Articles | Volume 16, issue 17
https://doi.org/10.5194/acp-16-11237-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-11237-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Impact of NOx and OH on secondary organic aerosol formation from β-pinene photooxidation
Mehrnaz Sarrafzadeh
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Centre for Atmospheric Chemistry, York University, 4700 Keele St.,
Toronto, ON M3J 1P3, Canada
Jürgen Wildt
CORRESPONDING AUTHOR
Institute of Bio- and Geosciences, IBG-2, Forschungszentrum Jülich,
52425 Jülich, Germany
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Iida Pullinen
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Monika Springer
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Einhard Kleist
Institute of Bio- and Geosciences, IBG-2, Forschungszentrum Jülich,
52425 Jülich, Germany
Ralf Tillmann
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Sebastian H. Schmitt
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Cheng Wu
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Thomas F. Mentel
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Defeng Zhao
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Donald R. Hastie
Centre for Atmospheric Chemistry, York University, 4700 Keele St.,
Toronto, ON M3J 1P3, Canada
Astrid Kiendler-Scharr
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
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Short summary
We investigated NOx impacts on the formation of secondary organic aerosol (SOA) mass from b-pinene and we could reveal two different mechanisms of impacts. One of them was the impact of NOx on OH that could explain increasing SOA yield with increasing NOx at low NOx conditions. The other was the suppression of new particle formation limiting the condensational sink for the SOA precursors. This effect could explain a substantial fraction of the decrease of SOA yield observed at high NOx.
We investigated NOx impacts on the formation of secondary organic aerosol (SOA) mass from...
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