Articles | Volume 16, issue 17
https://doi.org/10.5194/acp-16-11433-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-11433-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
14 Sep 2016
Research article |
| 14 Sep 2016
Isotopic constraints on the role of hypohalous acids in sulfate aerosol formation in the remote marine boundary layer
Qianjie Chen
Department of Atmospheric Sciences, University of Washington,
Seattle, WA, USA
Lei Geng
Department of Atmospheric Sciences, University of Washington,
Seattle, WA, USA
now at: Univ. Grenoble-Alpes, LGGE, 38000, Grenoble,
France
now at: CNRS, LGGE, 38000, Grenoble, France
Johan A. Schmidt
Department of Chemistry, University of Copenhagen, Copenhagen,
Denmark
Zhouqing Xie
Institute of Polar Environments, School of Earth and Space Sciences,
University of Science and Technology of China, Hefei, Anhui, China
Hui Kang
Institute of Polar Environments, School of Earth and Space Sciences,
University of Science and Technology of China, Hefei, Anhui, China
Jordi Dachs
Department of Environmental Chemistry, IDAEA-CSIC, IDAEA-CSIC,
Barcelona, Catalunya, Spain
Jihong Cole-Dai
Department of Chemistry and Biochemistry, South Dakota State
University, Brookings, SD, USA
Andrew J. Schauer
Department of Earth and Space Sciences, University of Washington,
Seattle, WA, USA
Madeline G. Camp
Joint Institute for the Study of Atmosphere and Ocean, University of
Washington, Seattle, WA, USA
now at: DSG Solutions, LLC, Shoreline, WA, USA
Becky Alexander
CORRESPONDING AUTHOR
Department of Atmospheric Sciences, University of Washington,
Seattle, WA, USA
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38 citations as recorded by crossref.
- Heterogeneous sulfate aerosol formation mechanisms during wintertime Chinese haze events: air quality model assessment using observations of sulfate oxygen isotopes in Beijing J. Shao et al. 10.5194/acp-19-6107-2019
- DMS oxidation and sulfur aerosol formation in the marine troposphere: a focus on reactive halogen and multiphase chemistry Q. Chen et al. 10.5194/acp-18-13617-2018
- Modification of the Conversion of Dimethylsulfide to Methanesulfonic Acid by Anthropogenic Pollution as Revealed by Long-Term Observations B. Jiang et al. 10.1021/acsearthspacechem.1c00222
- Isotopic Constraints on SO2 Oxidation Rates and Their Potential Relationship with Sulfate Formation Pathways in the Planetary Boundary Layer Z. Niu & M. Lin 10.1021/acsenvironau.4c00070
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- Stratospheric Gas‐Phase Production Alone Cannot Explain Observations of Atmospheric Perchlorate on Earth Y. Chan et al. 10.1029/2023GL102745
- Isotopic constraints on heterogeneous sulfate production in Beijing haze P. He et al. 10.5194/acp-18-5515-2018
- Multiphase Oxidation of Sulfur Dioxide in Aerosol Particles: Implications for Sulfate Formation in Polluted Environments T. Liu et al. 10.1021/acs.est.0c06496
- Modeling Aerosol Effects on Liquid Clouds in the Summertime Arctic R. Ghahreman et al. 10.1029/2021JD034962
- The sensitivity of Southern Ocean aerosols and cloud microphysics to sea spray and sulfate aerosol production in the HadGEM3-GA7.1 chemistry–climate model L. Revell et al. 10.5194/acp-19-15447-2019
- Spatial and Temporal Distribution of Sea Salt Aerosol Mass Concentrations in the Marine Boundary Layer From the Arctic to the Antarctic B. Jiang et al. 10.1029/2020JD033892
- Atmospheric Δ17O(NO3−) reveals nocturnal chemistry dominates nitrate production in Beijing haze P. He et al. 10.5194/acp-18-14465-2018
- The observation of isotopic compositions of atmospheric nitrate in Shanghai China and its implication for reactive nitrogen chemistry P. He et al. 10.1016/j.scitotenv.2020.136727
- Characteristics and major influencing factors of sulfate production via heterogeneous transition-metal-catalyzed oxidation during haze evolution in China F. Yue et al. 10.1016/j.apr.2020.05.014
- Multi O- and S-isotopes as tracers of black crusts formation under volcanic and non-volcanic atmospheric conditions in Sicily (Italy) A. Aroskay et al. 10.1016/j.scitotenv.2020.142283
- Identification of potential sources of elevated PM2.5-Hg using mercury isotopes during haze events Y. Qiu et al. 10.1016/j.atmosenv.2021.118203
- The mass-independent oxygen isotopic composition in sulfate aerosol-a useful tool to identify sulfate formation: a review Y. Zhao et al. 10.1016/j.atmosres.2020.105447
- Effects of halogens on European air-quality T. Sherwen et al. 10.1039/C7FD00026J
- A pH dependent sulfate formation mechanism caused by hypochlorous acid in the marine atmosphere J. Liu et al. 10.1016/j.scitotenv.2021.147551
- Catalytic sulfate formation mechanism influenced by important constituents of cloud waterviathe reaction of SO2oxidized by hypobromic acid in marine areas J. Liu et al. 10.1039/D1CP01981C
- 40 years of theoretical advances in mass-independent oxygen isotope effects and applications in atmospheric chemistry: A critical review and perspectives M. Lin & M. Thiemens 10.1016/j.apgeochem.2023.105860
- Vertically uniform formation pathways of tropospheric sulfate aerosols in East China detected from triple stable oxygen and radiogenic sulfur isotopes M. Lin et al. 10.1002/2017GL073637
- Importance of Atmospheric Transport on Methanesulfonic Acid (MSA) Concentrations in the Arctic Ocean During Summer Under Global Warming B. Jiang et al. 10.1029/2022JD037271
- Preparation and characterization of new sulfate reference materials for Δ17O analysis G. Su et al. 10.1039/D2JA00022A
- Isotopic Constraints on the Formation Mechanisms of Sulfate Aerosols in the Summer Arctic Marine Boundary Layer P. He et al. 10.1029/2022JD036601
- Regional Characteristics of Atmospheric Sulfate Formation in East Antarctica Imprinted on 17O‐Excess Signature S. Ishino et al. 10.1029/2020JD033583
- Isotopic constraints on atmospheric sulfate formation pathways in the Mt. Everest region, southern Tibetan Plateau K. Wang et al. 10.5194/acp-21-8357-2021
- Photochemical box modelling of volcanic SO2 oxidation: isotopic constraints T. Galeazzo et al. 10.5194/acp-18-17909-2018
- Quantification of Gas-to-Particle Conversion Rates of Sulfur in the Terrestrial Atmosphere Using High-Sensitivity Measurements of Cosmogenic 35S M. Lin et al. 10.1021/acsearthspacechem.7b00047
- Boundary layer and free-tropospheric dimethyl sulfide in the Arctic spring and summer R. Ghahreman et al. 10.5194/acp-17-8757-2017
- Enrichment of Organophosphate Esters in the Sea Surface Microlayer from the Atlantic and Southern Oceans N. Trilla-Prieto et al. 10.1021/acs.estlett.4c00636
- Assessing the Seasonal Dynamics of Nitrate and Sulfate Aerosols at the South Pole Utilizing Stable Isotopes W. Walters et al. 10.1029/2019JD030517
- Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds A. Tilgner et al. 10.5194/acp-21-13483-2021
- Isotopic evidence for acidity-driven enhancement of sulfate formation after SO 2 emission control S. Hattori et al. 10.1126/sciadv.abd4610
- Role of Dust and Iron Solubility in Sulfate Formation during the Long-Range Transport in East Asia Evidenced by 17O-Excess Signatures S. Itahashi et al. 10.1021/acs.est.2c03574
- Atmospheric SO2 oxidation by NO2 plays no role in the mass independent sulfur isotope fractionation of urban aerosols D. Au Yang et al. 10.1016/j.atmosenv.2018.09.007
- Seasonal variations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica S. Ishino et al. 10.5194/acp-17-3713-2017
Latest update: 31 Mar 2025
Short summary
The formation mechanisms of sulfate in the marine boundary layer are not well understood, which could result in large uncertainties in aerosol radiative forcing. We measure the oxygen isotopic composition (Δ17O) of sulfate collected in the MBL and analyze with a global transport model. Our results suggest that 33–50 % of MBL sulfate is formed via oxidation of S(IV) by hypohalous acids HOBr / HOCl in the aqueous phase, and the daily-mean HOBr/HOCl concentrations are on the order of 0.01–0.1 ppt.
The formation mechanisms of sulfate in the marine boundary layer are not well understood, which...
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