Articles | Volume 15, issue 16
https://doi.org/10.5194/acp-15-9109-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-9109-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
17 Aug 2015
Research article |
| 17 Aug 2015
Aqueous-phase oligomerization of methyl vinyl ketone through photooxidation – Part 2: Development of the chemical mechanism and atmospheric implications
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado, USA
Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, Colorado, USA
P. Renard
Aix Marseille Université, CNRS, LCE FRE 3416, 13331, Marseille, France
S. Tlili
Aix Marseille Université, CNRS, LCE FRE 3416, 13331, Marseille, France
S. Ravier
Aix Marseille Université, CNRS, LCE FRE 3416, 13331, Marseille, France
J.-L. Clément
Aix Marseille Université, CNRS, ICR UMR7273, 13397, Marseille, France
A. Monod
Aix Marseille Université, CNRS, LCE FRE 3416, 13331, Marseille, France
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Cited
18 citations as recorded by crossref.
- Cloud Processing of Secondary Organic Aerosol from Isoprene and Methacrolein Photooxidation C. Giorio et al. 10.1021/acs.jpca.7b05933
- Modeling the partitioning of organic chemical species in cloud phases with CLEPS (1.1) C. Rose et al. 10.5194/acp-18-2225-2018
- Dark, Photolysis, and Oxidation Reaction Mechanism of Gaseous Dicarbonyls Based on PTR-TOF-MS X. Ma et al. 10.1021/acsestair.5c00276
- Oxidation of low-molecular-weight organic compounds in cloud droplets: development of the Jülich Aqueous-phase Mechanism of Organic Chemistry (JAMOC) in CAABA/MECCA (version 4.5.0) S. Rosanka et al. 10.5194/gmd-14-4103-2021
- Water binding to the atmospheric oxidation product methyl vinyl ketone C. Cabezas et al. 10.1016/j.saa.2021.120846
- Opinion: Challenges and needs of tropospheric chemical mechanism development B. Ervens et al. 10.5194/acp-24-13317-2024
- Oligomer formation in the troposphere: from experimental knowledge to 3-D modeling V. Lemaire et al. 10.5194/gmd-9-1361-2016
- CLEPS 1.0: A new protocol for cloud aqueous phase oxidation of VOC mechanisms C. Mouchel-Vallon et al. 10.5194/gmd-10-1339-2017
- Kinetics and Mechanisms of Aqueous-Phase Reactions of Triplet-State Imidazole-2-carboxaldehyde and 3,4-Dimethoxybenzaldehyde with α,β-Unsaturated Carbonyl Compounds K. Aregahegn et al. 10.1021/acs.jpca.2c05015
- Study on the kinetics and product characteristics of aqueous-phase oxidation of Eugenol and acetosyringone upon 254 nm/313 nm irradiation Z. Wang et al. 10.1007/s11869-025-01717-4
- Biogenic, urban, and wildfire influences on the molecular composition of dissolved organic compounds in cloud water R. Cook et al. 10.5194/acp-17-15167-2017
- Spectral changes induced by pH variation of aqueous extracts derived from biomass burning aerosols: Under dark and in presence of simulated sunlight irradiation J. Cai et al. 10.1016/j.atmosenv.2018.04.037
- Formation of Organosulfur Compounds through Transition Metal Ion-Catalyzed Aqueous Phase Reactions L. Huang et al. 10.1021/acs.estlett.8b00225
- Aqueous-phase oxidation of three phenolic compounds by hydroxyl radical: Insight into secondary organic aerosol formation yields, mechanisms, products and optical properties Z. Ye et al. 10.1016/j.atmosenv.2019.117240
- Rapid Aqueous-Phase Photooxidation of Dimers in the α-Pinene Secondary Organic Aerosol R. Zhao et al. 10.1021/acs.estlett.7b00148
- Puy de Dôme Station (France): A Stoichiometric Approach to Compound Classification in Clouds P. Renard et al. 10.1029/2022JD036635
- Aqueous phase oligomerization of α,β-unsaturated carbonyls and acids investigated using ion mobility spectrometry coupled to mass spectrometry (IMS-MS) P. Renard et al. 10.1016/j.atmosenv.2015.10.060
- Fog composition at Baengnyeong Island in the eastern Yellow Sea: detecting markers of aqueous atmospheric oxidations A. Boris et al. 10.5194/acp-16-437-2016
16 citations as recorded by crossref.
- Cloud Processing of Secondary Organic Aerosol from Isoprene and Methacrolein Photooxidation C. Giorio et al. 10.1021/acs.jpca.7b05933
- Modeling the partitioning of organic chemical species in cloud phases with CLEPS (1.1) C. Rose et al. 10.5194/acp-18-2225-2018
- Dark, Photolysis, and Oxidation Reaction Mechanism of Gaseous Dicarbonyls Based on PTR-TOF-MS X. Ma et al. 10.1021/acsestair.5c00276
- Oxidation of low-molecular-weight organic compounds in cloud droplets: development of the Jülich Aqueous-phase Mechanism of Organic Chemistry (JAMOC) in CAABA/MECCA (version 4.5.0) S. Rosanka et al. 10.5194/gmd-14-4103-2021
- Water binding to the atmospheric oxidation product methyl vinyl ketone C. Cabezas et al. 10.1016/j.saa.2021.120846
- Opinion: Challenges and needs of tropospheric chemical mechanism development B. Ervens et al. 10.5194/acp-24-13317-2024
- Oligomer formation in the troposphere: from experimental knowledge to 3-D modeling V. Lemaire et al. 10.5194/gmd-9-1361-2016
- CLEPS 1.0: A new protocol for cloud aqueous phase oxidation of VOC mechanisms C. Mouchel-Vallon et al. 10.5194/gmd-10-1339-2017
- Kinetics and Mechanisms of Aqueous-Phase Reactions of Triplet-State Imidazole-2-carboxaldehyde and 3,4-Dimethoxybenzaldehyde with α,β-Unsaturated Carbonyl Compounds K. Aregahegn et al. 10.1021/acs.jpca.2c05015
- Study on the kinetics and product characteristics of aqueous-phase oxidation of Eugenol and acetosyringone upon 254 nm/313 nm irradiation Z. Wang et al. 10.1007/s11869-025-01717-4
- Biogenic, urban, and wildfire influences on the molecular composition of dissolved organic compounds in cloud water R. Cook et al. 10.5194/acp-17-15167-2017
- Spectral changes induced by pH variation of aqueous extracts derived from biomass burning aerosols: Under dark and in presence of simulated sunlight irradiation J. Cai et al. 10.1016/j.atmosenv.2018.04.037
- Formation of Organosulfur Compounds through Transition Metal Ion-Catalyzed Aqueous Phase Reactions L. Huang et al. 10.1021/acs.estlett.8b00225
- Aqueous-phase oxidation of three phenolic compounds by hydroxyl radical: Insight into secondary organic aerosol formation yields, mechanisms, products and optical properties Z. Ye et al. 10.1016/j.atmosenv.2019.117240
- Rapid Aqueous-Phase Photooxidation of Dimers in the α-Pinene Secondary Organic Aerosol R. Zhao et al. 10.1021/acs.estlett.7b00148
- Puy de Dôme Station (France): A Stoichiometric Approach to Compound Classification in Clouds P. Renard et al. 10.1029/2022JD036635
2 citations as recorded by crossref.
- Aqueous phase oligomerization of α,β-unsaturated carbonyls and acids investigated using ion mobility spectrometry coupled to mass spectrometry (IMS-MS) P. Renard et al. 10.1016/j.atmosenv.2015.10.060
- Fog composition at Baengnyeong Island in the eastern Yellow Sea: detecting markers of aqueous atmospheric oxidations A. Boris et al. 10.5194/acp-16-437-2016
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Latest update: 04 Nov 2025
Short summary
A detailed chemical mechanism is developed based on laboratory studies that predicts the formation of high molecular weight compounds in the aqueous phase of atmospheric aerosol particles. Model simulations using this mechanism for atmospheric conditions show that these pathways are likely not a substantial source of particle mass, unless unidentified precursors for these compounds exist that were not taken into account so far and/or the solubility of oxygen in aerosol water is overestimated.
A detailed chemical mechanism is developed based on laboratory studies that predicts the...
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