Determination of interfacial parameters of a soluble particle in a nonideal solution from measured deliquescence and efflorescence humidities

Hellmuth, O.; Shchekin, A. K.

doi:https://doi.org/10.5194/acp-15-3851-2015

Articles | Volume 15, issue 7

https://doi.org/10.5194/acp-15-3851-2015

© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

https://doi.org/10.5194/acp-15-3851-2015

© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Articles | Volume 15, issue 7

Research article

|

10 Apr 2015

Research article |

| 10 Apr 2015

Determination of interfacial parameters of a soluble particle in a nonideal solution from measured deliquescence and efflorescence humidities

O. Hellmuth and A. K. Shchekin

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Cumulative views and downloads (calculated since 08 Sep 2014)

Month	HTML	PDF	XML	Total
Sep 2014	54	38	3	95
Oct 2014	8	13	0	21
Nov 2014	19	15	2	36
Dec 2014	21	13	3	37
Jan 2015	22	5	2	29
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May 2015	23	23	6	52
Jun 2015	44	12	2	58
Jul 2015	27	12	1	40
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Nov 2015	24	13	6	43
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To study the growth/shrinking of a hygroscopic nanoparticle during hydration/dehydration in an atmosphere of water vapour we employed a thermodynamic approach. For application to a nanometric sodium chloride particle we extended the original approach and demonstrated how the solution/solute interface energy and the correlation length of a thin solution film can be determined from a combination of experimentally determinable efflorescence and deliquescence humidities with the present calculus.

Determination of interfacial parameters of a soluble particle in a nonideal solution from measured deliquescence and efflorescence humidities

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