Articles | Volume 15, issue 8
https://doi.org/10.5194/acp-15-4145-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-15-4145-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
22 Apr 2015
Research article |
| 22 Apr 2015
Elemental composition and clustering behaviour of α-pinene oxidation products for different oxidation conditions
A. P. Praplan
CORRESPONDING AUTHOR
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
S. Schobesberger
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
now at: University of Washington, Department of Atmospheric Sciences, Box 351640, Seattle, WA 98195, USA
F. Bianchi
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
M. P. Rissanen
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
T. Jokinen
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
H. Junninen
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
A. Adamov
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
A. Amorim
Laboratory for Systems, Instrumentation, and Modeling in Science and Technology for Space and the Environment (SIM), University of Lisbon and University of Beira Interior, 1749-016 Lisbon, Portugal
J. Dommen
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
J. Duplissy
Helsinki Institute of Physics, University of Helsinki, Helsinki, Finland
J. Hakala
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
A. Hansel
University of Innsbruck, Institute for Ion Physics and Applied Physics, Technikerstrasse 25, 6020 Innsbruck, Austria
Ionicon Analytik, Eduard Bodem Gasse 3, 6020 Innsbruck, Austria
M. Heinritzi
University of Innsbruck, Institute for Ion Physics and Applied Physics, Technikerstrasse 25, 6020 Innsbruck, Austria
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt am Main, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
J. Kangasluoma
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
J. Kirkby
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt am Main, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
CERN, CH1211, Geneva, Switzerland
M. Krapf
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
A. Kürten
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt am Main, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
K. Lehtipalo
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
F. Riccobono
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
L. Rondo
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt am Main, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
N. Sarnela
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt am Main, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
A. Tomé
Laboratory for Systems, Instrumentation, and Modeling in Science and Technology for Space and the Environment (SIM), University of Lisbon and University of Beira Interior, 1749-016 Lisbon, Portugal
J. Tröstl
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
P. M. Winkler
Faculty of Physics, University of Vienna, Boltzmanngasse 5, 1090 Vienna, Austria
C. Williamson
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt am Main, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
P. Ye
Center for Atmospheric Particle Studies, Carnegie Mellon University, 5000 Frobes Ave, Pittsburgh, PA 15213, USA
J. Curtius
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt am Main, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
U. Baltensperger
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
N. M. Donahue
Center for Atmospheric Particle Studies, Carnegie Mellon University, 5000 Frobes Ave, Pittsburgh, PA 15213, USA
M. Kulmala
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
Helsinki Institute of Physics, University of Helsinki, Helsinki, Finland
D. R. Worsnop
Department of Physics, P.O. Box 64, 00014 University of Helsinki, Helsinki, Finland
Aerodyne Research Incorporated, Billerica, MA 01821, USA
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Cited
15 citations as recorded by crossref.
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Modelling organic aerosol concentrations and properties during ChArMEx summer campaigns of 2012 and 2013 in the western Mediterranean region M. Chrit et al. 10.5194/acp-17-12509-2017
- Influence of temperature on the molecular composition of ions and charged clusters during pure biogenic nucleation C. Frege et al. 10.5194/acp-18-65-2018
- Hygroscopicity of nanoparticles produced from homogeneous nucleation in the CLOUD experiments J. Kim et al. 10.5194/acp-16-293-2016
- How the understanding of atmospheric new particle formation has evolved along with the development of measurement and analysis methods K. Lehtipalo et al. 10.1016/j.jaerosci.2024.106494
- Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber N. Sarnela et al. 10.5194/acp-18-2363-2018
- A method for the direct measurement of surface tension of collected atmospherically relevant aerosol particles using atomic force microscopy A. Hritz et al. 10.5194/acp-16-9761-2016
- Comparison of three aerosol chemical characterization techniques utilizing PTR-ToF-MS: a study on freshly formed and aged biogenic SOA G. Gkatzelis et al. 10.5194/amt-11-1481-2018
- Gas-to-particle partitioning of major biogenic oxidation products: a study on freshly formed and aged biogenic SOA G. Gkatzelis et al. 10.5194/acp-18-12969-2018
- Physicochemical Properties of Pinic, Pinonic, Norpinic, and Norpinonic Acids as Relevant α-Pinene Oxidation Products A. Kołodziejczyk et al. 10.1021/acs.jpcb.9b05211
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- An electrospray chemical ionization source for real-time measurement of atmospheric organic and inorganic vapors Y. Zhao et al. 10.5194/amt-10-3609-2017
- Formation of highly oxygenated organic molecules from aromatic compounds U. Molteni et al. 10.5194/acp-18-1909-2018
- Gas-to-Particle Partitioning of Cyclohexene- and α-Pinene-Derived Highly Oxygenated Dimers Evaluated Using COSMOtherm N. Hyttinen et al. 10.1021/acs.jpca.0c11328
- Observation of new particle formation and measurement of sulfuric acid, ammonia, amines and highly oxidized organic molecules at a rural site in central Germany A. Kürten et al. 10.5194/acp-16-12793-2016
15 citations as recorded by crossref.
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Modelling organic aerosol concentrations and properties during ChArMEx summer campaigns of 2012 and 2013 in the western Mediterranean region M. Chrit et al. 10.5194/acp-17-12509-2017
- Influence of temperature on the molecular composition of ions and charged clusters during pure biogenic nucleation C. Frege et al. 10.5194/acp-18-65-2018
- Hygroscopicity of nanoparticles produced from homogeneous nucleation in the CLOUD experiments J. Kim et al. 10.5194/acp-16-293-2016
- How the understanding of atmospheric new particle formation has evolved along with the development of measurement and analysis methods K. Lehtipalo et al. 10.1016/j.jaerosci.2024.106494
- Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber N. Sarnela et al. 10.5194/acp-18-2363-2018
- A method for the direct measurement of surface tension of collected atmospherically relevant aerosol particles using atomic force microscopy A. Hritz et al. 10.5194/acp-16-9761-2016
- Comparison of three aerosol chemical characterization techniques utilizing PTR-ToF-MS: a study on freshly formed and aged biogenic SOA G. Gkatzelis et al. 10.5194/amt-11-1481-2018
- Gas-to-particle partitioning of major biogenic oxidation products: a study on freshly formed and aged biogenic SOA G. Gkatzelis et al. 10.5194/acp-18-12969-2018
- Physicochemical Properties of Pinic, Pinonic, Norpinic, and Norpinonic Acids as Relevant α-Pinene Oxidation Products A. Kołodziejczyk et al. 10.1021/acs.jpcb.9b05211
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- An electrospray chemical ionization source for real-time measurement of atmospheric organic and inorganic vapors Y. Zhao et al. 10.5194/amt-10-3609-2017
- Formation of highly oxygenated organic molecules from aromatic compounds U. Molteni et al. 10.5194/acp-18-1909-2018
- Gas-to-Particle Partitioning of Cyclohexene- and α-Pinene-Derived Highly Oxygenated Dimers Evaluated Using COSMOtherm N. Hyttinen et al. 10.1021/acs.jpca.0c11328
- Observation of new particle formation and measurement of sulfuric acid, ammonia, amines and highly oxidized organic molecules at a rural site in central Germany A. Kürten et al. 10.5194/acp-16-12793-2016
Saved (final revised paper)
Latest update: 26 Dec 2024
Short summary
Our study shows, based on data from three atmospheric pressure interface time-of-flight mass spectrometers measuring in parallel charged and neutral molecules and molecular clusters, how oxidised organic compounds bind to inorganic ions (e.g. bisulfate, nitrate, ammonium). This ionisation is selective for compounds with lower molar mass due to their limited amount and variety of functional groups. We also found that extremely low volatile organic compounds (ELVOCs) can be formed immediately.
Our study shows, based on data from three atmospheric pressure interface time-of-flight mass...
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