Articles | Volume 16, issue 17
https://doi.org/10.5194/acp-16-11163-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-16-11163-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
09 Sep 2016
Research article |
| 09 Sep 2016
Phase state of ambient aerosol linked with water uptake and chemical aging in the southeastern US
Aki Pajunoja
Department of Applied Physics, University of Eastern Finland, Kuopio Campus, P.O. Box 1627, 70211 Kuopio, Finland
Weiwei Hu
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
Yu J. Leong
Department of Applied Physics, University of Eastern Finland, Kuopio Campus, P.O. Box 1627, 70211 Kuopio, Finland
Department of Civil and Environmental Engineering, Rice University, 6100 Main St MS-519, Houston, TX, USA
Nathan F. Taylor
Department of Atmospheric Sciences, Texas A&M University, College Station, TX, USA
Pasi Miettinen
Department of Applied Physics, University of Eastern Finland, Kuopio Campus, P.O. Box 1627, 70211 Kuopio, Finland
Brett B. Palm
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
Santtu Mikkonen
Department of Applied Physics, University of Eastern Finland, Kuopio Campus, P.O. Box 1627, 70211 Kuopio, Finland
Don R. Collins
Department of Atmospheric Sciences, Texas A&M University, College Station, TX, USA
Jose L. Jimenez
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
Annele Virtanen
CORRESPONDING AUTHOR
Department of Applied Physics, University of Eastern Finland, Kuopio Campus, P.O. Box 1627, 70211 Kuopio, Finland
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56 citations as recorded by crossref.
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- The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy Y. Zhang et al. 10.1021/acs.est.9b03317
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- Potential role of intraparticle diffusion in dynamic partitioning of secondary organic aerosols C. Liu & J. Cao 10.1016/j.apr.2018.04.012
- Effects of Atmospheric Aging Processes on Nascent Sea Spray Aerosol Physicochemical Properties C. Kaluarachchi et al. 10.1021/acsearthspacechem.2c00258
- Gas to Particle Partitioning of Organic Acids in the Boreal Atmosphere A. Lutz et al. 10.1021/acsearthspacechem.9b00041
- Impact of Thermal Decomposition on Thermal Desorption Instruments: Advantage of Thermogram Analysis for Quantifying Volatility Distributions of Organic Species H. Stark et al. 10.1021/acs.est.7b00160
- Low-volatility compounds contribute significantly to isoprene secondary organic aerosol (SOA) under high-NO<sub><i>x</i></sub> conditions R. Schwantes et al. 10.5194/acp-19-7255-2019
- Hygroscopic behavior of aerosols generated from solutions of 3-methyl-1,2,3-butanetricarboxylic acid, its sodium salts, and its mixtures with NaCl L. Wu et al. 10.5194/acp-20-14103-2020
- The importance of size ranges in aerosol instrument intercomparisons: a case study for the Atmospheric Tomography Mission H. Guo et al. 10.5194/amt-14-3631-2021
- Volatility and lifetime against OH heterogeneous reaction of ambient isoprene-epoxydiols-derived secondary organic aerosol (IEPOX-SOA) W. Hu et al. 10.5194/acp-16-11563-2016
- Aerosol Phase State and Its Link to Chemical Composition and Liquid Water Content in a Subtropical Coastal Megacity Y. Liu et al. 10.1021/acs.est.9b01196
54 citations as recorded by crossref.
- Multiphase Photochemistry of Pyruvic Acid under Atmospheric Conditions A. Reed Harris et al. 10.1021/acs.jpca.7b01107
- Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ Y. Li et al. 10.1021/acsearthspacechem.1c00094
- Bouncier Particles at Night: Biogenic Secondary Organic Aerosol Chemistry and Sulfate Drive Diel Variations in the Aerosol Phase in a Mixed Forest J. Slade et al. 10.1021/acs.est.8b07319
- Methylamine’s Effects on Methylglyoxal-Containing Aerosol: Chemical, Physical, and Optical Changes D. De Haan et al. 10.1021/acsearthspacechem.9b00103
- On the implications of aerosol liquid water and phase separation for organic aerosol mass H. Pye et al. 10.5194/acp-17-343-2017
- Current State of Atmospheric Aerosol Thermodynamics and Mass Transfer Modeling: A Review K. Semeniuk & A. Dastoor 10.3390/atmos11020156
- Real‐Time Characterization of Aerosol Compositions, Sources, and Aging Processes in Guangzhou During PRIDE‐GBA 2018 Campaign W. Chen et al. 10.1029/2021JD035114
- Exploring the Nanostructures Accessible to an Organic Surfactant Atmospheric Aerosol Proxy A. Milsom et al. 10.1021/acs.jpca.2c04611
- Direct observation and assessment of phase states of ambient and lab-generated sub-micron particles upon humidification Z. Cheng et al. 10.1039/D1RA02530A
- Ambient Quantification and Size Distributions for Organic Aerosol in Aerosol Mass Spectrometers with the New Capture Vaporizer W. Hu et al. 10.1021/acsearthspacechem.9b00310
- Heterogeneous oxidation of amorphous organic aerosol surrogates by O<sub>3</sub>, NO<sub>3</sub>, and OH at typical tropospheric temperatures J. Li et al. 10.5194/acp-20-6055-2020
- Ozonolysis Chemistry and Phase Behavior of 1-Octen-3-ol-Derived Secondary Organic Aerosol K. Fischer et al. 10.1021/acsearthspacechem.0c00092
- Particle phase state and aerosol liquid water greatly impact secondary aerosol formation: insights into phase transition and its role in haze events X. Meng et al. 10.5194/acp-24-2399-2024
- Effects of Molecular-Level Compositional Variability in Organic Aerosol on Phase State and Thermodynamic Mixing Behavior J. Ditto et al. 10.1021/acs.est.9b02664
- Influence of Relative Humidity and Composition on PM2.5 Phases in Northeast Asia C. Seong et al. 10.1021/acsearthspacechem.4c00019
- Enhanced Gas Uptake during α-Pinene Ozonolysis Points to a Burying Mechanism A. Vander Wall et al. 10.1021/acsearthspacechem.0c00163
- Phase state of secondary organic aerosol in chamber photo-oxidation of mixed precursors Y. Wang et al. 10.5194/acp-21-11303-2021
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. 10.1021/acsearthspacechem.1c00296
- Predicting Atmospheric Particle Phase State Using an Explainable Machine Learning Approach Based on Particle Rebound Measurements Y. Qiu et al. 10.1021/acs.est.3c05284
- Microphysical explanation of the RH‐dependent water affinity of biogenic organic aerosol and its importance for climate N. Rastak et al. 10.1002/2017GL073056
- Additional Benefits of Federal Air-Quality Rules: Model Estimates of Controllable Biogenic Secondary Organic Aerosol A. Carlton et al. 10.1021/acs.est.8b01869
- Comparison of Phase States of PM2.5 over Megacities, Seoul and Beijing, and Their Implications on Particle Size Distribution M. Song et al. 10.1021/acs.est.2c06377
- Humidity-Dependent Phase State of Gasoline Vehicle Emission-Related Aerosols X. Meng et al. 10.1021/acs.est.0c05478
- Influence of particle viscosity on mass transfer and heterogeneous ozonolysis kinetics in aqueous–sucrose–maleic acid aerosol F. Marshall et al. 10.1039/C8CP01666F
- Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon L. Yee et al. 10.1021/acs.est.0c00805
- Timescales of secondary organic aerosols to reach equilibrium at various temperatures and relative humidities Y. Li & M. Shiraiwa 10.5194/acp-19-5959-2019
- Photochemical Aging Alters Secondary Organic Aerosol Partitioning Behavior J. Shilling et al. 10.1021/acsearthspacechem.9b00248
- Anthropogenic influences on the physical state of submicron particulate matter over a tropical forest A. Bateman et al. 10.5194/acp-17-1759-2017
- Factors controlling the evaporation of secondary organic aerosol from α‐pinene ozonolysis T. Yli‐Juuti et al. 10.1002/2016GL072364
- Organic Coating Reduces Hygroscopic Growth of Phase-Separated Aerosol Particles W. Li et al. 10.1021/acs.est.1c05901
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- A model framework to retrieve thermodynamic and kinetic properties of organic aerosol from composition-resolved thermal desorption measurements S. Schobesberger et al. 10.5194/acp-18-14757-2018
- Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Y. Li et al. 10.5194/acp-20-8103-2020
- Initial pH Governs Secondary Organic Aerosol Phase State and Morphology after Uptake of Isoprene Epoxydiols (IEPOX) Z. Lei et al. 10.1021/acs.est.2c01579
- Interactions between water vapor and atmospheric aerosols have key roles in air quality and climate change Z. Wu et al. 10.1093/nsr/nwy063
- Nitrogen-Containing, Light-Absorbing Oligomers Produced in Aerosol Particles Exposed to Methylglyoxal, Photolysis, and Cloud Cycling D. De Haan et al. 10.1021/acs.est.7b06105
- Evolution of Sea Spray Aerosol Particle Phase State Across a Phytoplankton Bloom P. Tumminello et al. 10.1021/acsearthspacechem.1c00186
- Particle phase-state variability in the North Atlantic free troposphere during summertime is determined by atmospheric transport patterns and sources Z. Cheng et al. 10.5194/acp-22-9033-2022
- Oxidative and Toxicological Evolution of Engineered Nanoparticles with Atmospherically Relevant Coatings Q. Liu et al. 10.1021/acs.est.8b06879
- Microscopic observation of a liquid-liquid-(semi)solid phase in polluted PM2.5 S. Gaikwad et al. 10.3389/fenvs.2022.947924
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- The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy Y. Zhang et al. 10.1021/acs.est.9b03317
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- Utilizing an electrical low-pressure impactor to indirectly probe water uptake via particle bounce measurements K. Fischer & G. Petrucci 10.5194/amt-14-7565-2021
- Single-particle Raman spectroscopy for studying physical and chemical processes of atmospheric particles Z. Liang et al. 10.5194/acp-22-3017-2022
- Potential role of intraparticle diffusion in dynamic partitioning of secondary organic aerosols C. Liu & J. Cao 10.1016/j.apr.2018.04.012
- Effects of Atmospheric Aging Processes on Nascent Sea Spray Aerosol Physicochemical Properties C. Kaluarachchi et al. 10.1021/acsearthspacechem.2c00258
- Gas to Particle Partitioning of Organic Acids in the Boreal Atmosphere A. Lutz et al. 10.1021/acsearthspacechem.9b00041
- Impact of Thermal Decomposition on Thermal Desorption Instruments: Advantage of Thermogram Analysis for Quantifying Volatility Distributions of Organic Species H. Stark et al. 10.1021/acs.est.7b00160
- Low-volatility compounds contribute significantly to isoprene secondary organic aerosol (SOA) under high-NO<sub><i>x</i></sub> conditions R. Schwantes et al. 10.5194/acp-19-7255-2019
- Hygroscopic behavior of aerosols generated from solutions of 3-methyl-1,2,3-butanetricarboxylic acid, its sodium salts, and its mixtures with NaCl L. Wu et al. 10.5194/acp-20-14103-2020
- The importance of size ranges in aerosol instrument intercomparisons: a case study for the Atmospheric Tomography Mission H. Guo et al. 10.5194/amt-14-3631-2021
2 citations as recorded by crossref.
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- Aerosol Phase State and Its Link to Chemical Composition and Liquid Water Content in a Subtropical Coastal Megacity Y. Liu et al. 10.1021/acs.est.9b01196
Saved (preprint)
Latest update: 19 Apr 2024
Short summary
The phase state of ambient particles was inferred from bounce measurements conducted at a rural site in central Alabama during the SOAS campaign. The organic-dominated ambient particles are mostly in the liquid phase at summertime conditions but they turn semisolid when dried in the measurement setup. Bounce humidograms reveal that the hygroscopicity and oxidation of the particles decreases the liquefying RH. The effect of oxidation is emphasized by oxidation flow reactor measurements.
The phase state of ambient particles was inferred from bounce measurements conducted at a rural...
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