Articles | Volume 16, issue 21
https://doi.org/10.5194/acp-16-13929-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-13929-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
11 Nov 2016
Research article |
| 11 Nov 2016
The effect of particle acidity on secondary organic aerosol formation from α-pinene photooxidation under atmospherically relevant conditions
Air Quality Research Division, Atmospheric Science and Technology
Directorate, Environment and Climate Change Canada, Toronto, ON, M3H 5T4,
Canada
Craig A. Stroud
CORRESPONDING AUTHOR
Air Quality Research Division, Atmospheric Science and Technology
Directorate, Environment and Climate Change Canada, Toronto, ON, M3H 5T4,
Canada
John Liggio
Air Quality Research Division, Atmospheric Science and Technology
Directorate, Environment and Climate Change Canada, Toronto, ON, M3H 5T4,
Canada
Shao-Meng Li
Air Quality Research Division, Atmospheric Science and Technology
Directorate, Environment and Climate Change Canada, Toronto, ON, M3H 5T4,
Canada
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Cited
29 citations as recorded by crossref.
- Interaction between marine and terrestrial biogenic volatile organic compounds: Non-linear effect on secondary organic aerosol formation X. Chen et al. 10.1016/j.atmosenv.2024.120868
- Impact of NOx on secondary organic aerosol (SOA) formation from α-pinene and β-pinene photooxidation: the role of highly oxygenated organic nitrates I. Pullinen et al. 10.5194/acp-20-10125-2020
- Formation of Chromophores from cis-Pinonaldehyde Aged in Highly Acidic Conditions C. Wong et al. 10.1021/jacs.3c14177
- Monoterpene Photooxidation in a Continuous-Flow Chamber: SOA Yields and Impacts of Oxidants, NOx, and VOC Precursors J. Liu et al. 10.1021/acs.est.2c02630
- Impacts of Mixed Gaseous and Particulate Pollutants on Secondary Particle Formation during Ozonolysis of Butyl Vinyl Ether P. Zhang et al. 10.1021/acs.est.9b07650
- Seasonal variation of aerosol acidity in Nagoya, Japan and factors affecting it Q. Song & K. Osada 10.1016/j.aeaoa.2020.100062
- Chemical Characteristics of Size-Resolved Aerosols in Coastal Areas during KORUS-AQ Campaign; Comparison of Ion Neutralization Model M. Bae et al. 10.1007/s13143-018-00099-1
- Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al. 10.3390/atmos15020204
- Enhanced organic aerosol formation induced by inorganic aerosol formed in laboratory photochemical experiments A. Ali et al. 10.1016/j.jaerosci.2024.106481
- Chemical characteristics of haze particles in Xi'an during Chinese Spring Festival: Impact of fireworks burning C. Wu et al. 10.1016/j.jes.2018.04.008
- Anthropogenic Effects on Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1007/s00376-020-0284-3
- SO2 enhances aerosol formation from anthropogenic volatile organic compound ozonolysis by producing sulfur-containing compounds Z. Yang et al. 10.5194/acp-23-417-2023
- Particulate organic nitrates at Mount Tai in winter and spring: Variation characteristics and effects of mountain-valley breezes and elevated emission sources J. Chen et al. 10.1016/j.envres.2022.113182
- Comparison of chemical composition and acidity of size-resolved inorganic aerosols at the top and foot of Mt. Hua, Northwest China: The role of the gas-particle distribution of ammonia Q. Feng et al. 10.1016/j.scitotenv.2023.166985
- Modeling daytime and nighttime secondary organic aerosol formation via multiphase reactions of biogenic hydrocarbons S. Han & M. Jang 10.5194/acp-23-1209-2023
- Secondary organic aerosol formation from α-pinene, alkanes, and oil-sands-related precursors in a new oxidation flow reactor K. Li et al. 10.5194/acp-19-9715-2019
- Exploring the formation potential and optical properties of secondary organic aerosol from the photooxidation of selected short aliphatic ethers J. Zhu et al. 10.1016/j.jes.2020.03.050
- Significant impacts of anthropogenic activities on monoterpene and oleic acid-derived particulate organic nitrates in the North China Plain J. Zhang et al. 10.1016/j.atmosres.2021.105585
- Acidity and inorganic ion formation in PM2.5 based on continuous online observations in a South China megacity L. Wu et al. 10.1016/j.apr.2020.05.003
- NOx enhances secondary organic aerosol formation from nighttime γ-terpinene ozonolysis L. Xu et al. 10.1016/j.atmosenv.2020.117375
- Fine particle pH and gas–particle phase partitioning of inorganic species in Pasadena, California, during the 2010 CalNex campaign H. Guo et al. 10.5194/acp-17-5703-2017
- Effects of NOx and SO2 on the secondary organic aerosol formation from photooxidation of α-pinene and limonene D. Zhao et al. 10.5194/acp-18-1611-2018
- Highly Acidic Conditions Drastically Alter the Chemical Composition and Absorption Coefficient of α-Pinene Secondary Organic Aerosol C. Wong et al. 10.1021/acsearthspacechem.2c00249
- Effect of NOx and SO2 on the photooxidation of methylglyoxal: Implications in secondary aerosol formation S. Wang et al. 10.1016/j.jes.2020.02.011
- Relative Humidity Changes the Role of SO2 in Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1021/acs.jpclett.1c01550
- Multifactor colorimetric analysis on pH-indicator papers: an optimized approach for direct determination of ambient aerosol pH G. Li et al. 10.5194/amt-13-6053-2020
- Increased primary and secondary H2SO4 showing the opposing roles in secondary organic aerosol formation from ethyl methacrylate ozonolysis P. Zhang et al. 10.5194/acp-21-7099-2021
- Characteristics of Concentrations and Water-Soluble Ions in PM2.5 in Xinjiang Province, Northwest China Based on Super Station Observation L. Xinchun et al. 10.1007/s13143-025-00394-8
- Review of the influencing factors of secondary organic aerosol formation and aging mechanism based on photochemical smog chamber simulation methods Y. Zhang et al. 10.1016/j.jes.2022.10.033
29 citations as recorded by crossref.
- Interaction between marine and terrestrial biogenic volatile organic compounds: Non-linear effect on secondary organic aerosol formation X. Chen et al. 10.1016/j.atmosenv.2024.120868
- Impact of NOx on secondary organic aerosol (SOA) formation from α-pinene and β-pinene photooxidation: the role of highly oxygenated organic nitrates I. Pullinen et al. 10.5194/acp-20-10125-2020
- Formation of Chromophores from cis-Pinonaldehyde Aged in Highly Acidic Conditions C. Wong et al. 10.1021/jacs.3c14177
- Monoterpene Photooxidation in a Continuous-Flow Chamber: SOA Yields and Impacts of Oxidants, NOx, and VOC Precursors J. Liu et al. 10.1021/acs.est.2c02630
- Impacts of Mixed Gaseous and Particulate Pollutants on Secondary Particle Formation during Ozonolysis of Butyl Vinyl Ether P. Zhang et al. 10.1021/acs.est.9b07650
- Seasonal variation of aerosol acidity in Nagoya, Japan and factors affecting it Q. Song & K. Osada 10.1016/j.aeaoa.2020.100062
- Chemical Characteristics of Size-Resolved Aerosols in Coastal Areas during KORUS-AQ Campaign; Comparison of Ion Neutralization Model M. Bae et al. 10.1007/s13143-018-00099-1
- Differences in Secondary Organic Aerosol Formation from α-Pinene Photooxidation in a Chamber with Purified Air and Ambient Air as Matrices: Preliminary Results X. Li et al. 10.3390/atmos15020204
- Enhanced organic aerosol formation induced by inorganic aerosol formed in laboratory photochemical experiments A. Ali et al. 10.1016/j.jaerosci.2024.106481
- Chemical characteristics of haze particles in Xi'an during Chinese Spring Festival: Impact of fireworks burning C. Wu et al. 10.1016/j.jes.2018.04.008
- Anthropogenic Effects on Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1007/s00376-020-0284-3
- SO2 enhances aerosol formation from anthropogenic volatile organic compound ozonolysis by producing sulfur-containing compounds Z. Yang et al. 10.5194/acp-23-417-2023
- Particulate organic nitrates at Mount Tai in winter and spring: Variation characteristics and effects of mountain-valley breezes and elevated emission sources J. Chen et al. 10.1016/j.envres.2022.113182
- Comparison of chemical composition and acidity of size-resolved inorganic aerosols at the top and foot of Mt. Hua, Northwest China: The role of the gas-particle distribution of ammonia Q. Feng et al. 10.1016/j.scitotenv.2023.166985
- Modeling daytime and nighttime secondary organic aerosol formation via multiphase reactions of biogenic hydrocarbons S. Han & M. Jang 10.5194/acp-23-1209-2023
- Secondary organic aerosol formation from α-pinene, alkanes, and oil-sands-related precursors in a new oxidation flow reactor K. Li et al. 10.5194/acp-19-9715-2019
- Exploring the formation potential and optical properties of secondary organic aerosol from the photooxidation of selected short aliphatic ethers J. Zhu et al. 10.1016/j.jes.2020.03.050
- Significant impacts of anthropogenic activities on monoterpene and oleic acid-derived particulate organic nitrates in the North China Plain J. Zhang et al. 10.1016/j.atmosres.2021.105585
- Acidity and inorganic ion formation in PM2.5 based on continuous online observations in a South China megacity L. Wu et al. 10.1016/j.apr.2020.05.003
- NOx enhances secondary organic aerosol formation from nighttime γ-terpinene ozonolysis L. Xu et al. 10.1016/j.atmosenv.2020.117375
- Fine particle pH and gas–particle phase partitioning of inorganic species in Pasadena, California, during the 2010 CalNex campaign H. Guo et al. 10.5194/acp-17-5703-2017
- Effects of NOx and SO2 on the secondary organic aerosol formation from photooxidation of α-pinene and limonene D. Zhao et al. 10.5194/acp-18-1611-2018
- Highly Acidic Conditions Drastically Alter the Chemical Composition and Absorption Coefficient of α-Pinene Secondary Organic Aerosol C. Wong et al. 10.1021/acsearthspacechem.2c00249
- Effect of NOx and SO2 on the photooxidation of methylglyoxal: Implications in secondary aerosol formation S. Wang et al. 10.1016/j.jes.2020.02.011
- Relative Humidity Changes the Role of SO2 in Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1021/acs.jpclett.1c01550
- Multifactor colorimetric analysis on pH-indicator papers: an optimized approach for direct determination of ambient aerosol pH G. Li et al. 10.5194/amt-13-6053-2020
- Increased primary and secondary H2SO4 showing the opposing roles in secondary organic aerosol formation from ethyl methacrylate ozonolysis P. Zhang et al. 10.5194/acp-21-7099-2021
- Characteristics of Concentrations and Water-Soluble Ions in PM2.5 in Xinjiang Province, Northwest China Based on Super Station Observation L. Xinchun et al. 10.1007/s13143-025-00394-8
- Review of the influencing factors of secondary organic aerosol formation and aging mechanism based on photochemical smog chamber simulation methods Y. Zhang et al. 10.1016/j.jes.2022.10.033
Saved (preprint)
Latest update: 08 Jul 2025
Short summary
This study investigates the acidity effect on the yield and chemical composition of α-pinene secondary organic aerosol based on a series of laboratory experiments performed using a photochemical reaction chamber under high- and low-NOx conditions. We have found that the acidity effect largely depends on NOx level and the inorganic acidity has a significant role to play in determining various organic aerosol chemical properties such as mass yields, oxidation state, and organic nitrate content.
This study investigates the acidity effect on the yield and chemical composition of α-pinene...
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