Articles | Volume 16, issue 3
https://doi.org/10.5194/acp-16-1837-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-1837-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Organic peroxides' gas-particle partitioning and rapid heterogeneous decomposition on secondary organic aerosol
Huan Li
State Key Laboratory of Environmental Simulation and Pollution
Control,
College of Environmental Sciences and Engineering, Peking University,
Beijing 100871, China
Zhongming Chen
CORRESPONDING AUTHOR
State Key Laboratory of Environmental Simulation and Pollution
Control,
College of Environmental Sciences and Engineering, Peking University,
Beijing 100871, China
Liubin Huang
State Key Laboratory of Environmental Simulation and Pollution
Control,
College of Environmental Sciences and Engineering, Peking University,
Beijing 100871, China
Dao Huang
State Key Laboratory of Environmental Simulation and Pollution
Control,
College of Environmental Sciences and Engineering, Peking University,
Beijing 100871, China
now at: School of Earth Sciences, Zhejiang University, Hangzhou 310027, Zhejiang, China
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Cited
55 citations as recorded by crossref.
- Fates of Organic Hydroperoxides in Atmospheric Condensed Phases S. Enami 10.1021/acs.jpca.1c01513
- Photooxidation-Initiated Aqueous-Phase Formation of Organic Peroxides: Delving into Formation Mechanisms T. Gautam et al. 10.1021/acs.est.3c01162
- Observation of atmospheric peroxides during Wangdu Campaign 2014 at a rural site in the North China Plain Y. Wang et al. 10.5194/acp-16-10985-2016
- Decomposition mechanism of α-alkoxyalkyl-hydroperoxides in the liquid phase: temperature dependent kinetics and theoretical calculations M. Hu et al. 10.1039/D1EA00076D
- Aerosol Generating Potential of the Products of Atmospheric Photooxidation of Biogenic Organic Compounds G. Dultseva et al. 10.1134/S1024856020050073
- Proton-Catalyzed Decomposition of Multifunctionalized Organic Hydroperoxides Derived from the Reactions of Criegee Intermediates with Ethylene Glycol in Aqueous Organic Media S. Enami 10.1021/acsearthspacechem.2c00142
- Relative humidity-dependent evolution of molecular composition of α-pinene secondary organic aerosol upon heterogeneous oxidation by hydroxyl radicals W. Wang et al. 10.1016/j.jes.2023.08.021
- Reactive Oxygen Species Formed by Secondary Organic Aerosols in Water and Surrogate Lung Fluid H. Tong et al. 10.1021/acs.est.8b03695
- Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis Y. Gong & Z. Chen 10.5194/acp-21-813-2021
- Secondary Organic Aerosol (SOA) through Uptake of Isoprene Hydroxy Hydroperoxides (ISOPOOH) and its Oxidation Products P. Mettke et al. 10.1021/acsearthspacechem.2c00385
- Quantitative constraints on autoxidation and dimer formation from direct probing of monoterpene-derived peroxy radical chemistry Y. Zhao et al. 10.1073/pnas.1812147115
- Application of time-of-flight aerosol mass spectrometry for the real-time measurement of particle-phase organic peroxides: an online redox derivatization–aerosol mass spectrometer (ORD-AMS) M. Weloe & T. Hoffmann 10.5194/amt-13-5725-2020
- Quantifying bimolecular reaction kinetics of isoprene hydroxy peroxy radical: From dry to highly humid atmospheric environment J. Xu & Z. Chen 10.1016/j.atmosenv.2024.120627
- Potential Matrix Effects in Iodometry Determination of Peroxides Induced by Olefins T. Gautam et al. 10.1021/acs.jpca.1c10717
- Aqueous-phase fates of α-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with alcohols M. Hu et al. 10.1039/D0CP06308H
- Synthesis of Carboxylic Acid and Dimer Ester Surrogates to Constrain the Abundance and Distribution of Molecular Products in α-Pinene and β-Pinene Secondary Organic Aerosol C. Kenseth et al. 10.1021/acs.est.0c01566
- Multiphase Reactions between Secondary Organic Aerosol and Sulfur Dioxide: Kinetics and Contributions to Sulfate Formation and Aerosol Aging M. Yao et al. 10.1021/acs.estlett.9b00657
- Fresh versus Photo-recalcitrant Secondary Organic Aerosol: Effects of Organic Mixtures on Aqueous Photodegradation of 4-Nitrophenol T. Braman et al. 10.1021/acs.estlett.0c00177
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Temperature Dependence of Aqueous-Phase Decomposition of α-Hydroxyalkyl-Hydroperoxides M. Hu et al. 10.1021/acs.jpca.0c09862
- Analytical methodologies for oxidized organic compounds in the atmosphere A. Tiusanen et al. 10.1039/D3EM00163F
- Decomposition of multifunctionalized α-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with diols in liquid phases Y. Endo et al. 10.1039/D2CP00915C
- Relative importance of gas uptake on aerosol and ground surfaces characterized by equivalent uptake coefficients M. Li et al. 10.5194/acp-19-10981-2019
- Organic Peroxides and Sulfur Dioxide in Aerosol: Source of Particulate Sulfate S. Wang et al. 10.1021/acs.est.9b02591
- Importance of Hydroxyl Radical Chemistry in Isoprene Suppression of Particle Formation from α-Pinene Ozonolysis Y. Wang et al. 10.1021/acsearthspacechem.0c00294
- Partitioning of hydrogen peroxide in gas-liquid and gas-aerosol phases X. Xuan et al. 10.5194/acp-20-5513-2020
- Surface-Active β-Caryophyllene Oxidation Products at the Air/Aqueous Interface A. Bé et al. 10.1021/acsearthspacechem.9b00185
- Rapid Aqueous-Phase Hydrolysis of Ester Hydroperoxides Arising from Criegee Intermediates and Organic Acids R. Zhao et al. 10.1021/acs.jpca.8b02195
- The oxidation regime and SOA composition in limonene ozonolysis: roles of different double bonds, radicals, and water Y. Gong et al. 10.5194/acp-18-15105-2018
- Aerosol Health Effects from Molecular to Global Scales M. Shiraiwa et al. 10.1021/acs.est.7b04417
- Analytical optical methods for measuring organic peroxides and hydroperoxides: An evaluation D. Alba-Elena et al. 10.1016/j.atmosenv.2024.120858
- A new iodometric microwave-assisted method for peroxide determination in Secondary Organic Aerosols D. Alba-Elena et al. 10.1016/j.atmosenv.2023.119960
- Iodometry-Assisted Liquid Chromatography Electrospray Ionization Mass Spectrometry for Analysis of Organic Peroxides: An Application to Atmospheric Secondary Organic Aerosol R. Zhao et al. 10.1021/acs.est.7b04863
- Persistence of Monoterpene-Derived Organic Peroxides in the Atmospheric Aqueous Phase Z. Liu et al. 10.1021/acsearthspacechem.2c00145
- The fate of organic peroxides indoors: quantifying humidity-dependent uptake on naturally soiled indoor window glass M. Webb et al. 10.1039/D3EM00041A
- Multiphase Reactions between Organic Peroxides and Sulfur Dioxide in Internally Mixed Inorganic and Organic Particles: Key Roles of Particle Phase Separation and Acidity M. Yao et al. 10.1021/acs.est.3c04975
- Interfacial vs Bulk Ozonolysis of Nerolidol J. Qiu et al. 10.1021/acs.est.9b00364
- Water Dramatically Accelerates the Decomposition of α-Hydroxyalkyl-Hydroperoxides in Aerosol Particles J. Qiu et al. 10.1021/acs.jpclett.9b01953
- Growth Rate Dependence of Secondary Organic Aerosol on Seed Particle Size, Composition, and Phase D. Higgins et al. 10.1021/acsearthspacechem.2c00049
- Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol M. Yao et al. 10.1021/acs.est.2c01297
- Online Characterization of Organic Aerosol by Condensational Growth into Aqueous Droplets Coupled with Droplet-Assisted Ionization D. Kerecman et al. 10.1021/acs.analchem.0c03697
- The preferred geometry of hydroperoxides is the result of an interplay between electrostatic and hyperconjugative effects M. Afonso & R. Cormanich 10.1039/D0CP04688D
- Insights into HO<sub><i>x</i></sub> and RO<sub><i>x</i></sub> chemistry in the boreal forest via measurement of peroxyacetic acid, peroxyacetic nitric anhydride (PAN) and hydrogen peroxide J. Crowley et al. 10.5194/acp-18-13457-2018
- Review of Recent Smog Chamber Studies for Secondary Organic Aerosol Y. Lim et al. 10.5572/KOSAE.2016.32.2.131
- Dynamic Oxidative Potential of Organic Aerosol from Heated Cooking Oil S. Wang et al. 10.1021/acsearthspacechem.1c00038
- Secondary Organic Aerosol Generated from Biomass Burning Emitted Phenolic Compounds: Oxidative Potential, Reactive Oxygen Species, and Cytotoxicity Z. Fang et al. 10.1021/acs.est.3c09903
- Synthesis and Characterization of Organic Peroxides from Monoterpene-Derived Criegee Intermediates in Secondary Organic Aerosol K. Li et al. 10.1021/acs.est.3c07048
- Multiphase reactivity of gaseous hydroperoxide oligomers produced from isoprene ozonolysis in the presence of acidified aerosols M. Riva et al. 10.1016/j.atmosenv.2016.12.040
- Labile Peroxides in Secondary Organic Aerosol M. Krapf et al. 10.1016/j.chempr.2016.09.007
- Atmospheric β-Caryophyllene-Derived Ozonolysis Products at Interfaces A. Bé et al. 10.1021/acsearthspacechem.8b00156
- Hydrolysis reactivity reveals significant seasonal variation in the composition of organic peroxides in ambient PM2.5 Y. Dai et al. 10.1016/j.scitotenv.2024.172143
- Exploring hydroperoxides in combustion: History, recent advances and perspectives Z. Wang et al. 10.1016/j.pecs.2019.02.003
- Influence of Inorganic Gases on Formation and Chemical Composition of Monoaromatic Hydrocarbons Secondary Organic Aerosol J. XU & M. HUANG 10.1016/S1872-2040(20)60008-1
54 citations as recorded by crossref.
- Fates of Organic Hydroperoxides in Atmospheric Condensed Phases S. Enami 10.1021/acs.jpca.1c01513
- Photooxidation-Initiated Aqueous-Phase Formation of Organic Peroxides: Delving into Formation Mechanisms T. Gautam et al. 10.1021/acs.est.3c01162
- Observation of atmospheric peroxides during Wangdu Campaign 2014 at a rural site in the North China Plain Y. Wang et al. 10.5194/acp-16-10985-2016
- Decomposition mechanism of α-alkoxyalkyl-hydroperoxides in the liquid phase: temperature dependent kinetics and theoretical calculations M. Hu et al. 10.1039/D1EA00076D
- Aerosol Generating Potential of the Products of Atmospheric Photooxidation of Biogenic Organic Compounds G. Dultseva et al. 10.1134/S1024856020050073
- Proton-Catalyzed Decomposition of Multifunctionalized Organic Hydroperoxides Derived from the Reactions of Criegee Intermediates with Ethylene Glycol in Aqueous Organic Media S. Enami 10.1021/acsearthspacechem.2c00142
- Relative humidity-dependent evolution of molecular composition of α-pinene secondary organic aerosol upon heterogeneous oxidation by hydroxyl radicals W. Wang et al. 10.1016/j.jes.2023.08.021
- Reactive Oxygen Species Formed by Secondary Organic Aerosols in Water and Surrogate Lung Fluid H. Tong et al. 10.1021/acs.est.8b03695
- Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis Y. Gong & Z. Chen 10.5194/acp-21-813-2021
- Secondary Organic Aerosol (SOA) through Uptake of Isoprene Hydroxy Hydroperoxides (ISOPOOH) and its Oxidation Products P. Mettke et al. 10.1021/acsearthspacechem.2c00385
- Quantitative constraints on autoxidation and dimer formation from direct probing of monoterpene-derived peroxy radical chemistry Y. Zhao et al. 10.1073/pnas.1812147115
- Application of time-of-flight aerosol mass spectrometry for the real-time measurement of particle-phase organic peroxides: an online redox derivatization–aerosol mass spectrometer (ORD-AMS) M. Weloe & T. Hoffmann 10.5194/amt-13-5725-2020
- Quantifying bimolecular reaction kinetics of isoprene hydroxy peroxy radical: From dry to highly humid atmospheric environment J. Xu & Z. Chen 10.1016/j.atmosenv.2024.120627
- Potential Matrix Effects in Iodometry Determination of Peroxides Induced by Olefins T. Gautam et al. 10.1021/acs.jpca.1c10717
- Aqueous-phase fates of α-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with alcohols M. Hu et al. 10.1039/D0CP06308H
- Synthesis of Carboxylic Acid and Dimer Ester Surrogates to Constrain the Abundance and Distribution of Molecular Products in α-Pinene and β-Pinene Secondary Organic Aerosol C. Kenseth et al. 10.1021/acs.est.0c01566
- Multiphase Reactions between Secondary Organic Aerosol and Sulfur Dioxide: Kinetics and Contributions to Sulfate Formation and Aerosol Aging M. Yao et al. 10.1021/acs.estlett.9b00657
- Fresh versus Photo-recalcitrant Secondary Organic Aerosol: Effects of Organic Mixtures on Aqueous Photodegradation of 4-Nitrophenol T. Braman et al. 10.1021/acs.estlett.0c00177
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Temperature Dependence of Aqueous-Phase Decomposition of α-Hydroxyalkyl-Hydroperoxides M. Hu et al. 10.1021/acs.jpca.0c09862
- Analytical methodologies for oxidized organic compounds in the atmosphere A. Tiusanen et al. 10.1039/D3EM00163F
- Decomposition of multifunctionalized α-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with diols in liquid phases Y. Endo et al. 10.1039/D2CP00915C
- Relative importance of gas uptake on aerosol and ground surfaces characterized by equivalent uptake coefficients M. Li et al. 10.5194/acp-19-10981-2019
- Organic Peroxides and Sulfur Dioxide in Aerosol: Source of Particulate Sulfate S. Wang et al. 10.1021/acs.est.9b02591
- Importance of Hydroxyl Radical Chemistry in Isoprene Suppression of Particle Formation from α-Pinene Ozonolysis Y. Wang et al. 10.1021/acsearthspacechem.0c00294
- Partitioning of hydrogen peroxide in gas-liquid and gas-aerosol phases X. Xuan et al. 10.5194/acp-20-5513-2020
- Surface-Active β-Caryophyllene Oxidation Products at the Air/Aqueous Interface A. Bé et al. 10.1021/acsearthspacechem.9b00185
- Rapid Aqueous-Phase Hydrolysis of Ester Hydroperoxides Arising from Criegee Intermediates and Organic Acids R. Zhao et al. 10.1021/acs.jpca.8b02195
- The oxidation regime and SOA composition in limonene ozonolysis: roles of different double bonds, radicals, and water Y. Gong et al. 10.5194/acp-18-15105-2018
- Aerosol Health Effects from Molecular to Global Scales M. Shiraiwa et al. 10.1021/acs.est.7b04417
- Analytical optical methods for measuring organic peroxides and hydroperoxides: An evaluation D. Alba-Elena et al. 10.1016/j.atmosenv.2024.120858
- A new iodometric microwave-assisted method for peroxide determination in Secondary Organic Aerosols D. Alba-Elena et al. 10.1016/j.atmosenv.2023.119960
- Iodometry-Assisted Liquid Chromatography Electrospray Ionization Mass Spectrometry for Analysis of Organic Peroxides: An Application to Atmospheric Secondary Organic Aerosol R. Zhao et al. 10.1021/acs.est.7b04863
- Persistence of Monoterpene-Derived Organic Peroxides in the Atmospheric Aqueous Phase Z. Liu et al. 10.1021/acsearthspacechem.2c00145
- The fate of organic peroxides indoors: quantifying humidity-dependent uptake on naturally soiled indoor window glass M. Webb et al. 10.1039/D3EM00041A
- Multiphase Reactions between Organic Peroxides and Sulfur Dioxide in Internally Mixed Inorganic and Organic Particles: Key Roles of Particle Phase Separation and Acidity M. Yao et al. 10.1021/acs.est.3c04975
- Interfacial vs Bulk Ozonolysis of Nerolidol J. Qiu et al. 10.1021/acs.est.9b00364
- Water Dramatically Accelerates the Decomposition of α-Hydroxyalkyl-Hydroperoxides in Aerosol Particles J. Qiu et al. 10.1021/acs.jpclett.9b01953
- Growth Rate Dependence of Secondary Organic Aerosol on Seed Particle Size, Composition, and Phase D. Higgins et al. 10.1021/acsearthspacechem.2c00049
- Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol M. Yao et al. 10.1021/acs.est.2c01297
- Online Characterization of Organic Aerosol by Condensational Growth into Aqueous Droplets Coupled with Droplet-Assisted Ionization D. Kerecman et al. 10.1021/acs.analchem.0c03697
- The preferred geometry of hydroperoxides is the result of an interplay between electrostatic and hyperconjugative effects M. Afonso & R. Cormanich 10.1039/D0CP04688D
- Insights into HO<sub><i>x</i></sub> and RO<sub><i>x</i></sub> chemistry in the boreal forest via measurement of peroxyacetic acid, peroxyacetic nitric anhydride (PAN) and hydrogen peroxide J. Crowley et al. 10.5194/acp-18-13457-2018
- Review of Recent Smog Chamber Studies for Secondary Organic Aerosol Y. Lim et al. 10.5572/KOSAE.2016.32.2.131
- Dynamic Oxidative Potential of Organic Aerosol from Heated Cooking Oil S. Wang et al. 10.1021/acsearthspacechem.1c00038
- Secondary Organic Aerosol Generated from Biomass Burning Emitted Phenolic Compounds: Oxidative Potential, Reactive Oxygen Species, and Cytotoxicity Z. Fang et al. 10.1021/acs.est.3c09903
- Synthesis and Characterization of Organic Peroxides from Monoterpene-Derived Criegee Intermediates in Secondary Organic Aerosol K. Li et al. 10.1021/acs.est.3c07048
- Multiphase reactivity of gaseous hydroperoxide oligomers produced from isoprene ozonolysis in the presence of acidified aerosols M. Riva et al. 10.1016/j.atmosenv.2016.12.040
- Labile Peroxides in Secondary Organic Aerosol M. Krapf et al. 10.1016/j.chempr.2016.09.007
- Atmospheric β-Caryophyllene-Derived Ozonolysis Products at Interfaces A. Bé et al. 10.1021/acsearthspacechem.8b00156
- Hydrolysis reactivity reveals significant seasonal variation in the composition of organic peroxides in ambient PM2.5 Y. Dai et al. 10.1016/j.scitotenv.2024.172143
- Exploring hydroperoxides in combustion: History, recent advances and perspectives Z. Wang et al. 10.1016/j.pecs.2019.02.003
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Latest update: 04 Nov 2024
Short summary
The formation, gas-particle partitioning, and evolution of atmospheric organic peroxides are unclear. We investigated the ozonolysis of α-pinene, and focused on peroxides. We found that gas-particle partitioning coefficients of peroxides are much higher than the values from our theoretical prediction, and some gaseous peroxides undergo rapid heterogeneous decomposition on SOA particles in the presence of water vapor, resulting in the additional production of hydrogen peroxide.
The formation, gas-particle partitioning, and evolution of atmospheric organic peroxides are...
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