Articles | Volume 15, issue 12
https://doi.org/10.5194/acp-15-6851-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-6851-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
23 Jun 2015
Research article |
| 23 Jun 2015
Heterogeneous reaction of peroxyacetic acid and hydrogen peroxide on ambient aerosol particles under dry and humid conditions: kinetics, mechanism and implications
Q. Q. Wu
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
L. B. Huang
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
H. Liang
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
Y. Zhao
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
now at: Department of Chemistry, University of California, Irvine, CA 92697, USA
D. Huang
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
now at: Department of Earth Sciences, Zhejiang University, Hangzhou, Zhejiang Province 310027, China
Z. M. Chen
CORRESPONDING AUTHOR
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
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Cited
22 citations as recorded by crossref.
- Heterogeneous photooxidation of sulfur dioxide in the presence of airborne mineral dust particles J. Park & M. Jang 10.1039/C6RA09601H
- Photochemical Aging of Beijing Urban PM2.5: HONO Production F. Bao et al. 10.1021/acs.est.8b00538
- Investigating water adsorption onto natural mineral dust particles: Linking DRIFTS experiments and BET theory N. Joshi et al. 10.1016/j.aeolia.2017.06.001
- The OH-initiated oxidation of atmospheric peroxyacetic acid: Experimental and model studies H. Wu et al. 10.1016/j.atmosenv.2017.05.038
- A light-driven burst of hydroxyl radicals dominates oxidation chemistry in newly activated cloud droplets S. Paulson et al. 10.1126/sciadv.aav7689
- Partitioning of hydrogen peroxide in gas-liquid and gas-aerosol phases X. Xuan et al. 10.5194/acp-20-5513-2020
- Persistent Uptake of H2O2 onto Ambient PM2.5 via Dark-Fenton Chemistry X. Qin et al. 10.1021/acs.est.2c03630
- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Thermal treatment of Shengli lignite and subsequent oxidation Y. Li et al. 10.1016/j.jaap.2020.104810
- Reactive Uptake of Hydroperoxymethyl Thioformate to Sodium Chloride and Sodium Iodide Aerosol Particles C. Jernigan et al. 10.1021/acs.jpca.2c03222
- Heterogeneous Reaction of Peroxyacetyl Nitrate on Real-World PM2.5 Aerosols: Kinetics, Influencing Factors, and Atmospheric Implications M. Sun et al. 10.1021/acs.est.2c03050
- Reaction between CH<sub>3</sub>C(O)OOH (peracetic acid) and OH in the gas phase: a combined experimental and theoretical study of the kinetics and mechanism M. Berasategui et al. 10.5194/acp-20-13541-2020
- Kinetics of Heterogeneous Reaction of Sulfur Dioxide on Authentic Mineral Dust: Effects of Relative Humidity and Hydrogen Peroxide L. Huang et al. 10.1021/acs.est.5b03930
- Atmospheric chemistry of bioaerosols: heterogeneous and multiphase reactions with atmospheric oxidants and other trace gases A. Estillore et al. 10.1039/C6SC02353C
- Insights into HO<sub><i>x</i></sub> and RO<sub><i>x</i></sub> chemistry in the boreal forest via measurement of peroxyacetic acid, peroxyacetic nitric anhydride (PAN) and hydrogen peroxide J. Crowley et al. 10.5194/acp-18-13457-2018
- Kinetics of Heterogeneous Reaction of H2O2 and SO2 on Coal Fly Ash: Temperature Effect and Their Synergistic Effects L. Zhou et al. 10.3389/fenvs.2022.876289
- Molecular composition of secondary organic aerosol from styrene under different NO and humidity conditions S. Yu et al. 10.1016/j.atmosres.2021.105950
- Impact of aerosol in-situ peroxide formations induced by metal complexes on atmospheric H2O2 budgets H. Song et al. 10.1016/j.scitotenv.2023.164455
- Phase State Regulates Photochemical HONO Production from NaNO3/Dicarboxylic Acid Mixtures Q. Li et al. 10.1021/acs.est.3c10980
- Observation of atmospheric peroxides during Wangdu Campaign 2014 at a rural site in the North China Plain Y. Wang et al. 10.5194/acp-16-10985-2016
- Calculating ambient aerosol surface area concentrations using aerosol light scattering enhancement measurements Y. Kuang et al. 10.1016/j.atmosenv.2019.116919
- Impacts of heterogeneous reactions to atmospheric peroxides: Observations and budget analysis study M. Qin et al. 10.1016/j.atmosenv.2018.04.005
22 citations as recorded by crossref.
- Heterogeneous photooxidation of sulfur dioxide in the presence of airborne mineral dust particles J. Park & M. Jang 10.1039/C6RA09601H
- Photochemical Aging of Beijing Urban PM2.5: HONO Production F. Bao et al. 10.1021/acs.est.8b00538
- Investigating water adsorption onto natural mineral dust particles: Linking DRIFTS experiments and BET theory N. Joshi et al. 10.1016/j.aeolia.2017.06.001
- The OH-initiated oxidation of atmospheric peroxyacetic acid: Experimental and model studies H. Wu et al. 10.1016/j.atmosenv.2017.05.038
- A light-driven burst of hydroxyl radicals dominates oxidation chemistry in newly activated cloud droplets S. Paulson et al. 10.1126/sciadv.aav7689
- Partitioning of hydrogen peroxide in gas-liquid and gas-aerosol phases X. Xuan et al. 10.5194/acp-20-5513-2020
- Persistent Uptake of H2O2 onto Ambient PM2.5 via Dark-Fenton Chemistry X. Qin et al. 10.1021/acs.est.2c03630
- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Thermal treatment of Shengli lignite and subsequent oxidation Y. Li et al. 10.1016/j.jaap.2020.104810
- Reactive Uptake of Hydroperoxymethyl Thioformate to Sodium Chloride and Sodium Iodide Aerosol Particles C. Jernigan et al. 10.1021/acs.jpca.2c03222
- Heterogeneous Reaction of Peroxyacetyl Nitrate on Real-World PM2.5 Aerosols: Kinetics, Influencing Factors, and Atmospheric Implications M. Sun et al. 10.1021/acs.est.2c03050
- Reaction between CH<sub>3</sub>C(O)OOH (peracetic acid) and OH in the gas phase: a combined experimental and theoretical study of the kinetics and mechanism M. Berasategui et al. 10.5194/acp-20-13541-2020
- Kinetics of Heterogeneous Reaction of Sulfur Dioxide on Authentic Mineral Dust: Effects of Relative Humidity and Hydrogen Peroxide L. Huang et al. 10.1021/acs.est.5b03930
- Atmospheric chemistry of bioaerosols: heterogeneous and multiphase reactions with atmospheric oxidants and other trace gases A. Estillore et al. 10.1039/C6SC02353C
- Insights into HO<sub><i>x</i></sub> and RO<sub><i>x</i></sub> chemistry in the boreal forest via measurement of peroxyacetic acid, peroxyacetic nitric anhydride (PAN) and hydrogen peroxide J. Crowley et al. 10.5194/acp-18-13457-2018
- Kinetics of Heterogeneous Reaction of H2O2 and SO2 on Coal Fly Ash: Temperature Effect and Their Synergistic Effects L. Zhou et al. 10.3389/fenvs.2022.876289
- Molecular composition of secondary organic aerosol from styrene under different NO and humidity conditions S. Yu et al. 10.1016/j.atmosres.2021.105950
- Impact of aerosol in-situ peroxide formations induced by metal complexes on atmospheric H2O2 budgets H. Song et al. 10.1016/j.scitotenv.2023.164455
- Phase State Regulates Photochemical HONO Production from NaNO3/Dicarboxylic Acid Mixtures Q. Li et al. 10.1021/acs.est.3c10980
- Observation of atmospheric peroxides during Wangdu Campaign 2014 at a rural site in the North China Plain Y. Wang et al. 10.5194/acp-16-10985-2016
- Calculating ambient aerosol surface area concentrations using aerosol light scattering enhancement measurements Y. Kuang et al. 10.1016/j.atmosenv.2019.116919
- Impacts of heterogeneous reactions to atmospheric peroxides: Observations and budget analysis study M. Qin et al. 10.1016/j.atmosenv.2018.04.005
Saved (final revised paper)
Latest update: 26 Apr 2024
Short summary
The present study provides the first measurement for the uptake coefficient of gaseous peroxide compounds including peroxyacetic acid and hydrogen peroxide on the ambient particles (PM2.5 and Asian Storm Dust) over a wide range of relative humidity. The measured uptake coefficient values suggest that the heterogeneous reaction on the ambient particles plays an important role in the atmospheric budgets of peroxide compounds and potentially affects the components of aerosols in the atmosphere.
The present study provides the first measurement for the uptake coefficient of gaseous peroxide...
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