Articles | Volume 16, issue 4
https://doi.org/10.5194/acp-16-2109-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-2109-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Atmospheric OH reactivity in central London: observations, model predictions and estimates of in situ ozone production
Lisa K. Whalley
CORRESPONDING AUTHOR
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, LS2
9JT, UK
Daniel Stone
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Brian Bandy
School of Environmental Sciences, University of East Anglia, Norwich
Research Park, Norwich, NR4 7TJ, UK
Rachel Dunmore
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, Heslington, York, YO10 5DD, UK
Jacqueline F. Hamilton
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, Heslington, York, YO10 5DD, UK
James Hopkins
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, Heslington, York, YO10 5DD, UK
National Centre for Atmospheric Science, University of York, Heslington,
York, YO10 5DD, UK
James D. Lee
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, Heslington, York, YO10 5DD, UK
National Centre for Atmospheric Science, University of York, Heslington,
York, YO10 5DD, UK
Alastair C. Lewis
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, Heslington, York, YO10 5DD, UK
National Centre for Atmospheric Science, University of York, Heslington,
York, YO10 5DD, UK
Dwayne E. Heard
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, LS2
9JT, UK
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Cited
64 citations as recorded by crossref.
- Distribution of volatile organic compounds (VOCs) in the urban atmosphere of Hangzhou, East China: Temporal variation, source attribution, and impact on the secondary formations of ozone and aerosol X. Wang et al. 10.3389/fenvs.2024.1418948
- Radical chemistry at a rural site (Wangdu) in the North China Plain: observation and model calculations of OH, HO<sub>2</sub> and RO<sub>2</sub> radicals Z. Tan et al. 10.5194/acp-17-663-2017
- Observationally constrained modeling of atmospheric oxidation capacity and photochemical reactivity in Shanghai, China J. Zhu et al. 10.5194/acp-20-1217-2020
- Significant decreases in the volatile organic compound concentration, atmospheric oxidation capacity and photochemical reactivity during the National Day holiday over a suburban site in the North China Plain Y. Yang et al. 10.1016/j.envpol.2020.114657
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- Investigation on the budget of peroxyacetyl nitrate (PAN) in the Yangtze River Delta: Unravelling local photochemistry and regional impact T. Xu et al. 10.1016/j.scitotenv.2024.170373
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- Investigation of OH-reactivity budget in the isoprene, α-pinene and m-xylene oxidation with OH under high NOx conditions Y. Sakamoto et al. 10.1016/j.atmosenv.2021.118916
- Behaviour of traffic emitted semi-volatile and intermediate volatility organic compounds within the urban atmosphere R. Xu et al. 10.1016/j.scitotenv.2020.137470
- Implementation of a chemical background method for atmospheric OH measurements by laser-induced fluorescence: characterisation and observations from the UK and China R. Woodward-Massey et al. 10.5194/amt-13-3119-2020
- AtChem (version 1), an open-source box model for the Master Chemical Mechanism R. Sommariva et al. 10.5194/gmd-13-169-2020
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- Impacts of missing OH reactivity and aerosol uptake of HO2 radicals on tropospheric O3 production during the AQUAS-Kyoto summer campaign in 2018 N. Kohno et al. 10.1016/j.atmosenv.2022.119130
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- Total hydroxyl radical reactivity measurements in a suburban area during AQUAS–Tsukuba campaign in summer 2017 J. Li et al. 10.1016/j.scitotenv.2020.139897
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- Comparing Urban Anthropogenic NMVOC Measurements With Representation in Emission Inventories—A Global Perspective E. von Schneidemesser et al. 10.1029/2022JD037906
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- Total OH reactivity measurements for the OH-initiated oxidation of aromatic hydrocarbons in the presence of NOx K. Sato et al. 10.1016/j.atmosenv.2017.10.036
- Assessing chemistry schemes and constraints in air quality models used to predict ozone in London against the detailed Master Chemical Mechanism T. Malkin et al. 10.1039/C5FD00218D
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- Kinetic and mechanistic study on gas phase reactions of ozone with a series ofcis-3-hexenyl esters Q. Zhang et al. 10.1039/C7RA13369C
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- Potential Factors Contributing to Ozone Production in AQUAS–Kyoto Campaign in Summer 2020: Natural Source-Related Missing OH Reactivity and Heterogeneous HO2/RO2 Loss J. Li et al. 10.1021/acs.est.2c03628
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- Impact of aromatics and monoterpenes on simulated tropospheric ozone and total OH reactivity W. Porter et al. 10.1016/j.atmosenv.2017.08.048
- Comprehensive measurements of atmospheric OH reactivity and trace species within a suburban forest near Tokyo during AQUAS-TAMA campaign S. Ramasamy et al. 10.1016/j.atmosenv.2018.04.035
- Source characterization of volatile organic compounds in the Colorado Northern Front Range Metropolitan Area during spring and summer 2015 A. Abeleira et al. 10.1002/2016JD026227
- An instrument to measure fast gas phase radical kinetics at high temperatures and pressures D. Stone et al. 10.1063/1.4950906
- OH reactivity at a rural site (Wangdu) in the North China Plain: contributions from OH reactants and experimental OH budget H. Fuchs et al. 10.5194/acp-17-645-2017
- How the OH reactivity affects the ozone production efficiency: case studies in Beijing and Heshan, China Y. Yang et al. 10.5194/acp-17-7127-2017
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- Constraining remote oxidation capacity with ATom observations K. Travis et al. 10.5194/acp-20-7753-2020
- A Box-Model Simulation of the Formation of Inorganic Ionic Particulate Species and Their Air Quality Implications in Republic of Korea H. Lee et al. 10.5572/ajae.2022.119
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- Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area B. Nault et al. 10.5194/acp-24-9573-2024
- Measurement of OH reactivity by laser flash photolysis coupled with laser-induced fluorescence spectroscopy D. Stone et al. 10.5194/amt-9-2827-2016
- Understanding in situ ozone production in the summertime through radical observations and modelling studies during the Clean air for London project (ClearfLo) L. Whalley et al. 10.5194/acp-18-2547-2018
- A Review of the Direct Measurement of Total OH Reactivity: Ambient Air and Vehicular Emission X. Yang 10.3390/su152316246
- Evaluating the sensitivity of radical chemistry and ozone formation to ambient VOCs and NO<sub><i>x</i></sub> in Beijing L. Whalley et al. 10.5194/acp-21-2125-2021
- Parameterized atmospheric oxidation capacity and speciated OH reactivity over a suburban site in the North China Plain: A comparative study between summer and winter Y. Yang et al. 10.1016/j.scitotenv.2021.145264
- Measurements of Total OH Reactivity During CalNex‐LA R. Hansen et al. 10.1029/2020JD032988
- Global modelling of the total OH reactivity: investigations on the “missing” OH sink and its atmospheric implications V. Ferracci et al. 10.5194/acp-18-7109-2018
- Microbial aerosol chemistry characteristics in highly polluted air T. Zhang et al. 10.1007/s11426-019-9488-3
- An instrument for in situ measurement of total ozone reactivity R. Sommariva et al. 10.5194/amt-13-1655-2020
64 citations as recorded by crossref.
- Distribution of volatile organic compounds (VOCs) in the urban atmosphere of Hangzhou, East China: Temporal variation, source attribution, and impact on the secondary formations of ozone and aerosol X. Wang et al. 10.3389/fenvs.2024.1418948
- Radical chemistry at a rural site (Wangdu) in the North China Plain: observation and model calculations of OH, HO<sub>2</sub> and RO<sub>2</sub> radicals Z. Tan et al. 10.5194/acp-17-663-2017
- Observationally constrained modeling of atmospheric oxidation capacity and photochemical reactivity in Shanghai, China J. Zhu et al. 10.5194/acp-20-1217-2020
- Significant decreases in the volatile organic compound concentration, atmospheric oxidation capacity and photochemical reactivity during the National Day holiday over a suburban site in the North China Plain Y. Yang et al. 10.1016/j.envpol.2020.114657
- Inter-comparisons of VOC oxidation mechanisms based on box model: A focus on OH reactivity X. Yang et al. 10.1016/j.jes.2021.09.002
- Investigation on the budget of peroxyacetyl nitrate (PAN) in the Yangtze River Delta: Unravelling local photochemistry and regional impact T. Xu et al. 10.1016/j.scitotenv.2024.170373
- Observationally Constrained Modeling of Peroxy Radical During an Ozone Episode in the Pearl River Delta Region, China J. Wang et al. 10.1029/2022JD038279
- Radical chemistry and ozone production at a UK coastal receptor site R. Woodward-Massey et al. 10.5194/acp-23-14393-2023
- Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin Y. Yang et al. 10.5194/acp-20-8181-2020
- OH reactivity of the urban air in Helsinki, Finland, during winter A. Praplan et al. 10.1016/j.atmosenv.2017.09.013
- Investigation of OH-reactivity budget in the isoprene, α-pinene and m-xylene oxidation with OH under high NOx conditions Y. Sakamoto et al. 10.1016/j.atmosenv.2021.118916
- Behaviour of traffic emitted semi-volatile and intermediate volatility organic compounds within the urban atmosphere R. Xu et al. 10.1016/j.scitotenv.2020.137470
- Implementation of a chemical background method for atmospheric OH measurements by laser-induced fluorescence: characterisation and observations from the UK and China R. Woodward-Massey et al. 10.5194/amt-13-3119-2020
- AtChem (version 1), an open-source box model for the Master Chemical Mechanism R. Sommariva et al. 10.5194/gmd-13-169-2020
- Peroxy radical chemistry during ozone photochemical pollution season at a suburban site in the boundary of Jiangsu–Anhui–Shandong–Henan region, China N. Wei et al. 10.1016/j.scitotenv.2023.166355
- Impacts of missing OH reactivity and aerosol uptake of HO2 radicals on tropospheric O3 production during the AQUAS-Kyoto summer campaign in 2018 N. Kohno et al. 10.1016/j.atmosenv.2022.119130
- Detailed budget analysis of HONO in central London reveals a missing daytime source J. Lee et al. 10.5194/acp-16-2747-2016
- Evolution of OH reactivity in NO-free volatile organic compound photooxidation investigated by the fully explicit GECKO-A model Z. Peng et al. 10.5194/acp-21-14649-2021
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Contributions to OH reactivity from unexplored volatile organic compounds measured by PTR-ToF-MS – a case study in a suburban forest of the Seoul metropolitan area during the Korea–United States Air Quality Study (KORUS-AQ) 2016 D. Sanchez et al. 10.5194/acp-21-6331-2021
- Total hydroxyl radical reactivity measurements in a suburban area during AQUAS–Tsukuba campaign in summer 2017 J. Li et al. 10.1016/j.scitotenv.2020.139897
- Measurement report: Important contributions of oxygenated compounds to emissions and chemistry of volatile organic compounds in urban air C. Wu et al. 10.5194/acp-20-14769-2020
- Parameterized atmospheric oxidation capacity during summer at an urban site in Taiyuan and implications for O3 pollution control B. Shao et al. 10.1016/j.apr.2024.102181
- Atmospheric oxidation capacity and ozone pollution mechanism in a coastal city of southeastern China: analysis of a typical photochemical episode by an observation-based model T. Liu et al. 10.5194/acp-22-2173-2022
- OH and HO<sub>2</sub> radical chemistry at a suburban site during the EXPLORE-YRD campaign in 2018 X. Ma et al. 10.5194/acp-22-7005-2022
- Comparing Urban Anthropogenic NMVOC Measurements With Representation in Emission Inventories—A Global Perspective E. von Schneidemesser et al. 10.1029/2022JD037906
- Experimental budgets of OH, HO<sub>2</sub>, and RO<sub>2</sub> radicals and implications for ozone formation in the Pearl River Delta in China 2014 Z. Tan et al. 10.5194/acp-19-7129-2019
- Oxidative capacity and radical chemistry in the polluted atmosphere of Hong Kong and Pearl River Delta region: analysis of a severe photochemical smog episode L. Xue et al. 10.5194/acp-16-9891-2016
- In situ ozone production is highly sensitive to volatile organic compounds in Delhi, India B. Nelson et al. 10.5194/acp-21-13609-2021
- Composition and reactivity of volatile organic compounds in the South Coast Air Basin and San Joaquin Valley of California S. Liu et al. 10.5194/acp-22-10937-2022
- A quantitative understanding of total OH reactivity and ozone production in a coastal industrial area during the Yokohama air quality study (AQUAS) campaign of summer 2019 J. Li et al. 10.1016/j.atmosenv.2021.118754
- Total OH reactivity measurements for the OH-initiated oxidation of aromatic hydrocarbons in the presence of NOx K. Sato et al. 10.1016/j.atmosenv.2017.10.036
- Assessing chemistry schemes and constraints in air quality models used to predict ozone in London against the detailed Master Chemical Mechanism T. Malkin et al. 10.1039/C5FD00218D
- Distribution characteristics, source apportionment, and chemical reactivity of volatile organic compounds in two adjacent areas in Shanxi, North China X. Liu et al. 10.1016/j.atmosenv.2022.119374
- Kinetic and mechanistic study on gas phase reactions of ozone with a series ofcis-3-hexenyl esters Q. Zhang et al. 10.1039/C7RA13369C
- Oxidizing capacity of the rural atmosphere in Hong Kong, Southern China Z. Li et al. 10.1016/j.scitotenv.2017.08.310
- Long-term trends in air quality in major cities in the UK and India: a view from space K. Vohra et al. 10.5194/acp-21-6275-2021
- Chamber investigation of the formation and transformation of secondary organic aerosol in mixtures of biogenic and anthropogenic volatile organic compounds A. Voliotis et al. 10.5194/acp-22-14147-2022
- Low-NO atmospheric oxidation pathways in a polluted megacity M. Newland et al. 10.5194/acp-21-1613-2021
- Synthesizing evidence for the external cycling of NOx in high- to low-NOx atmospheres C. Ye et al. 10.1038/s41467-023-43866-z
- Observed versus simulated OH reactivity during KORUS-AQ campaign: Implications for emission inventory and chemical environment in East Asia H. Kim et al. 10.1525/elementa.2022.00030
- Potential Factors Contributing to Ozone Production in AQUAS–Kyoto Campaign in Summer 2020: Natural Source-Related Missing OH Reactivity and Heterogeneous HO2/RO2 Loss J. Li et al. 10.1021/acs.est.2c03628
- Comparison of OH reactivity measurements in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/amt-10-4023-2017
- Impact of aromatics and monoterpenes on simulated tropospheric ozone and total OH reactivity W. Porter et al. 10.1016/j.atmosenv.2017.08.048
- Comprehensive measurements of atmospheric OH reactivity and trace species within a suburban forest near Tokyo during AQUAS-TAMA campaign S. Ramasamy et al. 10.1016/j.atmosenv.2018.04.035
- Source characterization of volatile organic compounds in the Colorado Northern Front Range Metropolitan Area during spring and summer 2015 A. Abeleira et al. 10.1002/2016JD026227
- An instrument to measure fast gas phase radical kinetics at high temperatures and pressures D. Stone et al. 10.1063/1.4950906
- OH reactivity at a rural site (Wangdu) in the North China Plain: contributions from OH reactants and experimental OH budget H. Fuchs et al. 10.5194/acp-17-645-2017
- How the OH reactivity affects the ozone production efficiency: case studies in Beijing and Heshan, China Y. Yang et al. 10.5194/acp-17-7127-2017
- BAERLIN2014 – stationary measurements and source apportionment at an urban background station in Berlin, Germany E. von Schneidemesser et al. 10.5194/acp-18-8621-2018
- Elucidating the quantitative characterization of atmospheric oxidation capacity in Beijing, China Z. Liu et al. 10.1016/j.scitotenv.2021.145306
- Constraining remote oxidation capacity with ATom observations K. Travis et al. 10.5194/acp-20-7753-2020
- A Box-Model Simulation of the Formation of Inorganic Ionic Particulate Species and Their Air Quality Implications in Republic of Korea H. Lee et al. 10.5572/ajae.2022.119
- LES study of the impact of moist thermals on the oxidative capacity of the atmosphere in southern West Africa F. Brosse et al. 10.5194/acp-18-6601-2018
- Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area B. Nault et al. 10.5194/acp-24-9573-2024
- Measurement of OH reactivity by laser flash photolysis coupled with laser-induced fluorescence spectroscopy D. Stone et al. 10.5194/amt-9-2827-2016
- Understanding in situ ozone production in the summertime through radical observations and modelling studies during the Clean air for London project (ClearfLo) L. Whalley et al. 10.5194/acp-18-2547-2018
- A Review of the Direct Measurement of Total OH Reactivity: Ambient Air and Vehicular Emission X. Yang 10.3390/su152316246
- Evaluating the sensitivity of radical chemistry and ozone formation to ambient VOCs and NO<sub><i>x</i></sub> in Beijing L. Whalley et al. 10.5194/acp-21-2125-2021
- Parameterized atmospheric oxidation capacity and speciated OH reactivity over a suburban site in the North China Plain: A comparative study between summer and winter Y. Yang et al. 10.1016/j.scitotenv.2021.145264
- Measurements of Total OH Reactivity During CalNex‐LA R. Hansen et al. 10.1029/2020JD032988
- Global modelling of the total OH reactivity: investigations on the “missing” OH sink and its atmospheric implications V. Ferracci et al. 10.5194/acp-18-7109-2018
- Microbial aerosol chemistry characteristics in highly polluted air T. Zhang et al. 10.1007/s11426-019-9488-3
- An instrument for in situ measurement of total ozone reactivity R. Sommariva et al. 10.5194/amt-13-1655-2020
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