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Volume 16, issue 20
Atmos. Chem. Phys., 16, 13105–13119, 2016
https://doi.org/10.5194/acp-16-13105-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 16, 13105–13119, 2016
https://doi.org/10.5194/acp-16-13105-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 26 Oct 2016

Research article | 26 Oct 2016

Quantification of environmentally persistent free radicals and reactive oxygen species in atmospheric aerosol particles

Andrea M. Arangio et al.

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We have quantified environmentally persistent free radicals and reactive oxygen species (ROS) in size-segregated atmospheric aerosol particles. We suggest that ROS were formed by decomposition of secondary organic aerosols interacting with transition metal ions and quinones contained in humic-like substances. The results have significant implications for aqueous-phase and cloud processing of organic aerosols as well as adverse health effects upon respiratory deposition of aerosol particles.
We have quantified environmentally persistent free radicals and reactive oxygen species (ROS) in...
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