Articles | Volume 16, issue 4
https://doi.org/10.5194/acp-16-2175-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-2175-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
25 Feb 2016
Research article |
| 25 Feb 2016
Gas–particle partitioning and hydrolysis of organic nitrates formed from the oxidation of α-pinene in environmental chamber experiments
Jeffrey K. Bean
McKetta Department of Chemical Engineering, The University of Texas at
Austin, Austin, Texas, USA
McKetta Department of Chemical Engineering, The University of Texas at
Austin, Austin, Texas, USA
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39 citations as recorded by crossref.
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- Rapid hydrolysis of tertiary isoprene nitrate efficiently removes NO x from the atmosphere K. Vasquez et al. 10.1073/pnas.2017442117
- Measurement report: Online measurement of gas-phase nitrated phenols utilizing a CI-LToF-MS: primary sources and secondary formation K. Song et al. 10.5194/acp-21-7917-2021
- Formation of Particulate Matter from the Oxidation of Evaporated Hydraulic Fracturing Wastewater J. Bean et al. 10.1021/acs.est.7b06009
- Effects of Relative Humidity and Photoaging on the Formation, Composition, and Aging of Ethylbenzene SOA: Insights from Chamber Experiments on Chlorine Radical-Initiated Oxidation of Ethylbenzene L. Jahn et al. 10.1021/acsearthspacechem.3c00279
- Impact of NOx on secondary organic aerosol (SOA) formation from α-pinene and β-pinene photooxidation: the role of highly oxygenated organic nitrates I. Pullinen et al. 10.5194/acp-20-10125-2020
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- Air pollution from unconventional oil and gas development in the Eagle Ford Shale K. McPherson et al. 10.1016/j.atmosenv.2024.120812
- Modelling organic aerosol concentrations and properties during ChArMEx summer campaigns of 2012 and 2013 in the western Mediterranean region M. Chrit et al. 10.5194/acp-17-12509-2017
- Stability of α-Pinene and d-Limonene Ozonolysis Secondary Organic Aerosol Compounds Toward Hydrolysis and Hydration C. Wong et al. 10.1021/acsearthspacechem.1c00171
- Photolysis and oxidation by OH radicals of two carbonyl nitrates: 4-nitrooxy-2-butanone and 5-nitrooxy-2-pentanone B. Picquet-Varrault et al. 10.5194/acp-20-487-2020
- Differences in BVOC oxidation and SOA formation above and below the forest canopy B. Schulze et al. 10.5194/acp-17-1805-2017
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- Isoprene–Chlorine Oxidation in the Presence of NOx and Implications for Urban Atmospheric Chemistry D. Wang et al. 10.1021/acs.est.1c07048
- Light absorption and scattering properties of indole secondary organic aerosol prepared under various oxidant and relative humidity conditions V. Baboomian et al. 10.1080/02786826.2023.2193235
- Mechanism-based structure-activity relationship investigation on hydrolysis kinetics of atmospheric organic nitrates Q. Zhao et al. 10.1038/s41612-023-00517-w
- Synthesis and Hydrolysis of Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.est.1c05310
- Alkyl nitrates in the boreal forest: formation via the NO3-, OH- and O3-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Reaction Mechanisms Underlying Unfunctionalized Alkyl Nitrate Hydrolysis in Aqueous Aerosols F. Keshavarz et al. 10.1021/acsearthspacechem.0c00253
- Modeling biogenic secondary organic aerosol (BSOA) formation from monoterpene reactions with NO3: A case study of the SOAS campaign using CMAQ M. Qin et al. 10.1016/j.atmosenv.2018.03.042
- Condensed Phase Kinetic Studies of Hydroxynitrates Derived from the Photooxidation of Carene, Limonene, trans-Carveol, and Perillic Alcohol J. Vesto et al. 10.3390/atmos13040592
- Reactivity of a Carene-Derived Hydroxynitrate in Mixed Organic/Aqueous Matrices: Applying Synthetic Chemistry to Product Identification and Mechanistic Implications A. McAlister et al. 10.3390/atmos12121617
- High Molecular Diversity of Organic Nitrogen in Urban Snow in North China S. Su et al. 10.1021/acs.est.0c06851
- Nontargeted Tandem Mass Spectrometry Analysis Reveals Diversity and Variability in Aerosol Functional Groups across Multiple Sites, Seasons, and Times of Day J. Ditto et al. 10.1021/acs.estlett.9b00702
- The acid-catalyzed hydrolysis of an α-pinene-derived organic nitrate: kinetics, products, reaction mechanisms, and atmospheric impact J. Rindelaub et al. 10.5194/acp-16-15425-2016
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
- Mist cannon trucks can exacerbate the formation of water-soluble organic aerosol and PM2.5 pollution in the road environment Y. Xu et al. 10.5194/acp-23-6775-2023
- Chemodiversity of organic nitrogen emissions from light-duty gasoline vehicles is governed by engine displacements and driving speed H. Han et al. 10.1016/j.scitotenv.2024.170792
- Effects of NO x on the molecular composition of secondary organic aerosol formed by the ozonolysis and photooxidation of α-pinene J. Park et al. 10.1016/j.atmosenv.2017.07.022
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Effects of Relative Humidity on Time-Resolved Molecular Characterization of Secondary Organic Aerosols from the OH-Initiated Oxidation of Cresol in the Presence of NOx C. Carstens et al. 10.1021/acs.est.4c08215
- Chemical composition and hydrolysis of organic nitrate aerosol formed from hydroxyl and nitrate radical oxidation of α-pinene and β-pinene M. Takeuchi & N. Ng 10.5194/acp-19-12749-2019
- The production and hydrolysis of organic nitrates from OH radical oxidation of β-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Unified Theory of Vapor–Wall Mass Transport in Teflon-Walled Environmental Chambers Y. Huang et al. 10.1021/acs.est.7b05575
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Decadal changes in summertime reactive oxidized nitrogen and surface ozone over the Southeast United States J. Li et al. 10.5194/acp-18-2341-2018
- Secondary Organic Aerosol (SOA) from Nitrate Radical Oxidation of Monoterpenes: Effects of Temperature, Dilution, and Humidity on Aerosol Formation, Mixing, and Evaporation C. Boyd et al. 10.1021/acs.est.7b01460
- Organic Nitrate Contribution to New Particle Formation and Growth in Secondary Organic Aerosols from α-Pinene Ozonolysis T. Berkemeier et al. 10.1021/acs.est.6b00961
37 citations as recorded by crossref.
- Understanding the Impact of High-NOx Conditions on the Formation of Secondary Organic Aerosol in the Photooxidation of Oil Sand-Related Precursors K. Li et al. 10.1021/acs.est.9b05404
- Rapid hydrolysis of tertiary isoprene nitrate efficiently removes NO x from the atmosphere K. Vasquez et al. 10.1073/pnas.2017442117
- Measurement report: Online measurement of gas-phase nitrated phenols utilizing a CI-LToF-MS: primary sources and secondary formation K. Song et al. 10.5194/acp-21-7917-2021
- Formation of Particulate Matter from the Oxidation of Evaporated Hydraulic Fracturing Wastewater J. Bean et al. 10.1021/acs.est.7b06009
- Effects of Relative Humidity and Photoaging on the Formation, Composition, and Aging of Ethylbenzene SOA: Insights from Chamber Experiments on Chlorine Radical-Initiated Oxidation of Ethylbenzene L. Jahn et al. 10.1021/acsearthspacechem.3c00279
- Impact of NOx on secondary organic aerosol (SOA) formation from α-pinene and β-pinene photooxidation: the role of highly oxygenated organic nitrates I. Pullinen et al. 10.5194/acp-20-10125-2020
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- Air pollution from unconventional oil and gas development in the Eagle Ford Shale K. McPherson et al. 10.1016/j.atmosenv.2024.120812
- Modelling organic aerosol concentrations and properties during ChArMEx summer campaigns of 2012 and 2013 in the western Mediterranean region M. Chrit et al. 10.5194/acp-17-12509-2017
- Stability of α-Pinene and d-Limonene Ozonolysis Secondary Organic Aerosol Compounds Toward Hydrolysis and Hydration C. Wong et al. 10.1021/acsearthspacechem.1c00171
- Photolysis and oxidation by OH radicals of two carbonyl nitrates: 4-nitrooxy-2-butanone and 5-nitrooxy-2-pentanone B. Picquet-Varrault et al. 10.5194/acp-20-487-2020
- Differences in BVOC oxidation and SOA formation above and below the forest canopy B. Schulze et al. 10.5194/acp-17-1805-2017
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- Isoprene–Chlorine Oxidation in the Presence of NOx and Implications for Urban Atmospheric Chemistry D. Wang et al. 10.1021/acs.est.1c07048
- Light absorption and scattering properties of indole secondary organic aerosol prepared under various oxidant and relative humidity conditions V. Baboomian et al. 10.1080/02786826.2023.2193235
- Mechanism-based structure-activity relationship investigation on hydrolysis kinetics of atmospheric organic nitrates Q. Zhao et al. 10.1038/s41612-023-00517-w
- Synthesis and Hydrolysis of Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.est.1c05310
- Alkyl nitrates in the boreal forest: formation via the NO3-, OH- and O3-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Reaction Mechanisms Underlying Unfunctionalized Alkyl Nitrate Hydrolysis in Aqueous Aerosols F. Keshavarz et al. 10.1021/acsearthspacechem.0c00253
- Modeling biogenic secondary organic aerosol (BSOA) formation from monoterpene reactions with NO3: A case study of the SOAS campaign using CMAQ M. Qin et al. 10.1016/j.atmosenv.2018.03.042
- Condensed Phase Kinetic Studies of Hydroxynitrates Derived from the Photooxidation of Carene, Limonene, trans-Carveol, and Perillic Alcohol J. Vesto et al. 10.3390/atmos13040592
- Reactivity of a Carene-Derived Hydroxynitrate in Mixed Organic/Aqueous Matrices: Applying Synthetic Chemistry to Product Identification and Mechanistic Implications A. McAlister et al. 10.3390/atmos12121617
- High Molecular Diversity of Organic Nitrogen in Urban Snow in North China S. Su et al. 10.1021/acs.est.0c06851
- Nontargeted Tandem Mass Spectrometry Analysis Reveals Diversity and Variability in Aerosol Functional Groups across Multiple Sites, Seasons, and Times of Day J. Ditto et al. 10.1021/acs.estlett.9b00702
- The acid-catalyzed hydrolysis of an α-pinene-derived organic nitrate: kinetics, products, reaction mechanisms, and atmospheric impact J. Rindelaub et al. 10.5194/acp-16-15425-2016
- Vapor-Pressure Pathways Initiate but Hydrolysis Products Dominate the Aerosol Estimated from Organic Nitrates A. Zare et al. 10.1021/acsearthspacechem.9b00067
- Mist cannon trucks can exacerbate the formation of water-soluble organic aerosol and PM2.5 pollution in the road environment Y. Xu et al. 10.5194/acp-23-6775-2023
- Chemodiversity of organic nitrogen emissions from light-duty gasoline vehicles is governed by engine displacements and driving speed H. Han et al. 10.1016/j.scitotenv.2024.170792
- Effects of NO x on the molecular composition of secondary organic aerosol formed by the ozonolysis and photooxidation of α-pinene J. Park et al. 10.1016/j.atmosenv.2017.07.022
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Effects of Relative Humidity on Time-Resolved Molecular Characterization of Secondary Organic Aerosols from the OH-Initiated Oxidation of Cresol in the Presence of NOx C. Carstens et al. 10.1021/acs.est.4c08215
- Chemical composition and hydrolysis of organic nitrate aerosol formed from hydroxyl and nitrate radical oxidation of α-pinene and β-pinene M. Takeuchi & N. Ng 10.5194/acp-19-12749-2019
- The production and hydrolysis of organic nitrates from OH radical oxidation of β-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Unified Theory of Vapor–Wall Mass Transport in Teflon-Walled Environmental Chambers Y. Huang et al. 10.1021/acs.est.7b05575
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Decadal changes in summertime reactive oxidized nitrogen and surface ozone over the Southeast United States J. Li et al. 10.5194/acp-18-2341-2018
2 citations as recorded by crossref.
- Secondary Organic Aerosol (SOA) from Nitrate Radical Oxidation of Monoterpenes: Effects of Temperature, Dilution, and Humidity on Aerosol Formation, Mixing, and Evaporation C. Boyd et al. 10.1021/acs.est.7b01460
- Organic Nitrate Contribution to New Particle Formation and Growth in Secondary Organic Aerosols from α-Pinene Ozonolysis T. Berkemeier et al. 10.1021/acs.est.6b00961
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Latest update: 22 Feb 2025
Short summary
The fate of organic nitrates influences their role as sinks and sources of NOx and their effects on the formation of tropospheric ozone and organic aerosol. Organic nitrates were formed from the photo-oxidation of α-pinene in environmental chamber experiments. Results on partitioning and hydrolysis of organic nitrates from this work could be implemented in chemical transport models to more accurately represent the fate of NOx and the formation of ozone and particulate matter.
The fate of organic nitrates influences their role as sinks and sources of NOx and their effects...
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