Articles | Volume 15, issue 16
https://doi.org/10.5194/acp-15-9327-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-9327-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
21 Aug 2015
Research article |
| 21 Aug 2015
The influences of mass loading and rapid dilution of secondary organic aerosol on particle volatility
K. R. Kolesar
Department of Civil and Environmental Engineering, University of California, Davis, One Shields Avenue, Davis, California 95616, USA
C. Chen
Department of Civil and Environmental Engineering, University of California, Davis, One Shields Avenue, Davis, California 95616, USA
now at: Sustainable Energy Initiative, Santa Clara University, 500 El Camino Real, Santa Clara, California 95053, USA
D. Johnson
Department of Civil and Environmental Engineering, University of California, Davis, One Shields Avenue, Davis, California 95616, USA
now at: Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Rd, Berkeley, California 94720, USA
Department of Civil and Environmental Engineering, University of California, Davis, One Shields Avenue, Davis, California 95616, USA
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Cited
25 citations as recorded by crossref.
- Effects of oligomerization and decomposition on the nanoparticle growth: a model study A. Heitto et al. 10.5194/acp-22-155-2022
- Coupling Filter-Based Thermal Desorption Chemical Ionization Mass Spectrometry with Liquid Chromatography/Electrospray Ionization Mass Spectrometry for Molecular Analysis of Secondary Organic Aerosol Y. Huang et al. 10.1021/acs.est.0c01779
- Unexpected player in particle formation C. Cappa 10.1038/533478a
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
- Estimation of the volatility distribution of organic aerosol combining thermodenuder and isothermal dilution measurements E. Louvaris et al. 10.5194/amt-10-3909-2017
- Diverse Reactions in Highly Functionalized Organic Aerosols during Thermal Desorption Z. Zhao et al. 10.1021/acsearthspacechem.9b00312
- Comprehensive simulations of new particle formation events in Beijing with a cluster dynamics–multicomponent sectional model C. Li et al. 10.5194/acp-23-6879-2023
- Modeling the Effects of Dimerization and Bulk Diffusion on the Evaporative Behavior of Secondary Organic Aerosol Formed from α-Pinene and 1,3,5-Trimethylbenzene Y. Morino et al. 10.1021/acsearthspacechem.0c00106
- Quantifying the volatility of organic aerosol in the southeastern US P. Saha et al. 10.5194/acp-17-501-2017
- Isothermal Evaporation of α-Pinene Ozonolysis SOA: Volatility, Phase State, and Oligomeric Composition E. D’Ambro et al. 10.1021/acsearthspacechem.8b00084
- Experimental Determination of the Relationship Between Organic Aerosol Viscosity and Ice Nucleation at Upper Free Tropospheric Conditions S. Kasparoglu et al. 10.1029/2021JD036296
- Bulk Quantification and Molecular Characterization of Thermal Decomposition from the Thermal Desorption of Organic Aerosol Q. Guo et al. 10.1021/acsestair.4c00001
- A model framework to retrieve thermodynamic and kinetic properties of organic aerosol from composition-resolved thermal desorption measurements S. Schobesberger et al. 10.5194/acp-18-14757-2018
- Secondary Organic Aerosol (SOA) from Nitrate Radical Oxidation of Monoterpenes: Effects of Temperature, Dilution, and Humidity on Aerosol Formation, Mixing, and Evaporation C. Boyd et al. 10.1021/acs.est.7b01460
- The Influence of Absolute Mass Loading of Secondary Organic Aerosols on Their Phase State S. Jain et al. 10.3390/atmos9040131
- A core-shell box model for simulating viscosity dependent secondary organic aerosol (CSVA) and its application L. Jia & Y. Xu 10.1016/j.scitotenv.2021.147954
- Impact of aging on the sources, volatility, and viscosity of organic aerosols in Chinese outflows T. Feng et al. 10.5194/acp-23-611-2023
- Ozone and OH-induced oxidation of monoterpenes: Changes in the thermal properties of secondary organic aerosol (SOA) Å. Watne et al. 10.1016/j.jaerosci.2017.08.011
- Volatility of Cl-Initiated C12–C14 n-Alkylcyclohexane Secondary Organic Aerosol: Effects of NOx and Photoaging K. Wang et al. 10.1021/acsearthspacechem.2c00035
- Heating-Induced Evaporation of Nine Different Secondary Organic Aerosol Types K. Kolesar et al. 10.1021/acs.est.5b03038
- Enhanced Gas Uptake during α-Pinene Ozonolysis Points to a Burying Mechanism A. Vander Wall et al. 10.1021/acsearthspacechem.0c00163
- A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system T. Pan et al. 10.5194/amt-17-4915-2024
- Exploring Divergent Volatility Properties from Yield and Thermodenuder Measurements of Secondary Organic Aerosol from α-Pinene Ozonolysis P. Saha & A. Grieshop 10.1021/acs.est.6b00303
- Challenges in determining atmospheric organic aerosol volatility distributions using thermal evaporation techniques K. Cain et al. 10.1080/02786826.2020.1748172
- Exploring Volatility Properties of Discrete Secondary Organic Aerosol Constituents of α-Pinene and Polycyclic Aromatic Hydrocarbons Z. Babar et al. 10.1021/acsearthspacechem.0c00210
25 citations as recorded by crossref.
- Effects of oligomerization and decomposition on the nanoparticle growth: a model study A. Heitto et al. 10.5194/acp-22-155-2022
- Coupling Filter-Based Thermal Desorption Chemical Ionization Mass Spectrometry with Liquid Chromatography/Electrospray Ionization Mass Spectrometry for Molecular Analysis of Secondary Organic Aerosol Y. Huang et al. 10.1021/acs.est.0c01779
- Unexpected player in particle formation C. Cappa 10.1038/533478a
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
- Estimation of the volatility distribution of organic aerosol combining thermodenuder and isothermal dilution measurements E. Louvaris et al. 10.5194/amt-10-3909-2017
- Diverse Reactions in Highly Functionalized Organic Aerosols during Thermal Desorption Z. Zhao et al. 10.1021/acsearthspacechem.9b00312
- Comprehensive simulations of new particle formation events in Beijing with a cluster dynamics–multicomponent sectional model C. Li et al. 10.5194/acp-23-6879-2023
- Modeling the Effects of Dimerization and Bulk Diffusion on the Evaporative Behavior of Secondary Organic Aerosol Formed from α-Pinene and 1,3,5-Trimethylbenzene Y. Morino et al. 10.1021/acsearthspacechem.0c00106
- Quantifying the volatility of organic aerosol in the southeastern US P. Saha et al. 10.5194/acp-17-501-2017
- Isothermal Evaporation of α-Pinene Ozonolysis SOA: Volatility, Phase State, and Oligomeric Composition E. D’Ambro et al. 10.1021/acsearthspacechem.8b00084
- Experimental Determination of the Relationship Between Organic Aerosol Viscosity and Ice Nucleation at Upper Free Tropospheric Conditions S. Kasparoglu et al. 10.1029/2021JD036296
- Bulk Quantification and Molecular Characterization of Thermal Decomposition from the Thermal Desorption of Organic Aerosol Q. Guo et al. 10.1021/acsestair.4c00001
- A model framework to retrieve thermodynamic and kinetic properties of organic aerosol from composition-resolved thermal desorption measurements S. Schobesberger et al. 10.5194/acp-18-14757-2018
- Secondary Organic Aerosol (SOA) from Nitrate Radical Oxidation of Monoterpenes: Effects of Temperature, Dilution, and Humidity on Aerosol Formation, Mixing, and Evaporation C. Boyd et al. 10.1021/acs.est.7b01460
- The Influence of Absolute Mass Loading of Secondary Organic Aerosols on Their Phase State S. Jain et al. 10.3390/atmos9040131
- A core-shell box model for simulating viscosity dependent secondary organic aerosol (CSVA) and its application L. Jia & Y. Xu 10.1016/j.scitotenv.2021.147954
- Impact of aging on the sources, volatility, and viscosity of organic aerosols in Chinese outflows T. Feng et al. 10.5194/acp-23-611-2023
- Ozone and OH-induced oxidation of monoterpenes: Changes in the thermal properties of secondary organic aerosol (SOA) Å. Watne et al. 10.1016/j.jaerosci.2017.08.011
- Volatility of Cl-Initiated C12–C14 n-Alkylcyclohexane Secondary Organic Aerosol: Effects of NOx and Photoaging K. Wang et al. 10.1021/acsearthspacechem.2c00035
- Heating-Induced Evaporation of Nine Different Secondary Organic Aerosol Types K. Kolesar et al. 10.1021/acs.est.5b03038
- Enhanced Gas Uptake during α-Pinene Ozonolysis Points to a Burying Mechanism A. Vander Wall et al. 10.1021/acsearthspacechem.0c00163
- A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system T. Pan et al. 10.5194/amt-17-4915-2024
- Exploring Divergent Volatility Properties from Yield and Thermodenuder Measurements of Secondary Organic Aerosol from α-Pinene Ozonolysis P. Saha & A. Grieshop 10.1021/acs.est.6b00303
- Challenges in determining atmospheric organic aerosol volatility distributions using thermal evaporation techniques K. Cain et al. 10.1080/02786826.2020.1748172
- Exploring Volatility Properties of Discrete Secondary Organic Aerosol Constituents of α-Pinene and Polycyclic Aromatic Hydrocarbons Z. Babar et al. 10.1021/acsearthspacechem.0c00210
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Latest update: 01 Apr 2025
Short summary
Secondary organic aerosol from the dark ozonolysis of α‑pinene was formed at a range of mass loadings from 1 to 800μg m-3. The amount of mass loss during evaporation in a thermodenuder was found to be independent of mass loading. A kinetic model of evaporation was fit to the observations and good agreement was obtained when the particle was either composed of dimers that decompose into semi-volatile monomers or when it was composed of low-volatility compounds that evaporate directly.
Secondary organic aerosol from the dark ozonolysis of α‑pinene was formed at a range of mass...
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