Articles | Volume 16, issue 4
Atmos. Chem. Phys., 16, 2525–2541, 2016
Atmos. Chem. Phys., 16, 2525–2541, 2016

Research article 02 Mar 2016

Research article | 02 Mar 2016

Light absorption and morphological properties of soot-containing aerosols observed at an East Asian outflow site, Noto Peninsula, Japan

Sayako Ueda1,*, Tomoki Nakayama1,**, Fumikazu Taketani2, Kouji Adachi3, Atsushi Matsuki4, Yoko Iwamoto4,***, Yasuhiro Sadanaga5, and Yutaka Matsumi1,** Sayako Ueda et al.
  • 1Solar-Terrestrial Environment Laboratory, Nagoya University, Nagoya, Japan
  • 2Japan Agency for Marine-Earth Science and Technology, Yokohama, Japan
  • 3Atmospheric Environment and Applied Meteorology Research Department, Meteorological Research Institute, Tsukuba, Japan
  • 4Institute of Nature and Environmental Technology, Kanazawa University, Kanazawa, Japan
  • 5Graduate School of Engineering, Osaka Prefecture University, Sakai, Japan
  • *now at: Graduate School of Environmental Studies, Nagoya University, Nagoya, Japan
  • **now at: Institute for Space-Earth Environmental Research, Nagoya University, Nagoya, Japan
  • ***now at: Faculty of Science Division I, Tokyo University of Science, Tokyo, Japan

Abstract. The coating of black carbon (BC) with inorganic salts and organic compounds can enhance the magnitude of light absorption by BC. To elucidate the enhancement of light absorption of aged BC particles and its relation to the mixing state and morphology of individual particles, we conducted observations of particles at an Asian outflow site in Noto Peninsula, Japan, in the spring of 2013. Absorption and scattering coefficients at 405, 532, and 781 nm and mass concentrations/mixing states of refractory BC in PM2.5 were measured using a three-wavelength photoacoustic soot spectrometer and a single-particle soot photometer (SP2), respectively, after passage through a thermodenuder (TD) maintained at 300 or 400 °C or a bypass line maintained at room temperature (25 °C). The average enhancement factor of BC light absorption due to coating was estimated by comparing absorption coefficients at 781 nm for particles that with and without passing through the TD at 300 °C and was found to be 1.22. The largest enhancements (> 1.30) were observed under high absorption coefficient periods when the air mass was long-range transported from urban areas in China. Aerosol samples were also analyzed using a transmission electron microscope (TEM) equipped with an energy dispersive X-ray analyzer. The morphological features and mixing states of soot-containing particles of four samples collected during the high absorption events were analyzed by comparing microphotographs before and after the evaporation of beam-sensitive materials by irradiation with a high-density electron beam. The majority of the soot in all samples was found as mixed particles with sulfate-containing spherules or as clusters of such spherules. For samples showing high enhancement (> 1.30) of BC light absorption, the TEM showed that the internally mixed soot-containing particles tended to have a more spherical shape and to be thickly coated. The SP2 measurements also suggested that the proportion of thickly coated soot was greater. Thus, the observed enhancement of BC light absorption was found to differ according to the mixing states and morphology of soot-containing particles. The enhancement of BC light absorption in our in situ measurements and its relation with individual features of soot-containing particles will be useful to evaluate direct radiative forcing in the downwind areas of large emission sources of BC.

Short summary
Detailed understandings of the light absorption property of black carbon (BC) particles and its relation to the mixing state and morphology are important. In this study, the enhancement of light absorption of BC due to coating (lensing effect) in a well-aged air mass was observed at an East Asian outflow site in Japan using a photoacoustic spectrometer, and its relation with mixing state and morphology of individual particles was examined based on transmission electron microscope analyses.
Final-revised paper