Research article
09 Jun 2015
Research article
| 09 Jun 2015
A large and ubiquitous source of atmospheric formic acid
D. B. Millet et al.
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Cited
122 citations as recorded by crossref.
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120 citations as recorded by crossref.
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- Emission of formic and acetic acids from two Colorado soils A. Mielnik et al. 10.1039/C8EM00356D
- Kinetics and Product Yields of the OH Initiated Oxidation of Hydroxymethyl Hydroperoxide H. Allen et al. 10.1021/acs.jpca.8b04577
- Simultaneous Measurements of O 3 and HCOOH Vertical Fluxes Indicate Rapid In‐Canopy Terpene Chemistry Enhances O 3 Removal Over Mixed Temperate Forests M. Vermeuel et al. 10.1029/2020GL090996
- High gas-phase mixing ratios of formic and acetic acid in the High Arctic E. Mungall et al. 10.5194/acp-18-10237-2018
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- The reaction of methyl peroxy and hydroxyl radicals as a major source of atmospheric methanol J. Müller et al. 10.1038/ncomms13213
- Pollution trace gas distributions and their transport in the Asian monsoon upper troposphere and lowermost stratosphere during the StratoClim campaign 2017 S. Johansson et al. 10.5194/acp-20-14695-2020
- Path sampling for atmospheric reactions: formic acid catalysed conversion of SO3 + H2O to H2SO4 C. Daub et al. 10.7717/peerj-pchem.7
- Effects of Low-Molecular-Weight Organics on the Photoreduction of Bromate in Water Z. Chen et al. 10.1021/acsestengg.0c00244
- Bidirectional Ecosystem–Atmosphere Fluxes of Volatile Organic Compounds Across the Mass Spectrum: How Many Matter? D. Millet et al. 10.1021/acsearthspacechem.8b00061
- Atmospheric VOC measurements at a High Arctic site: characteristics and source apportionment J. Pernov et al. 10.5194/acp-21-2895-2021
- Seasonality of Formic Acid (HCOOH) in London during the ClearfLo Campaign T. Bannan et al. 10.1002/2017JD027064
- Spaceborne Measurements of Formic and Acetic Acids: A Global View of the Regional Sources B. Franco et al. 10.1029/2019GL086239
- Evidence for lactone formation during infrared multiple photon dissociation spectroscopy of bromoalkanoate doped salt clusters N. Bersenkowitsch et al. 10.1039/D0CP00272K
- Investigating the evolution of water-soluble organic carbon in evaporating cloud water V. Pratap et al. 10.1039/D0EA00005A
- Seasonal Flux Measurements over a Colorado Pine Forest Demonstrate a Persistent Source of Organic Acids S. Fulgham et al. 10.1021/acsearthspacechem.9b00182
- Long-term variability and source signature of gases emitted from oil & natural gas and cattle feedlot operations in the Colorado front range I. Ortega et al. 10.1016/j.atmosenv.2021.118663
- Atmospheric OH Oxidation of Three Chlorinated Aromatic Herbicides T. Murschell & D. Farmer 10.1021/acs.est.7b06025
- Measuring Biosphere–Atmosphere Exchange of Short-Lived Climate Forcers and Their Precursors D. Farmer & M. Riches 10.1021/acs.accounts.0c00203
- Development of an online-coupled MARGA upgrade for the 2 h interval quantification of low-molecular-weight organic acids in the gas and particle phases B. Stieger et al. 10.5194/amt-12-281-2019
- Microlayer source of oxygenated volatile organic compounds in the summertime marine Arctic boundary layer E. Mungall et al. 10.1073/pnas.1620571114
- The acidity of atmospheric particles and clouds H. Pye et al. 10.5194/acp-20-4809-2020
- HCOOH in the Remote Atmosphere: Constraints from Atmospheric Tomography (ATom) Airborne Observations X. Chen et al. 10.1021/acsearthspacechem.1c00049
- Primary and Secondary Sources of Gas-Phase Organic Acids from Diesel Exhaust B. Friedman et al. 10.1021/acs.est.7b01169
- Direct retrieval of isoprene from satellite-based infrared measurements D. Fu et al. 10.1038/s41467-019-11835-0
- Atmospheric Chemistry of Enols: The Formation Mechanisms of Formic and Peroxyformic Acids in Ozonolysis of Vinyl Alcohol X. Lei et al. 10.1021/acs.jpca.0c01480
- Unimolecular decay strongly limits the atmospheric impact of Criegee intermediates L. Vereecken et al. 10.1039/C7CP05541B
- Global simulation of tropospheric chemistry at 12.5 km resolution: performance and evaluation of the GEOS-Chem chemical module (v10-1) within the NASA GEOS Earth system model (GEOS-5 ESM) L. Hu et al. 10.5194/gmd-11-4603-2018
- Isomerization and decomposition reactions of acetaldehyde relevant to atmospheric processes from dynamics simulations on neural network-based potential energy surfaces S. Käser et al. 10.1063/5.0008223
- Chemistrees: Data-Driven Identification of Reaction Pathways via Machine Learning S. Roet et al. 10.1021/acs.jctc.1c00458
- Physicochemical uptake and release of volatile organic compounds by soil in coated-wall flow tube experiments with ambient air G. Li et al. 10.5194/acp-19-2209-2019
- Global Estimates of Inorganic Nitrogen Deposition Across Four Decades D. Ackerman et al. 10.1029/2018GB005990
- Underrated primary biogenic origin and lifetime of atmospheric formic and acetic acid X. Lee et al. 10.1038/s41598-021-86542-2
- Hydrogen-Bond Topology Is More Important Than Acid/Base Strength in Atmospheric Prenucleation Clusters S. Harold et al. 10.1021/acs.jpca.1c10754
- Changes to simulated global atmospheric composition resulting from recent revisions to isoprene oxidation chemistry M. Khan et al. 10.1016/j.atmosenv.2020.117914
- Development and evaluation of a new compact mechanism for aromatic oxidation in atmospheric models K. Bates et al. 10.5194/acp-21-18351-2021
- High upward fluxes of formic acid from a boreal forest canopy S. Schobesberger et al. 10.1002/2016GL069599
- Criegee intermediates and their impacts on the troposphere M. Khan et al. 10.1039/C7EM00585G
- Measurement report: Important contributions of oxygenated compounds to emissions and chemistry of volatile organic compounds in urban air C. Wu et al. 10.5194/acp-20-14769-2020
- A General Framework for Global Retrievals of Trace Gases From IASI: Application to Methanol, Formic Acid, and PAN B. Franco et al. 10.1029/2018JD029633
- Homologous series of low molecular weight (C1-C10) monocarboxylic acids, benzoic acid and hydroxyacids in fine-mode (PM2.5) aerosols over the Bay of Bengal: Influence of heterogeneity in air masses and formation pathways S. Boreddy et al. 10.1016/j.atmosenv.2017.08.008
- Characterisation of African biomass burning plumes and impacts on the atmospheric composition over the south-west Indian Ocean B. Verreyken et al. 10.5194/acp-20-14821-2020
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Latest update: 25 May 2022
Short summary
Formic acid (HCOOH) is an abundant atmospheric acid that affects precipitation chemistry and acidity. HCOOH measurements over the USA are 2-3× larger than can be explained by known sources and sinks, revealing a key gap in current understanding. Observations indicate a large biogenic source plus chemical production across a range of precursors. Model simulations cannot capture the HCOOH diurnal amplitude or nocturnal profile, implying a deposition bias and possibly even larger missing source.
Formic acid (HCOOH) is an abundant atmospheric acid that affects precipitation chemistry and...
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