Articles | Volume 15, issue 11
https://doi.org/10.5194/acp-15-6305-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-6305-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
10 Jun 2015
Research article |
| 10 Jun 2015
Connecting the solubility and CCN activation of complex organic aerosols: a theoretical study using solubility distributions
I. Riipinen
CORRESPONDING AUTHOR
Department of Environmental Science and Analytical Chemistry, Stockholm University, Stockholm, Sweden
Center of Atmospheric Particle Studies, Carnegie Mellon University, Pittsburgh, PA, USA
N. Rastak
Department of Environmental Science and Analytical Chemistry, Stockholm University, Stockholm, Sweden
S. N. Pandis
Center of Atmospheric Particle Studies, Carnegie Mellon University, Pittsburgh, PA, USA
Department of Chemical Engineering, University of Patras, Patras, Greece
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- An inversion method for polarity distribution of atmospheric water-soluble organic matter W. Lee et al. 10.1080/02786826.2020.1795482
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- Solubility Considerations for Cloud Condensation Nuclei (CCN) Activity Analysis of Pure and Mixed Black Carbon Species K. Gohil et al. 10.1021/acs.jpca.2c08585
- Complex Hygroscopic Behavior of Ambient Aerosol Particles Revealed by a Piezoelectric Technique C. Jose et al. 10.1021/acsearthspacechem.3c00347
- Inverse modelling of Köhler theory – Part 1: A response surface analysis of CCN spectra with respect to surface-active organic species S. Lowe et al. 10.5194/acp-16-10941-2016
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- Hygroscopic growth study in the framework of EARLINET during the SLOPE I campaign: synergy of remote sensing and in situ instrumentation A. Bedoya-Velásquez et al. 10.5194/acp-18-7001-2018
- Water Activity from Equilibrium Molecular Dynamics Simulations and Kirkwood-Buff Theory M. Lbadaoui-Darvas & S. Takahama 10.1021/acs.jpcb.9b06735
- Organic aerosol processing in tropical deep convective clouds: Development of a new model (CRM‐ORG) and implications for sources of particle number B. Murphy et al. 10.1002/2015JD023551
35 citations as recorded by crossref.
- Microphysical explanation of the RH‐dependent water affinity of biogenic organic aerosol and its importance for climate N. Rastak et al. 10.1002/2017GL073056
- Resolving the mechanisms of hygroscopic growth and cloud condensation nuclei activity for organic particulate matter P. Liu et al. 10.1038/s41467-018-06622-2
- Polarity-Dependent Chemical Characteristics of Water-Soluble Organic Matter from Laboratory-Generated Biomass-Burning Revealed by 1-Octanol–Water Partitioning W. Lee et al. 10.1021/acs.est.9b01691
- An inversion method for polarity distribution of atmospheric water-soluble organic matter W. Lee et al. 10.1080/02786826.2020.1795482
- Cloud condensation nuclei activity and hygroscopicity of fresh and aged cooking organic aerosol Y. Li et al. 10.1016/j.atmosenv.2017.11.035
- Solubility Considerations for Cloud Condensation Nuclei (CCN) Activity Analysis of Pure and Mixed Black Carbon Species K. Gohil et al. 10.1021/acs.jpca.2c08585
- Complex Hygroscopic Behavior of Ambient Aerosol Particles Revealed by a Piezoelectric Technique C. Jose et al. 10.1021/acsearthspacechem.3c00347
- Inverse modelling of Köhler theory – Part 1: A response surface analysis of CCN spectra with respect to surface-active organic species S. Lowe et al. 10.5194/acp-16-10941-2016
- Cloud condensation nuclei activation properties of Mediterranean pollen types considering organic chemical composition and surface tension effects A. Casans et al. 10.1016/j.atmosenv.2023.119961
- Using Novel Molecular-Level Chemical Composition Observations of High Arctic Organic Aerosol for Predictions of Cloud Condensation Nuclei K. Siegel et al. 10.1021/acs.est.2c02162
- Water Solubility Distribution of Organic Matter Accounts for the Discrepancy in Hygroscopicity among Sub- and Supersaturated Humidity Regimes W. Lee et al. 10.1021/acs.est.2c04647
- Secondary aerosol formation promotes water uptake by organic-rich wildfire haze particles in equatorial Asia J. Chen et al. 10.5194/acp-18-7781-2018
- Surface-Active β-Caryophyllene Oxidation Products at the Air/Aqueous Interface A. Bé et al. 10.1021/acsearthspacechem.9b00185
- Interactions of organosulfates with water vapor under sub- and supersaturated conditions C. Peng et al. 10.5194/acp-21-7135-2021
- Liquid–Liquid Phase Separation Can Drive Aerosol Droplet Growth in Supersaturated Regimes K. Malek et al. 10.1021/acsenvironau.3c00015
- The Relationship between Molecular Size and Polarity of Atmospheric Organic Aerosol in Singapore and Its Implications for Volatility and Light Absorption Properties L. Yang et al. 10.1021/acsearthspacechem.1c00274
- Accounting for Cloud Nucleation Activation Mechanism of Secondary Organic Matter from α-Pinene Oxidation Using Experimentally Retrieved Water Solubility Distributions W. Lee et al. 10.1021/acs.est.3c03039
- Water uptake by fresh Indonesian peat burning particles is limited by water-soluble organic matter J. Chen et al. 10.5194/acp-17-11591-2017
- Tropical and Boreal Forest – Atmosphere Interactions: A Review P. Artaxo et al. 10.16993/tellusb.34
- Hybrid water adsorption and solubility partitioning for aerosol hygroscopicity and droplet growth K. Gohil et al. 10.5194/acp-22-12769-2022
- Modelling the hygroscopic growth factors of aerosol material containing a large water-soluble organic fraction, collected at the Storm Peak Laboratory S. Clegg et al. 10.1016/j.atmosenv.2019.05.068
- Hygroscopicity of nitrogen-containing organic carbon compounds: o-aminophenol and p-aminophenol K. Malek et al. 10.1039/D2EM00163B
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Direct Comparison of the Submicron Aerosol Hygroscopicity of Water-Soluble Sugars J. Dawson et al. 10.1021/acsearthspacechem.0c00159
- Hygroscopicity of amino acids and their effect on the water uptake of ammonium sulfate in the mixed aerosol particles Q. Luo et al. 10.1016/j.scitotenv.2020.139318
- A Review on Laboratory Studies and Field Measurements of Atmospheric Organic Aerosol Hygroscopicity and Its Parameterization Based on Oxidation Levels Y. Kuang et al. 10.1007/s40726-020-00164-2
- A Method for the Measurement of the Water Solubility Distribution of Atmospheric Organic Aerosols A. Liangou et al. 10.1021/acs.est.1c06854
- 1-octanol-water partitioning as a classifier of water soluble organic matters: Implication for solubility distribution M. Kuwata & W. Lee 10.1080/02786826.2017.1283004
- A Significant Portion of Water-Soluble Organic Matter in Fresh Biomass Burning Particles Does Not Contribute to Hygroscopic Growth: An Application of Polarity Segregation by 1-Octanol–Water Partitioning Method J. Chen et al. 10.1021/acs.est.9b01696
- Low hygroscopic scattering enhancement of boreal aerosol and the implications for a columnar optical closure study P. Zieger et al. 10.5194/acp-15-7247-2015
- Cloud droplet activation of secondary organic aerosol is mainly controlled by molecular weight, not water solubility J. Wang et al. 10.5194/acp-19-941-2019
- Why would apparent κ linearly change with O/C? Assessing the role of volatility, solubility, and surface activity of organic aerosols S. Nakao 10.1080/02786826.2017.1352082
- Semivolatile POA and parameterized total combustion SOA in CMAQv5.2: impacts on source strength and partitioning B. Murphy et al. 10.5194/acp-17-11107-2017
- Hygroscopic growth study in the framework of EARLINET during the SLOPE I campaign: synergy of remote sensing and in situ instrumentation A. Bedoya-Velásquez et al. 10.5194/acp-18-7001-2018
- Water Activity from Equilibrium Molecular Dynamics Simulations and Kirkwood-Buff Theory M. Lbadaoui-Darvas & S. Takahama 10.1021/acs.jpcb.9b06735
Saved (final revised paper)
Saved (final revised paper)
Latest update: 25 Apr 2024
Short summary
Atmospheric organic aerosol is complex and thus a challenge to model. We introduce a theoretical framework (solubility distributions) to represent the solubility of multicomponent mixtures. Using the framework, we evaluate the commonly made assumptions about the cloud condensation nucleus (CCN) activity of organic mixtures. We find that material with water solubilities larger than 0.1-100 g/L can usually be treated as completely soluble, which simplifies the treatment of organic CCN.
Atmospheric organic aerosol is complex and thus a challenge to model. We introduce a theoretical...
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