Articles | Volume 16, issue 3
https://doi.org/10.5194/acp-16-1531-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-1531-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Pesticides in the atmosphere: a comparison of gas-particle partitioning and particle size distribution of legacy and current-use pesticides
C. Degrendele
Masaryk University, RECETOX (Research Centre for Toxic
Compounds in the Environment), Faculty of Science, Kamenice 753/5, 62500
Brno, Czech Republic
Max Planck Institute for Chemistry, Multiphase Chemistry
Department, Hahn-Meitner-Weg 1, 55128 Mainz, Germany
K. Okonski
Masaryk University, RECETOX (Research Centre for Toxic
Compounds in the Environment), Faculty of Science, Kamenice 753/5, 62500
Brno, Czech Republic
L. Melymuk
CORRESPONDING AUTHOR
Masaryk University, RECETOX (Research Centre for Toxic
Compounds in the Environment), Faculty of Science, Kamenice 753/5, 62500
Brno, Czech Republic
L. Landlová
Masaryk University, RECETOX (Research Centre for Toxic
Compounds in the Environment), Faculty of Science, Kamenice 753/5, 62500
Brno, Czech Republic
P. Kukučka
Masaryk University, RECETOX (Research Centre for Toxic
Compounds in the Environment), Faculty of Science, Kamenice 753/5, 62500
Brno, Czech Republic
O. Audy
Masaryk University, RECETOX (Research Centre for Toxic
Compounds in the Environment), Faculty of Science, Kamenice 753/5, 62500
Brno, Czech Republic
J. Kohoutek
Masaryk University, RECETOX (Research Centre for Toxic
Compounds in the Environment), Faculty of Science, Kamenice 753/5, 62500
Brno, Czech Republic
P. Čupr
Masaryk University, RECETOX (Research Centre for Toxic
Compounds in the Environment), Faculty of Science, Kamenice 753/5, 62500
Brno, Czech Republic
J. Klánová
CORRESPONDING AUTHOR
Masaryk University, RECETOX (Research Centre for Toxic
Compounds in the Environment), Faculty of Science, Kamenice 753/5, 62500
Brno, Czech Republic
Related authors
No articles found.
Gerhard Lammel, Franz X. Meixner, Branislav Vrana, Christos I. Efstathiou, Jiři Kohoutek, Petr Kukučka, Marie D. Mulder, Petra Přibylová, Roman Prokeš, Tatsiana P. Rusina, Guo-Zheng Song, and Manolis Tsapakis
Atmos. Chem. Phys., 16, 6381–6393, https://doi.org/10.5194/acp-16-6381-2016, https://doi.org/10.5194/acp-16-6381-2016, 2016
Short summary
Short summary
As a consequence of long-range transported pollution air–sea exchange can become a major source of anthropogenic organic pollutants. Fluxes were studied at a remote coastal site in the Mediterranean, based on gradient measurements in air, measurements in surface seawater and eddy covariance. Night-time maxima in air are explained by volatilisation from the sea surface. Fluctuation of the direction of air–sea exchange indicate that long-term observations are needed.
P. Shahpoury, G. Lammel, A. Holubová Šmejkalová, J. Klánová, P. Přibylová, and M. Váňa
Atmos. Chem. Phys., 15, 1795–1805, https://doi.org/10.5194/acp-15-1795-2015, https://doi.org/10.5194/acp-15-1795-2015, 2015
M. D. Mulder, A. Heil, P. Kukučka, J. Klánová, J. Kuta, R. Prokeš, F. Sprovieri, and G. Lammel
Atmos. Chem. Phys., 14, 8905–8915, https://doi.org/10.5194/acp-14-8905-2014, https://doi.org/10.5194/acp-14-8905-2014, 2014
Related subject area
Subject: Aerosols | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
Investigating the contribution of grown new particles to cloud condensation nuclei with largely varying preexisting particles – Part 1: Observational data analysis
Measurement report: Brown carbon aerosol in polluted urban air of the North China Plain – day–night differences in the chromophores and optical properties
Source apportionment of soot particles and aqueous-phase processing of black carbon coatings in an urban environment
Seasonal variations in composition and sources of atmospheric ultrafine particles in urban Beijing based on near-continuous measurements
Summertime response of ozone and fine particulate matter to mixing layer meteorology over the North China Plain
Trace elements in PM2.5 aerosols in East Asian outflow in the spring of 2018: emission, transport, and source apportionment
Measurement Report: Investigation on the sources and formation processes of dicarboxylic acids and related species in urban aerosols before and during the COVID-19 lockdown in Jinan, East China
pH dependence of brown-carbon optical properties in cloud water
Oxidative potential in rural, suburban and city centre atmospheric environments in central Europe
Secondary aerosol formation during a special dust transport event: impacts from unusually enhanced ozone and dust backflows over the ocean
Intra-event evolution of elemental and ionic concentrations in wet deposition in an urban environment
Spatial and diurnal variations of aerosol organosulfates in summertime Shanghai, China: potential influence of photochemical processes and anthropogenic sulfate pollution
Characterizing water-soluble brown carbon in fine particles in four typical cities in northwestern China during wintertime: integrating optical properties with chemical processes
Chemical composition-dependent hygroscopic behavior of individual ambient aerosol particles collected at a coastal site
Gas–particle partitioning of semivolatile organic compounds when wildfire smoke comes to town
Enrichment of calcium in sea spray aerosol: insights from bulk measurements and individual particle analysis during the R/V Xuelong cruise in the summertime in Ross Sea, Antarctica
Source apportionment study on particulate air pollution in two high-altitude Bolivian cities: La Paz and El Alto
Morphological features and water solubility of iron in aged fine aerosol particles over the Indian Ocean
Short-term Source Apportionment of Fine Particulate Matter with Time-dependent Profiles Using SoFi: Exploring the Reliability of Rolling Positive Matrix Factorization (PMF) Applied to Bihourly Molecular and Elemental Tracer Data
What chemical species are responsible for new particle formation and growth in the Netherlands? A hybrid positive matrix factorization (PMF) analysis using aerosol composition (ACSM) and size (SMPS)
Physicochemical and Temporal Characteristics of Individual Atmospheric Aerosol Particles in Urban Seoul during KORUS-AQ Campaign: Insights from Single-Particle Analysis
Measurement report: Stoichiometry of dissolved iron and aluminum as an indicator of the factors controlling the fractional solubility of aerosol iron – results of the annual observations of size-fractionated aerosol particles in Japan
In-depth study of the formation processes of single atmospheric particles in the south-eastern margin of the Tibetan Plateau
Climatology of aerosol properties at an atmospheric monitoring site on the northern California coast
Concurrent photochemical whitening and darkening of ambient brown carbon
High-time-resolution chemical composition and source apportionment of PM2.5 in northern Chinese cities: implications for policy
Measurement report: New insights into the mixing structures of black carbon on the eastern Tibetan Plateau – soot redistribution and fractal dimension enhancement by liquid–liquid phase separation
Seasonal variations in the production of singlet oxygen and organic triplet excited states in aqueous PM2.5 in Hong Kong SAR, South China
Fractional solubility of iron in mineral dust aerosols over coastal Namibia: a link with marine biogenic emissions?
Nighttime NO emissions strongly suppress chlorine and nitrate radical formation during the winter in Delhi
Influence of natural and anthropogenic aerosols on cloud base droplet size distributions in clouds over the South China Sea and West Pacific
The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS)
Measurement report: A 1-year study to estimate maritime contributions to PM10 in a coastal area in northern France
Marine Carbohydrates in Arctic Aerosol Particles and Fog – Diversity of Oceanic Sources and Atmospheric Transformations
Evolution and chemical characteristics of organic aerosols during wintertime PM2.5 episodes in Shanghai, China: insights gained from online measurements of organic molecular markers
Arctic observations of hydroperoxymethyl thioformate (HPMTF) – seasonal behavior and relationship to other oxidation products of dimethyl sulfide at the Zeppelin Observatory, Svalbard
A 1-year aerosol chemical speciation monitor (ACSM) source analysis of organic aerosol particle contributions from anthropogenic sources after long-range transport at the TROPOS research station Melpitz
Contributions of primary emissions and secondary formation to nitrated aromatic compounds in themountain background region of Southeast China
Mist cannon trucks can exacerbate the formation of water-soluble organic aerosol and PM2.5 pollution in the road environment
Amino acids, carbohydrates, and lipids in the tropical oligotrophic Atlantic Ocean: sea-to-air transfer and atmospheric in situ formation
Ambient carbonaceous aerosol levels in Cyprus and the role of pollution transport from the Middle East
High contribution of anthropogenic combustion sources to atmospheric inorganic reactive nitrogen in South China evidenced by isotopes
Measurement report: Diurnal variations of brown carbon during two distinct seasons in a megacity in northeast China
Source Apportionment of PM2.5 in Montréal, Canada and Health Risk Assessment for Potentially Toxic Elements
Characterization of water-soluble brown carbon chromophores from wildfire plumes in the western US using size exclusion chromatography
Evolution of Nucleophilic High-molecular-weight Organic Compounds in Ambient Aerosols
Comprehensive mass spectrometric analysis of unprecedented high levels of carbonaceous aerosol particles long-range transported from wildfires in the Siberian Arctic
Vertical profiles of volatile organic compounds and fine particles in atmospheric air by using an aerial drone with miniaturized samplers and portable devices
Real-world observations of ultrafine particles and reduced nitrogen in commercial cooking organic aerosol emissions
Multiple pathways for the formation of secondary organic aerosol in the North China Plain in summer
Xing Wei, Yanjie Shen, Xiao-Ying Yu, Yang Gao, Huiwang Gao, Ming Chu, Yujiao Zhu, and Xiaohong Yao
Atmos. Chem. Phys., 23, 15325–15350, https://doi.org/10.5194/acp-23-15325-2023, https://doi.org/10.5194/acp-23-15325-2023, 2023
Short summary
Short summary
We investigate the contribution of grown new particles to Nccn at a rural mountain site in the North China Plain. The total particle number concentrations (Ncn) observed on 8 new particle formation (NPF) days were higher compared to non-NPF days. The Nccn at 0.2 % supersaturation (SS) and 0.4 % SS on the NPF days was significantly lower than on non-NPF days. Only one of eight NPF events had detectable net contributions to Nccn at 0.4 % SS and 1.0 % SS with increased κ values.
Yuquan Gong, Ru-Jin Huang, Lu Yang, Ting Wang, Wei Yuan, Wei Xu, Wenjuan Cao, Yang Wang, and Yongjie Li
Atmos. Chem. Phys., 23, 15197–15207, https://doi.org/10.5194/acp-23-15197-2023, https://doi.org/10.5194/acp-23-15197-2023, 2023
Short summary
Short summary
This study reveals the large day–night differences in brown carbon (BrC) chromophore composition, which was not known previously. The results provide insights into the effects of atmospheric processes and emissions on BrC composition.
Ryan N. Farley, Sonya Collier, Christopher D. Cappa, Leah R. Williams, Timothy B. Onasch, Lynn M. Russell, Hwajin Kim, and Qi Zhang
Atmos. Chem. Phys., 23, 15039–15056, https://doi.org/10.5194/acp-23-15039-2023, https://doi.org/10.5194/acp-23-15039-2023, 2023
Short summary
Short summary
Soot particles, also known as black carbon (BC), have important implications for global climate and regional air quality. After the particles are emitted, BC can be coated with other material, impacting the aerosol properties. We selectively measured the composition of particles containing BC to explore their sources and chemical transformations in the atmosphere. We focus on a persistent, multiday fog event in order to study the effects of chemical reactions occurring within liquid droplets.
Xiaoxiao Li, Yijing Chen, Yuyang Li, Runlong Cai, Yiran Li, Chenjuan Deng, Jin Wu, Chao Yan, Hairong Cheng, Yongchun Liu, Markku Kulmala, Jiming Hao, James N. Smith, and Jingkun Jiang
Atmos. Chem. Phys., 23, 14801–14812, https://doi.org/10.5194/acp-23-14801-2023, https://doi.org/10.5194/acp-23-14801-2023, 2023
Short summary
Short summary
Near-continuous measurements show the composition, sources, and seasonal variations of ultrafine particles (UFPs) in urban Beijing. Vehicle and cooking emissions and new particle formation are the main sources of UFPs, and aqueous/heterogeneous processes increase UFP mode diameters. UFPs are the highest in winter due to the highest primary particle emission rates and new particle formation rates, and CHO fractions are the highest in summer due to the strongest photooxidation.
Jiaqi Wang, Jian Gao, Fei Che, Xin Yang, Yuanqin Yang, Lei Liu, Yan Xiang, and Haisheng Li
Atmos. Chem. Phys., 23, 14715–14733, https://doi.org/10.5194/acp-23-14715-2023, https://doi.org/10.5194/acp-23-14715-2023, 2023
Short summary
Short summary
Regional-scale observations of surface O3, PM2.5 and its major chemical species, mixing layer height (MLH), and other meteorological parameters were made in the North China Plain during summer. Unlike the cold season, synchronized increases in MDA8 O3 and PM2.5 under medium MLH conditions have been witnessed. The increasing trend of PM2.5 was associated with enhanced secondary chemical formation. The correlation between MLH and secondary air pollutants should be treated with care in hot seasons.
Takuma Miyakawa, Akinori Ito, Chunmao Zhu, Atsushi Shimizu, Erika Matsumoto, Yusuke Mizuno, and Yugo Kanaya
Atmos. Chem. Phys., 23, 14609–14626, https://doi.org/10.5194/acp-23-14609-2023, https://doi.org/10.5194/acp-23-14609-2023, 2023
Short summary
Short summary
This study conducted semi-continuous measurements of PM2.5 aerosols and their elemental composition in western Japan, during spring 2018. It analyzed the emissions, transport, and wet removal of elements such as Pb, Cu, Fe, and Mn. It also assessed the accuracy of modeled concentrations and found overestimations of BC and underestimations of Cu and anthropogenic Fe in East Asia. Insights into emissions, removals, and source apportionment of trace metals in the East Asian outflow were provided.
Jingjing Meng, Yachen Wang, Yuanyuan Li, Tonglin Huang, Zhifei Wang, Yiqiu Wang, Min Chen, Zhanfang Hou, Houhua Zhou, Keding Lu, Kimitaka Kawamura, and Pingqing Fu
Atmos. Chem. Phys., 23, 14481–14503, https://doi.org/10.5194/acp-23-14481-2023, https://doi.org/10.5194/acp-23-14481-2023, 2023
Short summary
Short summary
This study investigated the effect of COVID-19 lockdown (LCD) measures on the formation and evolutionary process of diacids and related compounds from field observations. Results demonstrate that more aged organic aerosols are observed during the LCD due to the enhanced photochemical oxidation. Our study also found that the reactivity of 13C was higher than that of 12C in the gaseous photochemical oxidation, leading to higher δ13C values of C2 during the LCD than before the LCD.
Christopher J. Hennigan, Michael McKee, Vikram Pratap, Bryanna Boegner, Jasper Reno, Lucia Garcia, Madison McLaren, and Sara M. Lance
Atmos. Chem. Phys., 23, 14437–14449, https://doi.org/10.5194/acp-23-14437-2023, https://doi.org/10.5194/acp-23-14437-2023, 2023
Short summary
Short summary
This study characterized the optical properties of light-absorbing organic compounds, called brown carbon (BrC), in atmospheric cloud water samples. In all samples, light absorption by BrC increased linearly with increasing pH. There was variability in the sensitivity of the absorption–pH relationship, depending on the degree of influence from fire emissions. Overall, these results show that the climate forcing of BrC is quite strongly affected by its pH-dependent absorption.
Máté Vörösmarty, Gaëlle Uzu, Jean-Luc Jaffrezo, Pamela Dominutti, Zsófia Kertész, Enikő Papp, and Imre Salma
Atmos. Chem. Phys., 23, 14255–14269, https://doi.org/10.5194/acp-23-14255-2023, https://doi.org/10.5194/acp-23-14255-2023, 2023
Short summary
Short summary
Poor air quality caused by high concentrations of particulate matter is one of the most severe public health concerns for humans worldwide. One of the most important biological mechanisms inducing adverse health effects is the oxidant–antioxidant imbalance. We showed that the oxidative stress changed substantially and in a complex manner with location and season. Biomass burning exhibited the dominant influence, while motor vehicles played an important role in the non-heating period.
Da Lu, Hao Li, Mengke Tian, Guochen Wang, Xiaofei Qin, Na Zhao, Juntao Huo, Fan Yang, Yanfen Lin, Jia Chen, Qingyan Fu, Yusen Duan, Xinyi Dong, Congrui Deng, Sabur F. Abdullaev, and Kan Huang
Atmos. Chem. Phys., 23, 13853–13868, https://doi.org/10.5194/acp-23-13853-2023, https://doi.org/10.5194/acp-23-13853-2023, 2023
Short summary
Short summary
Environmental conditions during dust are usually not favorable for secondary aerosol formation. However in this study, an unusual dust event was captured in a Chinese mega-city and showed “anomalous” meteorology and a special dust backflow transport pathway. The underlying formation mechanisms of secondary aerosols are probed in the context of this special dust event. This study shows significant implications for the varying dust aerosol chemistry in the future changing climate.
Thomas Audoux, Benoit Laurent, Karine Desboeufs, Gael Noyalet, Franck Maisonneuve, Olivier Lauret, and Servanne Chevaillier
Atmos. Chem. Phys., 23, 13485–13503, https://doi.org/10.5194/acp-23-13485-2023, https://doi.org/10.5194/acp-23-13485-2023, 2023
Short summary
Short summary
In the Paris region, a campaign was conducted to study wet deposition of aerosol particles during rainfall events. Simultaneous measurements of aerosol and wet deposition allowed us to discuss their transfer from the atmosphere to rain. Chemical evolution within events revealed meteorology, atmospheric conditions and local vs. long range sources as key factors. This study highlights the variability of wet deposition and the need to consider event-specific factors to understand its mechanisms.
Ting Yang, Yu Xu, Qing Ye, Yi-Jia Ma, Yu-Chen Wang, Jian-Zhen Yu, Yu-Sen Duan, Chen-Xi Li, Hong-Wei Xiao, Zi-Yue Li, Yue Zhao, and Hua-Yun Xiao
Atmos. Chem. Phys., 23, 13433–13450, https://doi.org/10.5194/acp-23-13433-2023, https://doi.org/10.5194/acp-23-13433-2023, 2023
Short summary
Short summary
In this study, 130 OS species were quantified in ambient fine particulate matter (PM2.5) collected in urban and suburban Shanghai (East China) in the summer of 2021. The daytime OS formation was concretized based on the interactions among OSs, ultraviolet (UV), ozone (O3), and sulfate. Our finding provides field evidence for the influence of photochemical process and anthropogenic sulfate on OS formation and has important implications for the mitigation of organic particulate pollution.
Miao Zhong, Jianzhong Xu, Huiqin Wang, Li Gao, Haixia Zhu, Lixiang Zhai, Xinghua Zhang, and Wenhui Zhao
Atmos. Chem. Phys., 23, 12609–12630, https://doi.org/10.5194/acp-23-12609-2023, https://doi.org/10.5194/acp-23-12609-2023, 2023
Short summary
Short summary
This study focus on coal-combustion-dominated aerosol in urban areas in northwestern China and combines the results of optical measurement and chemical analysis to deduce the evolution of these characteristics in the atmosphere, which has previously been unknown. The results provide insights into the effects of atmospheric processes and emissions on brown carbon properties.
Li Wu, Hyo-Jin Eom, Hanjin Yoo, Dhrubajyoti Gupta, Hye-Rin Cho, Pingqing Fu, and Chul-Un Ro
Atmos. Chem. Phys., 23, 12571–12588, https://doi.org/10.5194/acp-23-12571-2023, https://doi.org/10.5194/acp-23-12571-2023, 2023
Short summary
Short summary
Hygroscopicity of ambient marine aerosols is of critical relevance to investigate their atmospheric impacts, which, however, remain uncertain due to their complex compositions and mixing states. Therefore, a study on the hygroscopic behavior of ambient marine aerosols for understanding the phase states when interacting with water vapor at different RH levels and their subsequent impacts on the heterogeneous chemical reactions, atmospheric environment, and human health is of vital importance.
Yutong Liang, Rebecca A. Wernis, Kasper Kristensen, Nathan M. Kreisberg, Philip L. Croteau, Scott C. Herndon, Arthur W. H. Chan, Nga L. Ng, and Allen H. Goldstein
Atmos. Chem. Phys., 23, 12441–12454, https://doi.org/10.5194/acp-23-12441-2023, https://doi.org/10.5194/acp-23-12441-2023, 2023
Short summary
Short summary
We measured the gas–particle partitioning behaviors of biomass burning markers and examined the effect of wildfire organic aerosol on the partitioning of semivolatile organic compounds. Most compounds measured are less volatile than model predictions. Wildfire aerosol enhanced the condensation of polar compounds and caused some nonpolar (e.g., polycyclic aromatic hydrocarbons) compounds to partition into the gas phase, thus affecting their lifetimes in the atmosphere and the mode of exposure.
Bojiang Su, Xinhui Bi, Zhou Zhang, Yue Liang, Congbo Song, Tao Wang, Yaohao Hu, Lei Li, Zhen Zhou, Jinpei Yan, Xinming Wang, and Guohua Zhang
Atmos. Chem. Phys., 23, 10697–10711, https://doi.org/10.5194/acp-23-10697-2023, https://doi.org/10.5194/acp-23-10697-2023, 2023
Short summary
Short summary
During the R/V Xuelong cruise observation over the Ross Sea, Antarctica, the mass concentrations of water-soluble Ca2+ and the mass spectra of individual calcareous particles were measured. Our results indicated that lower temperature, lower wind speed, and the presence of sea ice may facilitate Ca2+ enrichment in sea spray aerosols and highlighted the potential contribution of organically complexed calcium to calcium enrichment, which is inaccurate based solely on water-soluble Ca2+ estimation.
Valeria Mardoñez, Marco Pandolfi, Lucille Joanna S. Borlaza, Jean-Luc Jaffrezo, Andrés Alastuey, Jean-Luc Besombes, Isabel Moreno R., Noemi Perez, Griša Močnik, Patrick Ginot, Radovan Krejci, Vladislav Chrastny, Alfred Wiedensohler, Paolo Laj, Marcos Andrade, and Gaëlle Uzu
Atmos. Chem. Phys., 23, 10325–10347, https://doi.org/10.5194/acp-23-10325-2023, https://doi.org/10.5194/acp-23-10325-2023, 2023
Short summary
Short summary
La Paz and El Alto are two fast-growing, high-altitude Bolivian cities forming the second-largest metropolitan area in the country. The sources of particulate matter (PM) in this conurbation were not previously investigated. This study identified 11 main sources of PM, of which dust and vehicular emissions stand out as the main ones. The influence of regional biomass combustion and local waste combustion was also observed, with the latter being a major source of hazardous compounds.
Sayako Ueda, Yoko Iwamoto, Fumikazu Taketani, Mingxu Liu, and Hitoshi Matsui
Atmos. Chem. Phys., 23, 10117–10135, https://doi.org/10.5194/acp-23-10117-2023, https://doi.org/10.5194/acp-23-10117-2023, 2023
Short summary
Short summary
We examine iron in atmospheric fine aerosol particles collected over the Indian Ocean during shipborne observations in November 2018. Transmission electron microscopy analysis with water dialysis shows that various types of iron (fly ash, iron oxide, and mineral dust) co-exist with ammonium sulfate and that their solubility differs depending on the iron type. Using PM2.5 bulk samples and global model simulations, we elucidate their origins, aging, and implications for present iron simulations.
Qiongqiong Wang, Shuhui Zhu, Shan Wang, Cheng Huang, Yunsen Duan, and Jian Zhen Yu
EGUsphere, https://doi.org/10.5194/egusphere-2023-1846, https://doi.org/10.5194/egusphere-2023-1846, 2023
Short summary
Short summary
We investigated short-term source apportionment of PM2.5 utilizing rolling positive matrix factorization (PMF) and online PM chemical speciation data, which included source-specific organic tracers collected over a period of 37 days during the winter of 2019–2020 in suburban Shanghai, China. The findings highlight that by imposing constraints on the primary source profiles, short-term PMF analysis successfully replicated both the individual primary sources and the total secondary sources.
Farhan R. Nursanto, Roy Meinen, Rupert Holzinger, Maarten C. Krol, Xinya Liu, Ulrike Dusek, Bas Henzing, and Juliane L. Fry
Atmos. Chem. Phys., 23, 10015–10034, https://doi.org/10.5194/acp-23-10015-2023, https://doi.org/10.5194/acp-23-10015-2023, 2023
Short summary
Short summary
Particulate matter (PM) is a harmful air pollutant that depends on the complex mixture of natural and anthropogenic emissions into the atmosphere. Thus, in different regions and seasons, the way that PM is formed and grows can differ. In this study, we use a combined statistical analysis of the chemical composition and particle size distribution to determine what drives particle formation and growth across seasons, using varying wind directions to elucidate the role of different sources.
Hanjin Yoo, Li Wu, Hong Geng, and Chul-Un Ro
EGUsphere, https://doi.org/10.5194/egusphere-2023-1787, https://doi.org/10.5194/egusphere-2023-1787, 2023
Short summary
Short summary
We conducted an investigation of atmospheric aerosols collected in Seoul, Korea, during the KORUS-AQ campaign, on a single-particle basis. We were able to identify their sources, atmospheric fate, and the impacts of local emissions and long-range transport on aerosol composition. Additionally, we traced potential sources of non-exhaust heavy metal particles. This comprehensive analysis provides valuable insights into the complex dynamics of urban aerosols.
Kohei Sakata, Aya Sakaguchi, Yoshiaki Yamakawa, Chihiro Miyamoto, Minako Kurisu, and Yoshio Takahashi
Atmos. Chem. Phys., 23, 9815–9836, https://doi.org/10.5194/acp-23-9815-2023, https://doi.org/10.5194/acp-23-9815-2023, 2023
Short summary
Short summary
Anthropogenic iron is the dominant source of dissolved Fe in aerosol particles, but its contribution to dissolved Fe in aerosol particles has not been quantitatively evaluated. We established the molar concentration ratio of dissolved Fe to dissolved Al as a new indicator to evaluate the contribution of anthropogenic iron. As a result, about 10 % of dissolved Fe in aerosol particles was derived from anthropogenic iron when aerosol particles were transported from East Asia to the Pacific Ocean.
Li Li, Qiyuan Wang, Jie Tian, Huikun Liu, Yong Zhang, Steven Sai Hang Ho, Weikang Ran, and Junji Cao
Atmos. Chem. Phys., 23, 9597–9612, https://doi.org/10.5194/acp-23-9597-2023, https://doi.org/10.5194/acp-23-9597-2023, 2023
Short summary
Short summary
The Tibetan Plateau has a unique geographical location, but there is a lack of detailed research on the real-time characteristics of full aerosol composition. This study elaborates the changes in chemical characteristics between transport and local fine particles during the pre-monsoon, reveals the size distribution and the mixing states of different individual particles, and highlights the contributions of photooxidation and aqueous reaction to the formation of the secondary species.
Erin K. Boedicker, Elisabeth Andrews, Patrick J. Sheridan, and Patricia K. Quinn
Atmos. Chem. Phys., 23, 9525–9547, https://doi.org/10.5194/acp-23-9525-2023, https://doi.org/10.5194/acp-23-9525-2023, 2023
Short summary
Short summary
We present 15 years of measurements from a marine site on the northern California coast and characterize the seasonal trends of aerosol ion composition and optical properties at the site. We investigate the relationship between the chemical and optical properties and show that they both support similar seasonal variations in aerosol sources at the site. Additionally, we show through comparisons to other marine aerosol observations that the site is representative of a clean marine environment.
Qian Li, Dantong Liu, Xiaotong Jiang, Ping Tian, Yangzhou Wu, Siyuan Li, Kang Hu, Quan Liu, Mengyu Huang, Ruijie Li, Kai Bi, Shaofei Kong, Deping Ding, and Chenjie Yu
Atmos. Chem. Phys., 23, 9439–9453, https://doi.org/10.5194/acp-23-9439-2023, https://doi.org/10.5194/acp-23-9439-2023, 2023
Short summary
Short summary
By attributing the shortwave absorption from black carbon, primary organic aerosol and secondary organic aerosol in a suburban environment, we firstly observed that the photochemically produced nitrogen-containing secondary organic aerosol may contribute to the enhancement of brown carbon absorption, partly compensating for some bleaching effect on the absorption of primary organic aerosol, hereby exerting radiative impacts.
Yong Zhang, Jie Tian, Qiyuan Wang, Lu Qi, Manousos Ioannis Manousakas, Yuemei Han, Weikang Ran, Yele Sun, Huikun Liu, Renjian Zhang, Yunfei Wu, Tianqu Cui, Kaspar Rudolf Daellenbach, Jay Gates Slowik, André S. H. Prévôt, and Junji Cao
Atmos. Chem. Phys., 23, 9455–9471, https://doi.org/10.5194/acp-23-9455-2023, https://doi.org/10.5194/acp-23-9455-2023, 2023
Short summary
Short summary
PM2.5 pollution still frequently occurs in northern China during winter, and it is necessary to figure out the causes of air pollution based on intensive real-time measurement. The findings elaborate the chemical characteristics and source contributions of PM2.5 in three pilot cities, reveal potential formation mechanisms of secondary aerosols, and highlight the importance of controlling biomass burning and inhibiting generation of secondary aerosol for air quality improvement.
Qi Yuan, Yuanyuan Wang, Yixin Chen, Siyao Yue, Jian Zhang, Yinxiao Zhang, Liang Xu, Wei Hu, Dantong Liu, Pingqing Fu, Huiwang Gao, and Weijun Li
Atmos. Chem. Phys., 23, 9385–9399, https://doi.org/10.5194/acp-23-9385-2023, https://doi.org/10.5194/acp-23-9385-2023, 2023
Short summary
Short summary
This study for the first time found large amounts of liquid–liquid phase separation particles with soot redistributing in organic coatings instead of sulfate cores in the eastern Tibetan Plateau atmosphere. The particle size and the ratio of the organic matter coating thickness to soot size are two of the major possible factors that likely affect the soot redistribution process. The soot redistribution process promoted the morphological compaction of soot particles.
Yuting Lyu, Yin Hau Lam, Yitao Li, Nadine Borduas-Dedekind, and Theodora Nah
Atmos. Chem. Phys., 23, 9245–9263, https://doi.org/10.5194/acp-23-9245-2023, https://doi.org/10.5194/acp-23-9245-2023, 2023
Short summary
Short summary
We measured singlet oxygen (1O2*) and triplet excited states of organic matter (3C*) in illuminated aqueous extracts of PM2.5 collected in different seasons at different sites in Hong Kong SAR, South China. In contrast to the locations, seasonality had significant effects on 3C* and 1O2* production due to seasonal variations in long-range air mass transport. The steady-state concentrations of 3C* and 1O2* correlated with the concentration and absorbance of water-soluble organic carbon.
Karine Desboeufs, Paola Formenti, Raquel Torres-Sánchez, Kerstin Schepanski, Jean-Pierre Chaboureau, Hendrik Andersen, Jan Cermak, Stefanie Feuerstein, Benoit Laurent, Danitza Klopper, Andreas Namwoonde, Mathieu Cazaunau, Servanne Chevaillier, Anaïs Feron, Cecile Mirande-Bret, Sylvain Triquet, and Stuart J. Piketh
EGUsphere, https://doi.org/10.5194/egusphere-2023-1736, https://doi.org/10.5194/egusphere-2023-1736, 2023
Short summary
Short summary
This study investigates the fractional solubility of iron (Fe) in dust particles along the coast of Namibia, a critical region for the atmospheric Fe supply of the Southern Atlantic Ocean. Our results suggest a possible two-way interplay whereby marine biogenic emissions from the coastal marine ecosystems to the atmosphere would increase the solubility of Fe-bearing dust by photo-reduction processes. The subsequent deposition of soluble Fe could act to further enhance marine biogenic emissions.
Sophie L. Haslett, David M. Bell, Varun Kumar, Jay G. Slowik, Dongyu S. Wang, Suneeti Mishra, Neeraj Rastogi, Atinderpal Singh, Dilip Ganguly, Joel Thornton, Feixue Zheng, Yuanyuan Li, Wei Nie, Yongchun Liu, Wei Ma, Chao Yan, Markku Kulmala, Kaspar R. Daellenbach, David Hadden, Urs Baltensperger, Andre S. H. Prevot, Sachchida N. Tripathi, and Claudia Mohr
Atmos. Chem. Phys., 23, 9023–9036, https://doi.org/10.5194/acp-23-9023-2023, https://doi.org/10.5194/acp-23-9023-2023, 2023
Short summary
Short summary
In Delhi, some aspects of daytime and nighttime atmospheric chemistry are inverted, and parodoxically, vehicle emissions may be limiting other forms of particle production. This is because the nighttime emissions of nitrogen oxide (NO) by traffic and biomass burning prevent some chemical processes that would otherwise create even more particles and worsen the urban haze.
Rose Marie Miller, Robert M. Rauber, Larry Di Girolamo, Matthew Rilloraza, Dongwei Fu, Greg M. McFarquhar, Stephen W. Nesbitt, Luke D. Ziemba, Sarah Woods, and Kenneth Lee Thornhill
Atmos. Chem. Phys., 23, 8959–8977, https://doi.org/10.5194/acp-23-8959-2023, https://doi.org/10.5194/acp-23-8959-2023, 2023
Short summary
Short summary
The influence of human-produced aerosols on clouds remains one of the uncertainties in radiative forcing of Earth’s climate. Measurements of aerosol chemistry from sources around the Philippines illustrate the linkage between aerosol chemical composition and cloud droplet characteristics. Differences in aerosol chemical composition in the marine layer from biomass burning, industrial, ship-produced, and marine aerosols are shown to impact cloud microphysical structure just above cloud base.
Yiyu Cai, Chenshuo Ye, Wei Chen, Weiwei Hu, Wei Song, Yuwen Peng, Shan Huang, Jipeng Qi, Sihang Wang, Chaomin Wang, Caihong Wu, Zelong Wang, Baolin Wang, Xiaofeng Huang, Lingyan He, Sasho Gligorovski, Bin Yuan, Min Shao, and Xinming Wang
Atmos. Chem. Phys., 23, 8855–8877, https://doi.org/10.5194/acp-23-8855-2023, https://doi.org/10.5194/acp-23-8855-2023, 2023
Short summary
Short summary
We studied the variability and molecular composition of ambient oxidized organic nitrogen (OON) in both gas and particle phases using a state-of-the-art online mass spectrometer in urban air. Biomass burning and secondary formation were found to be the two major sources of OON. Daytime nitrate radical chemistry for OON formation was more important than previously thought. Our results improved the understanding of the sources and molecular composition of OON in the polluted urban atmosphere.
Frédéric Ledoux, Cloé Roche, Gilles Delmaire, Gilles Roussel, Olivier Favez, Marc Fadel, and Dominique Courcot
Atmos. Chem. Phys., 23, 8607–8622, https://doi.org/10.5194/acp-23-8607-2023, https://doi.org/10.5194/acp-23-8607-2023, 2023
Short summary
Short summary
We quantify the emissions from the marine sector in northern France, whether from natural or human-made sources. Therefore, a 1-year PM10 sampling campaign was conducted at a French coastal site. Results showed that sea salts contributed 37 %, while secondary nitrate and sulfate contributed 42 %, biomass burning 8 %, and heavy-fuel-oil combustion from shipping emissions 5 %. Sources contributing more than 80 % of PM10 are of regional and/or long-range origin.
Sebastian Zeppenfeld, Manuela van Pinxteren, Markus Hartmann, Moritz Zeising, Astrid Bracher, and Hartmut Herrmann
EGUsphere, https://doi.org/10.5194/egusphere-2023-1607, https://doi.org/10.5194/egusphere-2023-1607, 2023
Short summary
Short summary
Marine carbohydrates are produced in the surface of the ocean, enter the atmophere as part of sea spray aerosol particles and potentially contribute to the formation of clouds. Here, we present the results of a sea-air transfer study of marine carbohydrates conducted in the high Arctic. Besides a chemo-selective transfer, we observed a quick atmospheric aging of carbohydrates, possibly as a result of both biotic and abiotic processes.
Shuhui Zhu, Min Zhou, Liping Qiao, Dan Dan Huang, Qiongqiong Wang, Shan Wang, Yaqin Gao, Shengao Jing, Qian Wang, Hongli Wang, Changhong Chen, Cheng Huang, and Jian Zhen Yu
Atmos. Chem. Phys., 23, 7551–7568, https://doi.org/10.5194/acp-23-7551-2023, https://doi.org/10.5194/acp-23-7551-2023, 2023
Short summary
Short summary
Organic aerosol (OA) is increasingly important in urban PM2.5 pollution as inorganic ions are becoming lower. We investigated the chemical characteristics of OA during nine episodes in Shanghai. The availability of bi-hourly measured molecular markers revealed that the control of local urban sources such as vehicular and cooking emissions lessened the severity of local episodes. Regional control of precursors and biomass burning would reduce PM2.5 episodes influenced by regional transport.
Karolina Siegel, Yvette Gramlich, Sophie L. Haslett, Gabriel Freitas, Radovan Krejci, Paul Zieger, and Claudia Mohr
Atmos. Chem. Phys., 23, 7569–7587, https://doi.org/10.5194/acp-23-7569-2023, https://doi.org/10.5194/acp-23-7569-2023, 2023
Short summary
Short summary
Hydroperoxymethyl thioformate (HPMTF) is a recently discovered oxidation product of dimethyl sulfide (DMS). We present a full year of concurrent gas- and particle-phase observations of HPMTF and other DMS oxidation products from the Arctic. We did not observe significant amounts of HPMTF in the particle phase but a good agreement between gas-phase HMPTF and methanesulfonic acid in the summer. Our study provides information about the relationship between HPMTF and other DMS oxidation products.
Samira Atabakhsh, Laurent Poulain, Gang Chen, Francesco Canonaco, André S. H. Prévôt, Mira Pöhlker, Alfred Wiedensohler, and Hartmut Herrmann
Atmos. Chem. Phys., 23, 6963–6988, https://doi.org/10.5194/acp-23-6963-2023, https://doi.org/10.5194/acp-23-6963-2023, 2023
Short summary
Short summary
The study focuses on the aerosol chemical variations found in the rural-background station of Melpitz based on ACSM and MAAP measurements. Source apportionment on both organic aerosol (OA) and black carbon (eBC) was performed, and source seasonality was also linked to air mass trajectories. Overall, three anthropogenic sources were identified in OA and eBC plus two additional aged OA. Our results demonstrate the influence of transported coal-combustion-related OA even during summer time.
Yanqin Ren, Gehui Wang, Jie Wei, Jun Tao, Zhisheng Zhang, and Hong Li
Atmos. Chem. Phys., 23, 6835–6848, https://doi.org/10.5194/acp-23-6835-2023, https://doi.org/10.5194/acp-23-6835-2023, 2023
Short summary
Short summary
Nine quantified nitrated aromatic compounds (NACs) in PM2.5 were examined at the peak of Mt. Wuyi. They manifested a significant rise in overall abundance in the winter and autumn. The transport of contaminants had a significant impact on NACs. Under low-NOx conditions, the formation of NACs was comparatively sensitive to NO2, suggesting that NACs would become significant in the aerosol characteristics when nitrate concentrations decreased as a result of emission reduction measures.
Yu Xu, Xin-Ni Dong, Chen He, Dai-She Wu, Hong-Wei Xiao, and Hua-Yun Xiao
Atmos. Chem. Phys., 23, 6775–6788, https://doi.org/10.5194/acp-23-6775-2023, https://doi.org/10.5194/acp-23-6775-2023, 2023
Short summary
Short summary
The air pollution associated with fine particles and secondary organic aerosol is not weakened by the application of mist cannon trucks but rather is aggravated. Our results provide not only new insights into the formation processes of aerosol water-soluble organic compounds associated with the water mist sprayed by mist cannon trucks in the road atmospheric environment but also crucial information for the decision makers to regulate the operation of mist cannon trucks in many cities in China.
Manuela van Pinxteren, Sebastian Zeppenfeld, Khanneh Wadinga Fomba, Nadja Triesch, Sanja Frka, and Hartmut Herrmann
Atmos. Chem. Phys., 23, 6571–6590, https://doi.org/10.5194/acp-23-6571-2023, https://doi.org/10.5194/acp-23-6571-2023, 2023
Short summary
Short summary
Important marine organic carbon compounds were identified in the Atlantic Ocean and marine aerosol particles. These compounds were strongly enriched in the atmosphere. Their enrichment was, however, not solely explained via sea-to-air transfer but also via atmospheric in situ formation. The identified compounds constituted about 50 % of the organic carbon on the aerosol particles, and a pronounced coupling between ocean and atmosphere for this oligotrophic region could be concluded.
Aliki Christodoulou, Iasonas Stavroulas, Mihalis Vrekoussis, Maximillien Desservettaz, Michael Pikridas, Elie Bimenyimana, Jonilda Kushta, Matic Ivančič, Martin Rigler, Philippe Goloub, Konstantina Oikonomou, Roland Sarda-Estève, Chrysanthos Savvides, Charbel Afif, Nikos Mihalopoulos, Stéphane Sauvage, and Jean Sciare
Atmos. Chem. Phys., 23, 6431–6456, https://doi.org/10.5194/acp-23-6431-2023, https://doi.org/10.5194/acp-23-6431-2023, 2023
Short summary
Short summary
Our study presents, for the first time, a detailed source identification of aerosols at an urban background site in Cyprus (eastern Mediterranean), a region strongly impacted by climate change and air pollution. Here, we identify an unexpected high contribution of long-range transported pollution from fossil fuel sources in the Middle East, highlighting an urgent need to further characterize these fast-growing emissions and their impacts on regional atmospheric composition, climate, and health.
Tingting Li, Jun Li, Zeyu Sun, Hongxing Jiang, Chongguo Tian, and Gan Zhang
Atmos. Chem. Phys., 23, 6395–6407, https://doi.org/10.5194/acp-23-6395-2023, https://doi.org/10.5194/acp-23-6395-2023, 2023
Short summary
Short summary
N-NH4+ and N-NO3- were vital components in nitrogenous aerosols and contributed 69 % to total nitrogen in PM2.5. Coal combustion was still the most important source of urban atmospheric NO3-. However, the non-agriculture sources play an increasingly important role in NH4+ emissions.
Yuan Cheng, Xu-bing Cao, Jiu-meng Liu, Ying-jie Zhong, Qin-qin Yu, Qiang Zhang, and Ke-bin He
Atmos. Chem. Phys., 23, 6241–6253, https://doi.org/10.5194/acp-23-6241-2023, https://doi.org/10.5194/acp-23-6241-2023, 2023
Short summary
Short summary
Brown carbon (BrC) aerosols were explored in the northernmost megacity in China during a frigid winter and an agricultural-fire-impacted spring. BrC was more light absorbing at night for both seasons, with more pronounced diurnal variations in spring, and the dominant drivers were identified as regulations on heavy-duty diesel trucks and open burning, respectively. Agricultural fires resulted in unique absorption spectra of BrC, which were characterized by a distinct peak at ∼365 nm.
Nansi Fakhri, Robin Stevens, Arnold Downey, Konstantina Oikonomou, Jean Sciare, Charbel Afif, and Patrick L. Hayes
EGUsphere, https://doi.org/10.5194/egusphere-2023-1039, https://doi.org/10.5194/egusphere-2023-1039, 2023
Short summary
Short summary
The chemical composition of PM2.5 and emission sources as well as potential human health risk associated with trace elements are investigated for an urban site in Montréal over a 3-month period (August–November). To our knowledge, this study represents the first time that such extensive composition measurements were included in an urban source apportionment study in Canada and provides greater resolution of PM2.5 sources than has been previously achieved using PMF in similar Canadian studies.
Lisa Azzarello, Rebecca A. Washenfelder, Michael A. Robinson, Alessandro Franchin, Caroline C. Womack, Christopher D. Holmes, Steven S. Brown, Ann Middlebrook, Tim Newberger, Colm Sweeney, and Cora J. Young
EGUsphere, https://doi.org/10.5194/egusphere-2023-1128, https://doi.org/10.5194/egusphere-2023-1128, 2023
Short summary
Short summary
We present a molecular size-resolved offline analysis of water-soluble brown carbon collected on an aircraft during FIREX-AQ. The smoke plumes were aged 0 to 5 h where absorption was dominated by small molecular weight molecules, brown carbon absorption downwind did not consistently decrease, and the measurements differed from online absorption measurements of the same samples. We show how differences between online and offline absorption could be related to different measurement conditions.
Chen He, Hanxiong Che, Zhier Bao, Yiliang Liu, Qing Li, Miao Hu, Jiawei Zhou, Shumin Zhang, Xiaojiang Yao, Quan Shi, Chunmao Chen, Yan Han, Lingshuo Meng, Xin Long, Fumo Yang, and Yang Chen
EGUsphere, https://doi.org/10.5194/egusphere-2023-936, https://doi.org/10.5194/egusphere-2023-936, 2023
Short summary
Short summary
We examined the daily evolution of high molecular weight organic compounds with molecular weights up to 1000 Da in order to comprehend their behavior in the atmosphere under actual conditions. Those compounds were proven to undergo multi-generation oxidation, carboxylation, and nitrification via both day- and night-time chemistry.
Eric Schneider, Hendryk Czech, Olga Popovicheva, Marina Chichaeva, Vasily Kobelev, Nikolay Kasimov, Tatiana Minkina, Christopher Paul Rüger, and Ralf Zimmermann
EGUsphere, https://doi.org/10.5194/egusphere-2023-769, https://doi.org/10.5194/egusphere-2023-769, 2023
Short summary
Short summary
This study provides insights into the complex chemical composition of long-range transported wildfire plumes from Yakutia, which underwent different levels of atmospheric processing. With mass complementary mass spectrometric techniques, we improve our understanding of the chemical processes and atmospheric fate of wildfire plumes. Unprecedented high levels of carbonaceous aerosols crossed the polar circle with implications for the Arctic ecosystem and consequently climate.
Eka Dian Pusfitasari, Jose Ruiz-Jimenez, Aleksi Tiusanen, Markus Suuronen, Jesse Haataja, Yusheng Wu, Juha Kangasluoma, Krista Luoma, Tuukka Petäjä, Matti Jussila, Kari Hartonen, and Marja-Liisa Riekkola
Atmos. Chem. Phys., 23, 5885–5904, https://doi.org/10.5194/acp-23-5885-2023, https://doi.org/10.5194/acp-23-5885-2023, 2023
Short summary
Short summary
A miniaturized air-sampling drone system was successfully applied for the collection of volatile organic compounds (VOCs) and for the measurement of black carbon (BC) and total particle number concentrations in atmospheric air. Here we report, for the first time, the vertical profiles of BC and aerosol number concentrations above the boreal forest in Hyytiälä (Finland) at high altitudes close to the boundary layer in autumn 2021. VOC composition with its distribution was studied as well.
Sunhye Kim, Jo Machesky, Drew R. Gentner, and Albert A. Presto
EGUsphere, https://doi.org/10.5194/egusphere-2023-885, https://doi.org/10.5194/egusphere-2023-885, 2023
Short summary
Short summary
Cooking emissions are often an overlooked source of air pollution. To better understand them, we used a mobile laboratory and measured the characteristics of particles emitted by cooking sites in two cities. Our findings show that cooking releases a substantial number of fine particles into the air. While most emissions were similar, a bakery site showed differences with higher nitrogen compound levels. Thus, understanding particle emissions from different cooking activities is crucial.
Yifang Gu, Ru-Jin Huang, Jing Duan, Wei Xu, Chunshui Lin, Haobin Zhong, Ying Wang, Haiyan Ni, Quan Liu, Ruiguang Xu, Litao Wang, and Yong Jie Li
Atmos. Chem. Phys., 23, 5419–5433, https://doi.org/10.5194/acp-23-5419-2023, https://doi.org/10.5194/acp-23-5419-2023, 2023
Short summary
Short summary
Secondary organic aerosol (SOA) can be produced by various pathways, but its formation mechanisms are unclear. Observations were conducted in the North China Plain during a highly oxidizing atmosphere in summer. We found that fast photochemistry dominated SOA formation during daytime. Two types of aqueous-phase chemistry (nocturnal and daytime processing) take place at high relative humidity. The potential transformation from primary organic aerosol (POA) to SOA was also an important pathway.
Cited articles
Bidleman, T. F., Billings, W. N., and Foreman, W. T.: Vapor-particle
partitioning of semivolatile organic compounds: estimates from field
collections, Environ. Sci. Technol., 20, 1038–1043, 1986.
Bogdal, C., Scheringer, M., Abad, E., Abalos, M., van Bavel, B., Hagberg, J.,
and Fiedler, H.: Worldwide distribution of persistent organic pollutants in
air, including results of air monitoring by passive air sampling in five
continents, TrAC Trends Anal. Chem., 46, 150–161,
https://doi.org/10.1016/j.trac.2012.05.011, 2013.
Borrás, E., Sánchez, P., Muñoz, A., and Tortajada-Genaro, L. A.:
Development of a gas chromatography-mass spectrometry method for the
determination of pesticides in gaseous and particulate phases in the
atmosphere, Anal. Chim. Acta, 699, 57–65, https://doi.org/10.1016/j.aca.2011.05.009,
2011.
Cabrerizo, A., Dachs, J., Jones, K. C., and Barceló, D.: Soil-Air
exchange controls on background atmospheric concentrations of organochlorine
pesticides, Atmos. Chem. Phys., 11, 12799–12811,
https://doi.org/10.5194/acp-11-12799-2011, 2011.
Chevreuil, M., Garmouma, M., Teil, M.-J., and Chesterikoff, A.: Occurrence of
organochlorines (PCBs, pesticides) and herbicides (triazines, phenylureas) in
the atmosphere and in the fallout from urban and rural stations of the Paris
area, Sci. Total Environ., 182, 25–37, https://doi.org/10.1016/0048-9697(95)05032-9,
1996.
Cindoruk, S. S.: Atmospheric organochlorine pesticide (OCP) levels in a
metropolitan city in Turkey, Chemosphere, 82, 78–87,
https://doi.org/10.1016/j.chemosphere.2010.10.003, 2011.
Coscollà, C., Castillo, M., Pastor, A., and Yusa, V.: Determination of 40
currently used pesticides in airborne particulate matter (PM10) by
microwave-assisted extraction and gas chromatography coupled to triple
quadrupole mass spectrometry, Anal. Chim. Acta, 693, 72–81,
https://doi.org/10.1016/j.aca.2011.03.017, 2011.
Coscollà, C., Hart, E., Pastor, A., and Yusà, V.: LC-MS
characterization of contemporary pesticides in PM10 of Valencia Region,
Spain, Atmos. Environ., 77, 394–403, https://doi.org/10.1016/j.atmosenv.2013.05.022,
2013a.
Coscollà, C., Yahyaoui, A., Colin, P., Robin, C., Martinon, L., Val, S.,
Baeza-Squiban, A., Mellouki, A., and Yusà, V.: Particle size
distributions of currently used pesticides in a rural atmosphere of France,
Atmos. Environ., 81, 32–38, https://doi.org/10.1016/j.atmosenv.2013.08.057, 2013b.
Coscollà, C., Yahyaoui, A., Colin, P., Robin, C., Martinon, L., Val, S.,
Baeza-Squiban, A., Mellouki, A., and Yusà, V.: Particle size
distributions of currently used pesticides in a rural atmosphere of France,
Atmos. Environ., 81, 32–38, https://doi.org/10.1016/j.atmosenv.2013.08.057, 2013c.
Coscollà, C., Munoz, A., Borras, E., Vera, T., Rodenas, M., and Yusa, V.:
Particle size distributions of currently used pesticides in ambient air of an
agricultural Mediterranean area, Atmos. Environ., 95, 29–35,
https://doi.org/10.1016/j.atmosenv.2014.06.022, 2014.
Cousins, I. T. and Mackay, D.: Gas–particle partitioning of organic
compounds and its interpretation using relative solubilities, Environ. Sci.
Technol., 35, 643–647, https://doi.org/10.1021/es001123m, 2001.
Davie-Martin, C. L., Hageman, K. J., Chin, Y.-P., Rougé, V., and Fujita,
Y.: Influence of temperature, relative humidity, and soil properties on the
soil–air partitioning of semivolatile pesticides: Laboratory measurements
and predictive models, Environ. Sci. Technol., 49, 10431–10439,
https://doi.org/10.1021/acs.est.5b02525, 2015.
Degrendele, C., Okonski, K., Melymuk, L., Landlová, L., Kukučka, P.,
Čupr, P., and Klánová, J.: Size specific distribution of the
atmospheric particulate PCDD/Fs, dl-PCBs and PAHs on a seasonal scale:
Implications for cancer risks from inhalation, Atmos. Environ., 98, 410–416,
https://doi.org/10.1016/j.atmosenv.2014.09.001, 2014.
Dubus, I. G., Hollis, J. M., and Brown, C. D.: Pesticides in rainfall in
Europe, Environ. Pollut., 110, 331–344, https://doi.org/10.1016/S0269-7491(99)00295-X,
2000.
Eisenreich, S. J., Looney, B. B., and Thornton, J. D.: Airborne organic
contaminants in the Great Lakes ecosystem, Environ. Sci. Technol., 15,
30–38, https://doi.org/10.1021/es00083a002, 1981.
Englert, N.: Fine particles and human health – a review of epidemiological
studies, Toxicol. Lett., 149, 235–242, https://doi.org/10.1016/j.toxlet.2003.12.035,
2004.
European Commission: Commission Decision of 10 March 2004 concerning the non-inclusion
of atrazine in Annex I to Council Directive 91/414/EEC and the withdrawal of
authorisations for plant protection products containing this active substance
(notified under document number C(2004) 731), available at: http://eur-lex.europa.eu/legal-content/EN/TXT/?uri=CELEX%
3A32004D0248 (last access: December 2014), 2004.
FOCUS: Pesticides in Air: Considerations for Exposure Assessment, Rep. Focus
Work, Gr. Pestic. Air (FOCUS Air Group), 2008.
Garthwaite, D. G., Hudson, S., Barker, I., Parrish, G., Smith, L., and
Pietravalle, S.: Pesticide usage survey report 250. Arable crops in the
United Kingdom 2012 (including aerial applications 2012), Department for
Environment, Food & Rural Affairs, 2014.
Gil, Y. and Sinfort, C.: Emission of pesticides to the air during sprayer
application: A bibliographic review, Atmos. Environ., 39, 5183–5193,
https://doi.org/10.1016/j.atmosenv.2005.05.019, 2005.
Glotfelty, D. E., Leech, M. M., Jersey, J., and Taylor, A. W.: Volatilization
and Wind Erosion of Soil Surface Applied Atrazine, J. Agr. Food Chem.,
546–551, 1989.
Goss, K.-U.: Conceptual Model for the Adsorption of Organic Compounds from
the Gas Phase to Liquid and Solid Surfaces, Environ. Sci. Technol., 31,
3600–3605, https://doi.org/10.1021/es970361n, 1997.
Goss, K. U., Buschmann, J., and Schwarzenbach, R.: Adsorption of organic
vapors to air-dry soils: model predictions and experimental validation,
Environ. Sci. Technol., 38, 3667–3673, 2004.
Götz, C. W., Scheringer, M., MacLeod, M., Roth, C. M., and
Hungerbühler, K.: Alternative Approaches for Modeling Gas–Particle
Partitioning of Semivolatile Organic Chemicals: Model Development and
Comparison, Environ. Sci. Technol., 41, 1272–1278, https://doi.org/10.1021/es060583y,
2007.
Götz, C. W., Scheringer, M., MacLeod, M., Wegmann, F., and
Hungerbühler, K.: Regional differences in gas–particle partitioning and
deposition of semivolatile organic compounds on a global scale, Atmos.
Environ., 42, 554–567, https://doi.org/10.1016/j.atmosenv.2007.08.033, 2008.
Halse, A. K., Schlabach, M., Eckhardt, S., Sweetman, A., Jones, K. C., and
Breivik, K.: Spatial variability of POPs in European background air, Atmos.
Chem. Phys., 11, 1549–1564, https://doi.org/10.5194/acp-11-1549-2011, 2011.
Harner, T. and Bidleman, T. F.: Octanol-Air Partition Coefficient for Describing
Particle/Gas Partitioning of Aromatic Compounds in Urban Air, Environ. Sci. Technol., 32, 1494–1502, https://doi.org/10.1021/es970890r,
1998.
Hayward, S. J., Gouin, T., and Wania, F.: Levels and Seasonal Variability of
Pesticides in the Rural Atmosphere of Southern Ontario. J. Agric. Food Chem.
58, 1077–1084. https://doi.org/10.1021/jf902898f, 2010.
Hoff, R. M., Brice, K. A., and Halsall, C. J.: Nonlinearity in the slopes of
Clausius-Clapeyron plots for SVOCs, Environ. Sci. Technol., 32, 1793–1798,
1998.
Holoubek, I., Klánová, J., Jarkovský, J., and Kohoutek, J.:
Trends in background levels of persistent organic pollutants at Kosetice
observatory, Czech Republic. Part I. Ambient air and wet deposition
1996–2005, J. Environ. Monitor., 9, 557–563, 2007.
Holoubek, I., Dušek, L., Sáňka, M., Hofman, J., Čupr, P.,
Jarkovský, J., Zbíral, J., and Klánová, J.: Soil burdens of
persistent organic pollutants – Their levels, fate and risk. Part I.
Variation of concentration ranges according to different soil uses and
locations, Environ. Pollut., 157, 3207–3217,
https://doi.org/10.1016/j.envpol.2009.05.031, 2009.
Kannan, K., Ridal, J., and Struger, J.: Pesticides in the Great Lakes, in:
Persistent Organic Pollutants in the Great Lakes, edited by: Hites, R., The
Handbook of Environmental Chemistry, Springer Berlin Heidelberg, 151–199,
https://doi.org/10.1007/698_5_041, 2006.
Koblizková, M., Lee, S. C., and Harner, T.: Sorbent impregnated
polyurethane foam disk passive air samplers for investigating current-use
pesticides at the global scale, Atmos. Pollut. Res., 3, 456–462, 2012.
Lammel, G., Klánová, J., Kohoutek, J., Prokeš, R., Ries, L., and
Stohl, A.: Observation and origin of organochlorine compounds and polycyclic
aromatic hydrocarbons in the free troposphere over central Europe, Environ.
Pollut., 157, 3264–3271, https://doi.org/10.1016/j.envpol.2009.05.028, 2009.
Lee, R. G. M., Burnett, V., Harner, T., and Jones, K. C.: Short-term
temperature-dependent air-surface exchange and atmospheric concentrations of
polychlorinated naphthalenes and organochlorine pesticides. Environ. Sci.
Technol., 34, 393–398, https://doi.org/10.1021/es9907414, 2000.
Li, H., Ma, H., Lydy, M. J., and You, J.: Occurrence, seasonal variation and
inhalation exposure of atmospheric organophosphate and pyrethroid pesticides
in an urban community in South China, Chemosphere, 95, 363–369,
https://doi.org/10.1016/j.chemosphere.2013.09.046, 2014.
Li, J., Zhang, G., Guo, L., Xu, W., Li, X., Lee, C. S. L., Ding, A., and
Wang, T.: Organochlorine pesticides in the atmosphere of Guangzhou and Hong
Kong: Regional sources and long-range atmospheric transport, Atmos. Environ.,
41, 3889–3903, https://doi.org/10.1016/j.atmosenv.2006.12.052, 2007.
Li, Y. F. and Macdonald, R. W.: Sources and pathways of selected
organochlorine pesticides to the Arctic and the effect of pathway divergence
on HCH trends in biota: a review, Sci. Total Environ. 342, 87–106,
https://doi.org/10.1016/j.scitotenv.2004.12.027, 2005.
Lohmann, R. and Lammel, G.: Adsorptive and absorptive contributions to the
gas-particle partitioning of polycyclic aromatic hydrocarbons: State of
knowledge and recommended parametrization for modeling, Environ. Sci.
Technol., 38, 3793–3803, https://doi.org/10.1021/es035337q, 2004.
Lohmann, R., Klanova, J., Kukucka, P., Yonis, S., and Bollinger, K.: PCBs and
OCPs on a East-to-West Transect: The Importance of Major Currents and Net
Volatilization for PCBs in the Atlantic Ocean, Environ. Sci. Technol., 46,
10471–10479, https://doi.org/10.1021/es203459e, 2012.
Mackay, D.: Multimedia Environmental Models The Fugacity Approach, 2nd Edn.,
Lewis, Boca Raton, USA, 2001.
Mai, C., Theobald, N., Lammel, G., and Hühnerfuss, H.: Spatial, seasonal
and vertical distributions of currently-used pesticides in the marine
boundary layer of the North Sea, Atmos. Environ., 75, 92–102,
https://doi.org/10.1016/j.atmosenv.2013.04.027, 2013.
Majewski, M. S., Coupe, R. H., Foreman, W. T., and Capel, P. D.: Pesticides
in Mississippi air and rain: A comparison between 1995 and 2007, Environ.
Toxicol. Chem., 33, 1283–1293, https://doi.org/10.1002/etc.2550, 2014.
Melymuk, L., Bohlin, P., Sáňka, O., Pozo, K., and Klánová,
J.: Current challenges in air sampling of semi-volatile organic contaminants:
sampling artifacts and their influence on data comparability, Environ. Sci.
Technol., 48, 14077–14091, https://doi.org/10.1021/es502164r, 2014.
Melymuk, L., Bohlin-Nizzetto, P., Prokeš, R., Kukučka, P., and
Klánová, J.: Sampling artifacts in active air sampling of
semivolatile organic contaminants: Comparing theoretical and measured
artifacts and evaluating implications for monitoring networks, Environ.
Pollut., https://doi.org/10.1016/j.envpol.2015.12.015, online first, 2015.
Muñoz, A., Ródenas, M., Borrás, E., Vázquez, M., and Vera,
T.: The gas-phase degradation of chlorpyrifos and chlorpyrifos-oxon towards
OH radical under atmospheric conditions, Chemosphere, 111, 522–528,
https://doi.org/10.1016/j.chemosphere.2014.04.087, 2014.
Odabasi, M. and Cetin, B.: Determination of octanol-air partition
coefficients of organochlorine pesticides (OCPs) as a function of
temperature: Application to air-soil exchange, J. Environ. Manage., 113,
432–439, https://doi.org/10.1016/j.jenvman.2012.10.010, 2012a.
Odabasi, M. and Cetin, B.: Determination of octanol-air partition
coefficients of organochlorine pesticides (OCPs) as a function of
temperature: application to air-soil exchange, J. Environ. Manage., 113,
432–439, 2012b.
Okonski, K., Degrendele, C., Melymuk, L., Landlová, L., Kukučka, P.,
Vojta, Š., Jiri, K., Čupr, P., and Klánová, J.: Particle size
distribution of halogenated flame retardants and implications for atmospheric
deposition and transport, Environ. Sci. Technol., 48, 14426–14434, 2014.
Pankow, J. F.: Review and comparative analysis of the theories on
partitioning between the gas and aerosol particulate phases in the
atmosphere, Atmos. Environ., 21, 2275–2283,
https://doi.org/10.1016/0004-6981(87)90363-5, 1987.
Peck, A. M. and Hornbuckle, K. C.: Gas-Phase Concentrations of Current-Use
Pesticides in Iowa, Environ. Sci. Technol., 39, 2952–2959,
https://doi.org/10.1021/es0486418, 2005.
PPDB: The Pesticide Properties DataBase (PPDB), 2006–2013, Dev. by
Agric. Environ. Res. Unit (AERU), Univ. Hertfordshire, available at: http://sitem.herts.ac.uk/aeru/footprint/index2.htm (last access: December 2014), 2013.
Putaud, J.-P., Raes, F., Van Dingenen, R., Brüggemann, E., Facchini, M.
C., Decesari, S., Fuzzi, S., Gehrig, R., Hüglin, C., Laj, P., Lorbeer,
G., Maenhaut, W., Mihalopoulos, N., Müller, K., Querol, X., Rodriguez,
S., Schneider, J., Spindler, G., Brink, H. ten, Třrseth, K., and
Wiedensohler, A.: A European aerosol phenomenology – 2: chemical
characteristics of particulate matter at kerbside, urban, rural and
background sites in Europe, Atmos. Environ., 38, 2579–2595,
https://doi.org/10.1016/j.atmosenv.2004.01.041, 2004.
Růzicková, P., Klánová, J., Cupr, P., Lammel, G., and
Holoubek, I.: An assessment of air-soil exchange of polychlorinated biphenyls
and organochlorine pesticides across central and southern Europe, Environ.
Sci. Technol., 42, 179–85, 2008.
Sadiki, M. and Poissant, L.: Atmospheric concentrations and gas-particle
partitions of pesticides: Comparisons between measured and gas-particle
partitioning models from source and receptor sites, Atmos. Environ., 42,
8288–8299, doi10.1016/j.atmosenv.2008.07.041, 2008.
Sanusi, A., Millet, M., Mirabel, P., and Wortham, H.: Gas–particle
partitioning of pesticides in atmospheric samples, Atmos. Environ., 33,
4941–4951, https://doi.org/10.1016/S1352-2310(99)00275-7, 1999.
Sanusi, A., Millet, M., Mirabel, P., and Wortham, H.: Comparison of
atmospheric pesticide concentrations measured at three sampling sites: local,
regional and long-range transport, Sci. Total Environ., 263, 263–277,
https://doi.org/10.1016/S0048-9697(00)00714-2, 2000.
Sauret, N., Wortham, H., Putaud, J.-P., and Mirabel, P.: Study of the effects
of environmental parameters on the gas/particle partitioning of current-use
pesticides in urban air, Atmos. Environ., 42, 544–553,
https://doi.org/10.1016/j.atmosenv.2007.09.012, 2008.
Scheyer, A., Morville, S., Mirabel, P., and Millet, M.: Gas/particle
partitioning of lindane and current-used pesticides and their relationship
with temperature in urban and rural air in Alsace region (east of France),
Atmos. Environ., 42, 7695–7705, https://doi.org/10.1016/j.atmosenv.2008.05.029, 2008.
Schummer, C., Mothiron, E., Appenzeller, B. M. R., Rizet, A.-L., Wennig, R.,
and Millet, M.: Temporal variations of concentrations of currently used
pesticides in the atmosphere of Strasbourg, France, Environ. Pollut., 158,
576–584, https://doi.org/10.1016/j.envpol.2009.08.019, 2010.
Shen, L., Wania, F., Lei, Y. D., Teixeira, C., Muir, D. C. G., and Bidleman,
T. F.: Atmospheric distribution and long-range transport behavior of
organochlorine pesticides in north America, Environ. Sci. Technol., 39,
409–420, https://doi.org/10.1021/es049489c, 2004.
Shoeib, M. and Harner, T.: Using measured octanol-air partition coefficients
to explain environmental partitioning of organochlorine pesticides, Environ.
Toxicol. Chem., 21, 984–990,
https://doi.org/10.1897/1551-5028(2002)021<0984:umoapc>2.0.co;2,
2002.
Sofuoglu, A., Cetin, E., Bozacioglu, S. S., Sener, G. D., and Odabasi, M.:
Short-term variation in ambient concentrations and gas/particle partitioning
of organochlorine pesticides in Izmir, Turkey, Atmos. Environ., 38,
4483–4493, https://doi.org/10.1016/j.atmosenv.2004.05.036, 2004.
Solomon, K. R., Williams, W. M., Mackay, D., Purdy, J., Giddings, J., and
Giesy, J.: Properties and Uses of Chlorpyrifos in the United States, in:
Ecological Risk Assessment for Chlorpyrifos in Terrestrial and Aquatic
Systems in the United States, edited by: Giesy, J. P. and Solomon, K. R.,
Reviews of Environmental Contamination and Toxicology, Springer International
Publishing, 13–34, https://doi.org/10.1007/978-3-319-03865-0_2, 2014.
SRS: State Phytosanitary Administration. Usage of active substances in 2012,
Czech Republic, available at:
http://eagri.cz/public/web/file/439598/celek_2012_EN.pdf (last access: December 2014),
2013.
SRS: State Phytosanitary Administration, Usage of active substances in 2013,
Czech Republic, available at:
http://eagri.cz/public/web/file/439536/celek_2013_EN.pdf (last access: December 2014),
2014.
US Environmental Protection Agency: Atrazine Updates,
Pestic. Reregistration, available at: http://www.epa.gov/ingredients-used-pesticide-products/atrazine-background-and-updates (last access: July 2015), 2013.
US EPA: Estimation Programs Interface Suite™
for Microsoft® Windows, v 4.11, United
States Environmental Protection Agency, Washington, DC, USA, 2014.
Van den Berg, F., Kubiak, R., Benjey, W. G., Majewski, M. S., Yates, S. R.,
Reeves, G. L., Smelt, J. H., and van der Linden, A. M. A.: Emission of
Pesticides into the Air, Water. Air. Soil Poll., 115, 195–218,
https://doi.org/10.1023/A:1005234329622, 1999.
Van Dijk, H. F. G. and Guicherit, R.: Atmospheric dispersion of current-use
pesticides: A review of the evidence from monitoring studies, Water. Air.
Soil Poll., 115, 21–70, https://doi.org/10.1023/A:1005293020536, 1999.
Vecchi, R., Marcazzan, G., and Valli, G.: A study on nighttime-daytime
PM10 concentration and elemental composition in relation to atmospheric
dispersion in the urban area of Milan (Italy), Atmos. Environ., 41,
2136–2144, https://doi.org/10.1016/j.atmosenv.2006.10.069, 2007.
Wang, X. P., Sheng, J. J., Gong, P., Xue, Y. G., Yao, T. D., and Jones, K.
C.: Persistent organic pollutants in the Tibetan surface soil: Spatial
distribution, air-soil exchange and implications for global cycling, Environ.
Pollut., 170, 145–151, https://doi.org/10.1016/j.envpol.2012.06.012, 2012.
Wania, F., Haugen, J.-E., Lei, Y. D., and Mackay, D.: Temperature dependence of atmospheric
concentrations of semivolatile organic compounds, Environ. Sci.
Technol., 32, 1013–1021,
https://doi.org/10.1021/es970856c, 1998.
Wei, Y. L., Bao, L. J., Wu, C. C., He, Z. C., and Zeng, E. Y.: Association of
soil polycyclic aromatic hydrocarbon levels and anthropogenic impacts in a
rapidly urbanizing region: Spatial distribution, soil-air exchange and
ecological risk, Sci. Total Environ., 473–474, 676–684,
https://doi.org/10.1016/j.scitotenv.2013.12.106, 2014.
Yadav, I. C., Devi, N. L., Syed, J. H., Cheng, Z., Li, J., Zhang, G., and
Jones, K. C.: Current status of persistent organic pesticides residues in
air, water, and soil, and their possible effect on neighboring countries: A
comprehensive review of India, Sci. Total Environ., 511, 123–137,
https://doi.org/10.1016/j.scitotenv.2014.12.041, 2015.
Yao, Y., Harner, T., Blanchard, P., Tuduri, L., Waite, D., Poissant, L.,
Murphy, C., Belzer, W., Aulagnier, F., and Sverko, E.: Pesticides in the
Atmosphere Across Canadian Agricultural Regions, Environ. Sci. Technol., 42,
5931–5937, https://doi.org/10.1021/es800878r, 2008.
Zhang, L. and Vet, R.: A review of current knowledge concerning
size-dependent aerosol removal, China Particuology, 4, 272–282,
https://doi.org/10.1016/S1672-2515(07)60276-0, 2006.
Zhang, N., Yang, Y., Liu, Y., and Tao, S.: Determination of octanol-air
partition coefficients and supercooled liquid vapor pressures of
organochlorine pesticides, J. Environ. Sci. Heal. B, 44, 649–656, 2009.
Zhang, X. M., Meyer, T., Muir, D. C. G., Teixeira, C., Wang, X. W., and
Wania, F.: Atmospheric deposition of current use pesticides in the Arctic:
Snow core records from the Devon Island Ice Cap, Nunavut, Canada, Environ.
Sci. Impacts, 15, 2304–2311, https://doi.org/10.1039/c3em00433c, 2013.
Short summary
We examined gas-particle partitioning and size-fraction specific particle phase distributions for current use pesticides, identifying seasonal, and source-related trends, and contrasting with those of legacy organochlorine pesticides. The timing of pesticide use, seasonal air concentration trends, and particle size distributions were related. This informs our understanding of the atmospheric fate and transport of current use pesticides.
We examined gas-particle partitioning and size-fraction specific particle phase distributions...
Altmetrics
Final-revised paper
Preprint