Articles | Volume 16, issue 24
https://doi.org/10.5194/acp-16-15561-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-15561-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
16 Dec 2016
Research article |
| 16 Dec 2016
Size-dependent chemical ageing of oleic acid aerosol under dry and humidified conditions
Suad S. Al-Kindi
School of Geography, Earth and Environmental Sciences, University of
Birmingham, Edgbaston, Birmingham B15 2TT, UK
School of Geography, Earth and Environmental Sciences, University of
Birmingham, Edgbaston, Birmingham B15 2TT, UK
David C. Beddows
School of Geography, Earth and Environmental Sciences, University of
Birmingham, Edgbaston, Birmingham B15 2TT, UK
also at: National Centre for Atmospheric Science, UK
William J. Bloss
School of Geography, Earth and Environmental Sciences, University of
Birmingham, Edgbaston, Birmingham B15 2TT, UK
Roy M. Harrison
School of Geography, Earth and Environmental Sciences, University of
Birmingham, Edgbaston, Birmingham B15 2TT, UK
also at: Department of Environmental Sciences/Center of Excellence in
Environmental Studies, King Abdulaziz University, Jeddah, 21589, Saudi
Arabia
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Cited
18 citations as recorded by crossref.
- Compositional evolution of particle-phase reaction products and water in the heterogeneous OH oxidation of model aqueous organic aerosols M. Chim et al. https://doi.org/10.5194/acp-17-14415-2017
- Ozonolysis of Oleic Acid Aerosol Revisited: Multiphase Chemical Kinetics and Reaction Mechanisms T. Berkemeier et al. https://doi.org/10.1021/acsearthspacechem.1c00232
- Diesel exhaust nanoparticles and their behaviour in the atmosphere R. Harrison et al. https://doi.org/10.1098/rspa.2018.0492
- Real-Time Single-Particle Characteristics and Aging of Cooking Aerosols in Urban Beijing T. Ma et al. https://doi.org/10.1021/acs.estlett.3c00053
- The influence of saturation on the surface structure of mixed fatty acid-on-water aerosol: a molecular dynamics study A. Stewart et al. https://doi.org/10.1039/D2EA00089J
- An organic crystalline state in ageing atmospheric aerosol proxies: spatially resolved structural changes in levitated fatty acid particles A. Milsom et al. https://doi.org/10.5194/acp-21-15003-2021
- PM2.5 Organosulfates/Organonitrates and Organic Acids at Two Different Sites on Cyprus: Time and Spatial Variation and Source Apportionment S. Kotsaki et al. https://doi.org/10.3390/environments13020069
- Oxidation pathways of linoleic acid revisited with electrodynamic balance–mass spectrometry M. Müller et al. https://doi.org/10.1039/D2EA00127F
- Complex three-dimensional self-assembly in proxies for atmospheric aerosols C. Pfrang et al. https://doi.org/10.1038/s41467-017-01918-1
- Transported smoke from crop residue burning as the major source of organic aerosol and health risks in northern Indian cities during post-monsoon Y. Hao et al. https://doi.org/10.1016/j.envint.2025.109583
- Comprehensive modeling study of ozonolysis of oleic acid aerosol based on real‐time, online measurements of aerosol composition P. Gallimore et al. https://doi.org/10.1002/2016JD026221
- Kinetics of Heterogeneous Reaction of Ozone with Oleic Acid and Its Dependence on Droplet Size, Relative Humidity, and Ozone Concentration G. Zeng et al. https://doi.org/10.3390/atmos16040433
- Mechanisms of reactivity of benzo(a)pyrene and other PAH inferred from field measurements R. Harrison et al. https://doi.org/10.1016/j.apr.2018.05.009
- Heterogeneous Ozonolysis of Endocyclic Unsaturated Organic Aerosol Proxies: Implications for Criegee Intermediate Dynamics and Later-Generation Reactions Z. Zhao et al. https://doi.org/10.1021/acsearthspacechem.8b00177
- Electrodynamic balance–mass spectrometry reveals impact of oxidant concentration on product composition in the ozonolysis of oleic acid M. Müller et al. https://doi.org/10.1039/D2CP03289A
- Size-Segregated Chemical Compositions of HULISs in Ambient Aerosols Collected during the Winter Season in Songdo, South Korea K. Jang et al. https://doi.org/10.3390/atmos10040226
- Exploring the Nanostructures Accessible to an Organic Surfactant Atmospheric Aerosol Proxy A. Milsom et al. https://doi.org/10.1021/acs.jpca.2c04611
- The persistence of a proxy for cooking emissions in megacities: a kinetic study of the ozonolysis of self-assembled films by simultaneous small and wide angle X-ray scattering (SAXS/WAXS) and Raman microscopy A. Milsom et al. https://doi.org/10.1039/D0FD00088D
18 citations as recorded by crossref.
- Compositional evolution of particle-phase reaction products and water in the heterogeneous OH oxidation of model aqueous organic aerosols M. Chim et al. https://doi.org/10.5194/acp-17-14415-2017
- Ozonolysis of Oleic Acid Aerosol Revisited: Multiphase Chemical Kinetics and Reaction Mechanisms T. Berkemeier et al. https://doi.org/10.1021/acsearthspacechem.1c00232
- Diesel exhaust nanoparticles and their behaviour in the atmosphere R. Harrison et al. https://doi.org/10.1098/rspa.2018.0492
- Real-Time Single-Particle Characteristics and Aging of Cooking Aerosols in Urban Beijing T. Ma et al. https://doi.org/10.1021/acs.estlett.3c00053
- The influence of saturation on the surface structure of mixed fatty acid-on-water aerosol: a molecular dynamics study A. Stewart et al. https://doi.org/10.1039/D2EA00089J
- An organic crystalline state in ageing atmospheric aerosol proxies: spatially resolved structural changes in levitated fatty acid particles A. Milsom et al. https://doi.org/10.5194/acp-21-15003-2021
- PM2.5 Organosulfates/Organonitrates and Organic Acids at Two Different Sites on Cyprus: Time and Spatial Variation and Source Apportionment S. Kotsaki et al. https://doi.org/10.3390/environments13020069
- Oxidation pathways of linoleic acid revisited with electrodynamic balance–mass spectrometry M. Müller et al. https://doi.org/10.1039/D2EA00127F
- Complex three-dimensional self-assembly in proxies for atmospheric aerosols C. Pfrang et al. https://doi.org/10.1038/s41467-017-01918-1
- Transported smoke from crop residue burning as the major source of organic aerosol and health risks in northern Indian cities during post-monsoon Y. Hao et al. https://doi.org/10.1016/j.envint.2025.109583
- Comprehensive modeling study of ozonolysis of oleic acid aerosol based on real‐time, online measurements of aerosol composition P. Gallimore et al. https://doi.org/10.1002/2016JD026221
- Kinetics of Heterogeneous Reaction of Ozone with Oleic Acid and Its Dependence on Droplet Size, Relative Humidity, and Ozone Concentration G. Zeng et al. https://doi.org/10.3390/atmos16040433
- Mechanisms of reactivity of benzo(a)pyrene and other PAH inferred from field measurements R. Harrison et al. https://doi.org/10.1016/j.apr.2018.05.009
- Heterogeneous Ozonolysis of Endocyclic Unsaturated Organic Aerosol Proxies: Implications for Criegee Intermediate Dynamics and Later-Generation Reactions Z. Zhao et al. https://doi.org/10.1021/acsearthspacechem.8b00177
- Electrodynamic balance–mass spectrometry reveals impact of oxidant concentration on product composition in the ozonolysis of oleic acid M. Müller et al. https://doi.org/10.1039/D2CP03289A
- Size-Segregated Chemical Compositions of HULISs in Ambient Aerosols Collected during the Winter Season in Songdo, South Korea K. Jang et al. https://doi.org/10.3390/atmos10040226
- Exploring the Nanostructures Accessible to an Organic Surfactant Atmospheric Aerosol Proxy A. Milsom et al. https://doi.org/10.1021/acs.jpca.2c04611
- The persistence of a proxy for cooking emissions in megacities: a kinetic study of the ozonolysis of self-assembled films by simultaneous small and wide angle X-ray scattering (SAXS/WAXS) and Raman microscopy A. Milsom et al. https://doi.org/10.1039/D0FD00088D
Saved (final revised paper)
Latest update: 12 Jun 2026
Short summary
Oleic acid is a chemical substance which is emitted from cooking processes and is present as tiny particles in the atmosphere. The oleic acid in the particles reacts chemically with atmospheric ozone, causing substantial changes to the composition of the particles. This paper uses new techniques to explore these chemical reactions and the effect of humidity upon them. The significance of the results for the atmosphere is considered.
Oleic acid is a chemical substance which is emitted from cooking processes and is present as...
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