Articles | Volume 15, issue 1
https://doi.org/10.5194/acp-15-55-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-15-55-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
On the composition of ammonia–sulfuric-acid ion clusters during aerosol particle formation
S. Schobesberger
CORRESPONDING AUTHOR
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
A. Franchin
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
F. Bianchi
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
L. Rondo
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt am Main, Germany
J. Duplissy
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Helsinki Institute of Physics, University of Helsinki, 00014 Helsinki, Finland
CERN, 1211 Geneva, Switzerland
A. Kürten
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt am Main, Germany
I. K. Ortega
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Laboratoire de Physique des Lasers, Atomes et Molécules, Université de Lille 1, 59655 Villeneuve d'Ascq, France
A. Metzger
Ionicon Analytik GmbH, 6020 Innsbruck, Austria
R. Schnitzhofer
Institute for Ion and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria
J. Almeida
CERN, 1211 Geneva, Switzerland
A. Amorim
SIM, University of Lisbon and University of Beira Interior, 1749-016 Lisbon, Portugal
J. Dommen
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
E. M. Dunne
School of Earth and Environment, University of Leeds, LS2 9JT Leeds, UK
Finnish Meteorological Institute, Atmospheric Research Centre of Eastern Finland, 70211 Kuopio, Finland
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Helsinki Institute of Physics, University of Helsinki, 00014 Helsinki, Finland
now at: Department of Physics and Atmospheric Science, Dalhousie University, Halifax, B3H 3J5, Canada, and Environment Canada, Downsview, Toronto, M3H 5T4, Canada
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt am Main, Germany
now at: Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
H. Junninen
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
A. Hansel
Ionicon Analytik GmbH, 6020 Innsbruck, Austria
Institute for Ion and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria
V.-M. Kerminen
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
J. Kirkby
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt am Main, Germany
CERN, 1211 Geneva, Switzerland
Faculty of Physics, University of Vienna, 1090 Vienna, Austria
A. Laaksonen
Finnish Meteorological Institute, 00101 Helsinki, Finland
Department of Applied Physics, University of Eastern Finland, 70211 Kuopio, Finland
K. Lehtipalo
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
S. Mathot
CERN, 1211 Geneva, Switzerland
A. Onnela
CERN, 1211 Geneva, Switzerland
T. Petäjä
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
F. Riccobono
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
F. D. Santos
SIM, University of Lisbon and University of Beira Interior, 1749-016 Lisbon, Portugal
M. Sipilä
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Helsinki Institute of Physics, University of Helsinki, 00014 Helsinki, Finland
A. Tomé
SIM, University of Lisbon and University of Beira Interior, 1749-016 Lisbon, Portugal
G. Tsagkogeorgas
Leibniz Institute for Tropospheric Research, 04318 Leipzig, Germany
Y. Viisanen
Finnish Meteorological Institute, 00101 Helsinki, Finland
P. E. Wagner
Faculty of Physics, University of Vienna, 1090 Vienna, Austria
D. Wimmer
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt am Main, Germany
J. Curtius
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, 60438 Frankfurt am Main, Germany
N. M. Donahue
Center for Atmospheric Particle Studies, Carnegie Mellon University, Pittsburgh, PA 15213, USA
U. Baltensperger
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
M. Kulmala
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
D. R. Worsnop
Department of Physics, University of Helsinki, 00014 Helsinki, Finland
Finnish Meteorological Institute, 00101 Helsinki, Finland
Department of Applied Physics, University of Eastern Finland, 70211 Kuopio, Finland
Aerodyne Research, Inc., Billerica, MA 01821, USA
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- Measurement report: Molecular-level investigation of atmospheric cluster ions at the tropical high-altitude research station Chacaltaya (5240 m a.s.l.) in the Bolivian Andes Q. Zha et al. 10.5194/acp-23-4559-2023
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- Aerosol formation by heterogeneous reactions in ammonia-based WFGD systems R. Huang et al. 10.1016/j.jaerosci.2017.08.012
- Effect of ions on sulfuric acid‐water binary particle formation: 2. Experimental data and comparison with QC‐normalized classical nucleation theory J. Duplissy et al. 10.1002/2015JD023539
- Vapor phase nucleation of the short-chain n-alkanes (n-pentane, n-hexane and n-heptane): Experiments and Monte Carlo simulations K. Ogunronbi et al. 10.1063/1.5023567
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- Temperature effects on sulfuric acid aerosol nucleation and growth: initial results from the TANGENT study L. Tiszenkel et al. 10.5194/acp-19-8915-2019
- Observations of particle number size distributions and new particle formation in six Indian locations M. Sebastian et al. 10.5194/acp-22-4491-2022
- Impact of Quantum Chemistry Parameter Choices and Cluster Distribution Model Settings on Modeled Atmospheric Particle Formation Rates V. Besel et al. 10.1021/acs.jpca.0c03984
- Clustering of highly oxidized organic acid with atmospheric NO3− and HSO4− ions and neutral species: Thermochemistry and implications to new particle formation A. Nadykto et al. 10.1016/j.cplett.2018.05.080
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- Volatile organic compounds enhancing sulfuric acid-based ternary homogeneous nucleation: The important role of synergistic effect Y. Zhao et al. 10.1016/j.atmosenv.2020.117609
- Computational Tools for Handling Molecular Clusters: Configurational Sampling, Storage, Analysis, and Machine Learning J. Kubečka et al. 10.1021/acsomega.3c07412
- The importance of ammonia for springtime atmospheric new particle formation and aerosol number abundance over the United States A. Nair et al. 10.1016/j.scitotenv.2022.160756
- Knudsen cell studies of the uptake of gaseous ammonia and amines onto C3–C7 solid dicarboxylic acids M. Fairhurst et al. 10.1039/C7CP05252A
- Improvement of a Global High-Resolution Ammonia Emission Inventory for Combustion and Industrial Sources with New Data from the Residential and Transportation Sectors W. Meng et al. 10.1021/acs.est.6b03694
- Chemical characterization of atmospheric ions at the high altitude research station Jungfraujoch (Switzerland) C. Frege et al. 10.5194/acp-17-2613-2017
- Clustering, methodology, and mechanistic insights into acetate chemical ionization using high-resolution time-of-flight mass spectrometry P. Brophy & D. Farmer 10.5194/amt-9-3969-2016
- Overview: Homogeneous nucleation from the vapor phase—The experimental science B. Wyslouzil & J. Wölk 10.1063/1.4962283
- Wintertime subarctic new particle formation from Kola Peninsula sulfur emissions M. Sipilä et al. 10.5194/acp-21-17559-2021
- Identification of molecular cluster evaporation rates, cluster formation enthalpies and entropies by Monte Carlo method A. Shcherbacheva et al. 10.5194/acp-20-15867-2020
- Bidirectional Interaction of Alanine with Sulfuric Acid in the Presence of Water and the Atmospheric Implication C. Wang et al. 10.1021/acs.jpca.5b11678
- The role of H<sub>2</sub>SO<sub>4</sub>-NH<sub>3</sub> anion clusters in ion-induced aerosol nucleation mechanisms in the boreal forest C. Yan et al. 10.5194/acp-18-13231-2018
- Bisulfate – cluster based atmospheric pressure chemical ionization mass spectrometer for high-sensitivity (< 100 ppqV) detection of atmospheric dimethyl amine: proof-of-concept and first ambient data from boreal forest M. Sipilä et al. 10.5194/amt-8-4001-2015
- Measurement report: Insights into the chemical composition and origin of molecular clusters and potential precursor molecules present in the free troposphere over the southern Indian Ocean: observations from the Maïdo Observatory (2150 m a.s.l., Réunion) R. Salignat et al. 10.5194/acp-24-3785-2024
- H<sub>2</sub>SO<sub>4</sub>–H<sub>2</sub>O–NH<sub>3</sub> ternary ion-mediated nucleation (TIMN): kinetic-based model and comparison with CLOUD measurements F. Yu et al. 10.5194/acp-18-17451-2018
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Short summary
We used an ion mass spectrometer at CERN's CLOUD chamber to investigate the detailed composition of ammonia--sulfuric acid ion clusters (of both polarities) as they initially form and then grow into aerosol particles, at atmospherically relevant conditions. We found that these clusters’ composition is mainly determined by the ratio of the precursor vapors and ranges from ammonia-free clusters to clusters containing > 1 ammonia per sulfuric acid. Acid--base bindings are a key formation mechanism.
We used an ion mass spectrometer at CERN's CLOUD chamber to investigate the detailed composition...
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