Articles | Volume 16, issue 19
https://doi.org/10.5194/acp-16-12767-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-12767-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
13 Oct 2016
Research article |
| 13 Oct 2016
Discontinuities in hygroscopic growth below and above water saturation for laboratory surrogates of oligomers in organic atmospheric aerosols
Natasha Hodas
CORRESPONDING AUTHOR
Division of Chemistry and Chemical Engineering, California Institute
of Technology, Pasadena, CA, USA
Department of Environmental Sciences and Management, Portland State
University, Portland, OR, USA
Andreas Zuend
Department of Atmospheric and Oceanic Sciences, McGill University,
Montreal, Quebec, Canada
Katherine Schilling
Division of Chemistry and Chemical Engineering, California Institute
of Technology, Pasadena, CA, USA
now at: United States Army Criminal Investigation Laboratory, Forest
Park, GA, USA
Thomas Berkemeier
Multiphase Chemistry Department, Max Planck Institute for Chemistry,
Mainz, Germany
Manabu Shiraiwa
Multiphase Chemistry Department, Max Planck Institute for Chemistry,
Mainz, Germany
Department of Chemistry, University of California Irvine, Irvine, CA, USA
Richard C. Flagan
Division of Chemistry and Chemical Engineering, California Institute
of Technology, Pasadena, CA, USA
Division of Engineering and Applied Science, California Institute of
Technology, Pasadena, CA, USA
John H. Seinfeld
Division of Chemistry and Chemical Engineering, California Institute
of Technology, Pasadena, CA, USA
Division of Engineering and Applied Science, California Institute of
Technology, Pasadena, CA, USA
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33 citations as recorded by crossref.
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- Flash Freeze Flow Tube to Vitrify Aerosol Particles at Fixed Relative Humidity Values T. Kucinski et al. 10.1021/acs.analchem.9b05757
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- Kinetic Limitations Affect Cloud Condensation Nuclei Activity Measurements Under Low Supersaturation J. Tao et al. 10.1029/2022GL101603
- Size-Dependent Liquid–Liquid Phase Separation in Atmospherically Relevant Complex Systems T. Kucinski et al. 10.1021/acs.jpclett.9b02532
- Effects of Phase State and Phase Separation on Dimethylamine Uptake of Ammonium Sulfate and Ammonium Sulfate–Sucrose Mixed Particles W. DeRieux et al. 10.1021/acsearthspacechem.9b00142
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- Influence of organic compound functionality on aerosol hygroscopicity: dicarboxylic acids, alkyl-substituents, sugars and amino acids A. Marsh et al. 10.5194/acp-17-5583-2017
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- Liquid–liquid phase separation and morphologies in organic particles consisting of <i>α</i>-pinene and <i>β</i>-caryophyllene ozonolysis products and mixtures with commercially available organic compounds Y. Song et al. 10.5194/acp-20-11263-2020
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- Phase State Regulates Photochemical HONO Production from NaNO3/Dicarboxylic Acid Mixtures Q. Li et al. 10.1021/acs.est.3c10980
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33 citations as recorded by crossref.
- Water uptake of subpollen aerosol particles: hygroscopic growth, cloud condensation nuclei activation, and liquid–liquid phase separation E. Mikhailov et al. 10.5194/acp-21-6999-2021
- Modelling the gas–particle partitioning and water uptake of isoprene-derived secondary organic aerosol at high and low relative humidity D. Amaladhasan et al. 10.5194/acp-22-215-2022
- Predicting hygroscopic growth of organosulfur aerosol particles using COSMOtherm Z. Li et al. 10.5194/acp-24-11717-2024
- Liquid–Liquid Phase Separation Can Drive Aerosol Droplet Growth in Supersaturated Regimes K. Malek et al. 10.1021/acsenvironau.3c00015
- Role of WSOCs and pH on Ammonium Nitrate Aerosol Efflorescence: Insights into Secondary Aerosol Formation J. Sun et al. 10.1021/acs.est.3c07603
- Liquid–Liquid Phase Separation in Supermicrometer and Submicrometer Aerosol Particles M. Freedman 10.1021/acs.accounts.0c00093
- Water Solubility Distribution of Organic Matter Accounts for the Discrepancy in Hygroscopicity among Sub- and Supersaturated Humidity Regimes W. Lee et al. 10.1021/acs.est.2c04647
- Flash Freeze Flow Tube to Vitrify Aerosol Particles at Fixed Relative Humidity Values T. Kucinski et al. 10.1021/acs.analchem.9b05757
- Hygroscopic behavior of inorganic–organic aerosol systems including ammonium sulfate, dicarboxylic acids, and oligomer H. Bouzidi et al. 10.1016/j.atmosenv.2020.117481
- Kinetic Limitations Affect Cloud Condensation Nuclei Activity Measurements Under Low Supersaturation J. Tao et al. 10.1029/2022GL101603
- Size-Dependent Liquid–Liquid Phase Separation in Atmospherically Relevant Complex Systems T. Kucinski et al. 10.1021/acs.jpclett.9b02532
- Effects of Phase State and Phase Separation on Dimethylamine Uptake of Ammonium Sulfate and Ammonium Sulfate–Sucrose Mixed Particles W. DeRieux et al. 10.1021/acsearthspacechem.9b00142
- Relative-humidity-dependent organic aerosol thermodynamics via an efficient reduced-complexity model K. Gorkowski et al. 10.5194/acp-19-13383-2019
- Effect of Particle Morphology on Cloud Condensation Nuclei Activity M. Altaf et al. 10.1021/acsearthspacechem.7b00146
- Influence of organic compound functionality on aerosol hygroscopicity: dicarboxylic acids, alkyl-substituents, sugars and amino acids A. Marsh et al. 10.5194/acp-17-5583-2017
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. 10.5194/acp-19-12515-2019
- Liquid–liquid phase separation in particles containing secondary organic material free of inorganic salts M. Song et al. 10.5194/acp-17-11261-2017
- Liquid–liquid phase separation and morphologies in organic particles consisting of <i>α</i>-pinene and <i>β</i>-caryophyllene ozonolysis products and mixtures with commercially available organic compounds Y. Song et al. 10.5194/acp-20-11263-2020
- Hygroscopic growth and CCN activity of secondary organic aerosol produced from dark ozonolysis of γ-terpinene H. Bouzidi et al. 10.1016/j.scitotenv.2022.153010
- Markedly different impacts of primary emissions and secondary aerosol formation on aerosol mixing states revealed by simultaneous measurements of CCNC, H(/V)TDMA, and SP2 J. Tao et al. 10.5194/acp-24-9131-2024
- Observations on hygroscopic growth and phase transitions of mixed 1, 2, 6-hexanetriol ∕ (NH4)2SO4 particles: investigation of the liquid–liquid phase separation (LLPS) dynamic process and mechanism and secondary LLPS during the dehumidification S. Ma et al. 10.5194/acp-21-9705-2021
- Resolving the mechanisms of hygroscopic growth and cloud condensation nuclei activity for organic particulate matter P. Liu et al. 10.1038/s41467-018-06622-2
- Characterization of Size-Resolved Hygroscopicity of Black Carbon-Containing Particle in Urban Environment Y. Wu et al. 10.1021/acs.est.9b05546
- Liquid–liquid phase separation in organic particles containing one and two organic species: importance of the average O : C M. Song et al. 10.5194/acp-18-12075-2018
- Phase State Regulates Photochemical HONO Production from NaNO3/Dicarboxylic Acid Mixtures Q. Li et al. 10.1021/acs.est.3c10980
- Phase separation in organic aerosol M. Freedman 10.1039/C6CS00783J
- Hygroscopicity of secondary marine organic aerosols: Mixtures of alkylammonium salts and inorganic components B. Asadzadeh et al. 10.1016/j.scitotenv.2021.148131
- A comprehensive study on hygroscopic behaviour and nitrate depletion of NaNO3 and dicarboxylic acid mixtures: implications for nitrate depletion in tropospheric aerosols S. Ma et al. 10.5194/acp-22-10955-2022
- Measurement report: High Arctic aerosol hygroscopicity at sub- and supersaturated conditions during spring and summer A. Massling et al. 10.5194/acp-23-4931-2023
- Hygroscopicity of organic surrogate compounds from biomass burning and their effect on the efflorescence of ammonium sulfate in mixed aerosol particles T. Lei et al. 10.5194/acp-18-1045-2018
- Liquid–liquid phase separation in secondary organic aerosol particles produced from <i>α</i>-pinene ozonolysis and <i>α</i>-pinene photooxidation with/without ammonia S. Ham et al. 10.5194/acp-19-9321-2019
- Probing the evaporation dynamics of semi-volatile organic compounds to reveal the thermodynamics of liquid–liquid phase separated aerosol J. Choczynski et al. 10.1039/D3SC05164A
- Current State of Atmospheric Aerosol Thermodynamics and Mass Transfer Modeling: A Review K. Semeniuk & A. Dastoor 10.3390/atmos11020156
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Discontinuities in apparent hygroscopicity below and above water saturation have been observed for organic and mixed organic-inorganic aerosol particles in both laboratory studies and in the ambient atmosphere. This work explores the extent to which such discontinuities are influenced by organic component molecular mass and viscosity, non-ideal thermodynamic interactions between aerosol components, and the combination of these factors.
Discontinuities in apparent hygroscopicity below and above water saturation have been observed...
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