Articles | Volume 15, issue 8
Atmos. Chem. Phys., 15, 4145–4159, 2015
https://doi.org/10.5194/acp-15-4145-2015

Special issue: The CERN CLOUD experiment (ACP/AMT inter-journal SI)

Atmos. Chem. Phys., 15, 4145–4159, 2015
https://doi.org/10.5194/acp-15-4145-2015

Research article 22 Apr 2015

Research article | 22 Apr 2015

Elemental composition and clustering behaviour of α-pinene oxidation products for different oxidation conditions

A. P. Praplan et al.

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Our study shows, based on data from three atmospheric pressure interface time-of-flight mass spectrometers measuring in parallel charged and neutral molecules and molecular clusters, how oxidised organic compounds bind to inorganic ions (e.g. bisulfate, nitrate, ammonium). This ionisation is selective for compounds with lower molar mass due to their limited amount and variety of functional groups. We also found that extremely low volatile organic compounds (ELVOCs) can be formed immediately.
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