Articles | Volume 15, issue 14
https://doi.org/10.5194/acp-15-8301-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-8301-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Formation and aging of secondary organic aerosol from toluene: changes in chemical composition, volatility, and hygroscopicity
The University of Texas at Austin, Austin, Texas, USA
Carnegie Mellon University, Pittsburgh, Pennsylvania, USA
A. L. Paciga
Carnegie Mellon University, Pittsburgh, Pennsylvania, USA
now at: Phillips66®, Bartlesville, Oklahoma, USA
K. M. Cerully
Georgia Institute of Technology, Atlanta, Georgia, USA
now at: TSI, Inc., Shoreview, Minnesota, USA
Georgia Institute of Technology, Atlanta, Georgia, USA
N. M. Donahue
Carnegie Mellon University, Pittsburgh, Pennsylvania, USA
S. N. Pandis
Carnegie Mellon University, Pittsburgh, Pennsylvania, USA
University of Patras, Patras, Greece
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Short summary
Secondary organic aerosol (SOA) is transformed after its initial formation. We explored the effects of this chemical aging on the composition, mass yield, volatility, and hygroscopicity of SOA formed from the photo-oxidation of small aromatic volatile organic compounds. Higher exposure to the hydroxyl radical resulted in different SOA composition, average carbon oxidation state, and mass yield. The vapor pressure of SOA formed under different conditions varied by as much as a factor of 30.
Secondary organic aerosol (SOA) is transformed after its initial formation. We explored the...
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