Articles | Volume 15, issue 14
https://doi.org/10.5194/acp-15-7765-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-7765-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
16 Jul 2015
Research article |
| 16 Jul 2015
Phase partitioning and volatility of secondary organic aerosol components formed from α-pinene ozonolysis and OH oxidation: the importance of accretion products and other low volatility compounds
F. D. Lopez-Hilfiker
Department of Atmospheric Sciences, University of Washington, Seattle, WA, 98195, USA
Department of Atmospheric Sciences, University of Washington, Seattle, WA, 98195, USA
Institute for Meteorology and Climate Research, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen, Germany
Department of Physics, P.O. Box 64, 00014, University of Helsinki, Helsinki, Finland
Institute for Energy and Climate Research (IEK-8), Forschungszentrum Jülich, 52425 Jülich, Germany
F. Rubach
Institute for Energy and Climate Research (IEK-8), Forschungszentrum Jülich, 52425 Jülich, Germany
E. Kleist
Institute of Bio-Geosciences (IBG-2), Forschungszentrum Jülich, 52425 Jülich, Germany
J. Wildt
Institute of Bio-Geosciences (IBG-2), Forschungszentrum Jülich, 52425 Jülich, Germany
Th. F. Mentel
Institute for Energy and Climate Research (IEK-8), Forschungszentrum Jülich, 52425 Jülich, Germany
A. J. Carrasquillo
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA
K. E. Daumit
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA
J. F. Hunter
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA
J. H. Kroll
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA
D. R. Worsnop
Department of Physics, P.O. Box 64, 00014, University of Helsinki, Helsinki, Finland
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, MA, USA
J. A. Thornton
CORRESPONDING AUTHOR
Department of Atmospheric Sciences, University of Washington, Seattle, WA, 98195, USA
Department of Physics, P.O. Box 64, 00014, University of Helsinki, Helsinki, Finland
Institute for Energy and Climate Research (IEK-8), Forschungszentrum Jülich, 52425 Jülich, Germany
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Short summary
We measured a large suite organic compounds using a recently developed Filter Inlet for Gases and AEROsols (FIGAERO) coupled to a (HR-ToF-CIMS). The instrument was deployed on environmental simulation chambers to study monoterpene oxidation as a secondary organic aerosol (SOA) source. We find that approximately 50% of the detected particle phase mass is associated with compounds having effective vapor pressures 4, or more, orders of magnitude lower than commonly measured products.
We measured a large suite organic compounds using a recently developed Filter Inlet for Gases...
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