurnal story of Δ17O($$\rm{NO}_{3}^{-}$$) in urban Nanjing and its implication for nitrate aerosol formation Y. Zhang et al. 10.1038/s41612-022-00273-3
- Summer variability of the atmospheric NO2 : NO ratio at Dome C on the East Antarctic Plateau A. Barbero et al. 10.5194/acp-22-12025-2022
- Regional Characteristics of Atmospheric Sulfate Formation in East Antarctica Imprinted on 17O‐Excess Signature S. Ishino et al. 10.1029/2020JD033583
- An inverse model to correct for the effects of post-depositional processing on ice-core nitrate and its isotopes: model framework and applications at Summit, Greenland, and Dome C, Antarctica Z. Jiang et al. 10.5194/acp-24-4895-2024
- Distinguishing summertime atmospheric production of nitrate across the East Antarctic Ice Sheet G. Shi et al. 10.1016/j.gca.2018.03.025
- Investigating atmospheric nitrate sources and formation pathways between heating and non-heating seasons in urban North China X. Yan et al. 10.1088/1748-9326/acb805
- A seasonal analysis of aerosol NO3− sources and NOx oxidation pathways in the Southern Ocean marine boundary layer J. Burger et al. 10.5194/acp-23-5605-2023
- Atmospheric sea-salt and halogen cycles in the Antarctic K. Hara et al. 10.1039/D0EM00092B
- Determination of the triple oxygen isotopic composition of tropospheric ozone in terminal positions using a multistep nitrite‐coated filter‐pack system H. Xu et al. 10.1002/rcm.9124
- Origin of the isotopic composition of natural perchlorate: Experimental results for the impact of reaction pathway and initial ClOx reactant N. Estrada et al. 10.1016/j.gca.2021.06.039
- New Estimation of the NOx Snow‐Source on the Antarctic Plateau A. Barbero et al. 10.1029/2021JD035062
- Antarctic ozone hole modifies iodine geochemistry on the Antarctic Plateau A. Spolaor et al. 10.1038/s41467-021-26109-x
- Isotopic Evidence for the High Contribution of Wintertime Photochemistry to Particulate Nitrate Formation in Northern China Z. Zhang et al. 10.1029/2021JD035324
- Identifying NOx Sources in Arequipa, Peru Using Nitrogen Isotopes in Particulate Nitrate G. Michalski et al. 10.3389/fenvs.2022.916738
- Photolytic modification of seasonal nitrate isotope cycles in East Antarctica P. Akers et al. 10.5194/acp-22-15637-2022
- Seasonal variations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica S. Ishino et al. 10.5194/acp-17-3713-2017
- Preparation and characterization of new sulfate reference materials for Δ17O analysis G. Su et al. 10.1039/D2JA00022A
- Assessing the Seasonal Dynamics of Nitrate and Sulfate Aerosols at the South Pole Utilizing Stable Isotopes W. Walters et al. 10.1029/2019JD030517
- Recent Isotopic Evidence for Elevated Vehicular NOx Emission to Atmospheric Nitrate Formation in Chinese Megacities Z. Zhang et al. 10.1021/acsearthspacechem.1c00166
- Atmospheric nitrogen oxides (NO and NO<sub>2</sub>) at Dome C, East Antarctica, during the OPALE campaign M. Frey et al. 10.5194/acp-15-7859-2015
- Air–snow transfer of nitrate on the East Antarctic Plateau – Part 2: An isotopic model for the interpretation of deep ice-core records J. Erbland et al. 10.5194/acp-15-12079-2015
26 citations as recorded by crossref.
- Importance of NO3 radical in particulate nitrate formation in a southeast Chinese urban city: New constraints by δ15N-δ18O space of NO3- Z. Zhang et al. 10.1016/j.atmosenv.2021.118387
- Using stable isotopes to distinguish atmospheric nitrate production and its contribution to the surface ocean across hemispheres G. Shi et al. 10.1016/j.epsl.2021.116914
- The mass-independent oxygen isotopic composition in sulfate aerosol-a useful tool to identify sulfate formation: a review Y. Zhao et al. 10.1016/j.atmosres.2020.105447
- Isotopic evidence for acidity-driven enhancement of sulfate formation after SO 2 emission control S. Hattori et al. 10.1126/sciadv.abd4610
- The observation of isotopic compositions of atmospheric nitrate in Shanghai China and its implication for reactive nitrogen chemistry P. He et al. 10.1016/j.scitotenv.2020.136727
- Diurnal variations in oxygen and nitrogen isotopes of atmospheric nitrogen dioxide and nitrate: implications for tracing NOx oxidation pathways and emission sources S. Albertin et al. 10.5194/acp-24-1361-2024
- Incorporating Oxygen Isotopes of Oxidized Reactive Nitrogen in the Regional Atmospheric Chemistry Mechanism, version 2 (ICOIN-RACM2) W. Walters et al. 10.5194/gmd-17-4673-2024
- A diurnal story of Δ17O($$\rm{NO}_{3}^{-}$$) in urban Nanjing and its implication for nitrate aerosol formation Y. Zhang et al. 10.1038/s41612-022-00273-3
- Summer variability of the atmospheric NO2 : NO ratio at Dome C on the East Antarctic Plateau A. Barbero et al. 10.5194/acp-22-12025-2022
- Regional Characteristics of Atmospheric Sulfate Formation in East Antarctica Imprinted on 17O‐Excess Signature S. Ishino et al. 10.1029/2020JD033583
- An inverse model to correct for the effects of post-depositional processing on ice-core nitrate and its isotopes: model framework and applications at Summit, Greenland, and Dome C, Antarctica Z. Jiang et al. 10.5194/acp-24-4895-2024
- Distinguishing summertime atmospheric production of nitrate across the East Antarctic Ice Sheet G. Shi et al. 10.1016/j.gca.2018.03.025
- Investigating atmospheric nitrate sources and formation pathways between heating and non-heating seasons in urban North China X. Yan et al. 10.1088/1748-9326/acb805
- A seasonal analysis of aerosol NO3− sources and NOx oxidation pathways in the Southern Ocean marine boundary layer J. Burger et al. 10.5194/acp-23-5605-2023
- Atmospheric sea-salt and halogen cycles in the Antarctic K. Hara et al. 10.1039/D0EM00092B
- Determination of the triple oxygen isotopic composition of tropospheric ozone in terminal positions using a multistep nitrite‐coated filter‐pack system H. Xu et al. 10.1002/rcm.9124
- Origin of the isotopic composition of natural perchlorate: Experimental results for the impact of reaction pathway and initial ClOx reactant N. Estrada et al. 10.1016/j.gca.2021.06.039
- New Estimation of the NOx Snow‐Source on the Antarctic Plateau A. Barbero et al. 10.1029/2021JD035062
- Antarctic ozone hole modifies iodine geochemistry on the Antarctic Plateau A. Spolaor et al. 10.1038/s41467-021-26109-x
- Isotopic Evidence for the High Contribution of Wintertime Photochemistry to Particulate Nitrate Formation in Northern China Z. Zhang et al. 10.1029/2021JD035324
- Identifying NOx Sources in Arequipa, Peru Using Nitrogen Isotopes in Particulate Nitrate G. Michalski et al. 10.3389/fenvs.2022.916738
- Photolytic modification of seasonal nitrate isotope cycles in East Antarctica P. Akers et al. 10.5194/acp-22-15637-2022
- Seasonal variations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica S. Ishino et al. 10.5194/acp-17-3713-2017
- Preparation and characterization of new sulfate reference materials for Δ17O analysis G. Su et al. 10.1039/D2JA00022A
- Assessing the Seasonal Dynamics of Nitrate and Sulfate Aerosols at the South Pole Utilizing Stable Isotopes W. Walters et al. 10.1029/2019JD030517
- Recent Isotopic Evidence for Elevated Vehicular NOx Emission to Atmospheric Nitrate Formation in Chinese Megacities Z. Zhang et al. 10.1021/acsearthspacechem.1c00166
2 citations as recorded by crossref.
- Atmospheric nitrogen oxides (NO and NO<sub>2</sub>) at Dome C, East Antarctica, during the OPALE campaign M. Frey et al. 10.5194/acp-15-7859-2015
- Air–snow transfer of nitrate on the East Antarctic Plateau – Part 2: An isotopic model for the interpretation of deep ice-core records J. Erbland et al. 10.5194/acp-15-12079-2015
Saved (final revised paper)
Latest update: 13 Dec 2024
Short summary
Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable...
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