Articles | Volume 15, issue 5
https://doi.org/10.5194/acp-15-2775-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-2775-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
A critical evaluation of proxy methods used to estimate the acidity of atmospheric particles
Department of Chemical, Biochemical and Environmental Engineering, University of Maryland, Baltimore County, Baltimore, MD, USA
J. Izumi
Department of Chemical, Biochemical and Environmental Engineering, University of Maryland, Baltimore County, Baltimore, MD, USA
A. P. Sullivan
Department of Atmospheric Science, Colorado State University, Fort Collins, CO, USA
R. J. Weber
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
Foundation for Research and Technology – Hellas, Patras, Greece
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Saved (final revised paper)
Latest update: 01 Apr 2023
Short summary
We show that the ion balance and molar ratio methods are unsuitable for use as aerosol pH proxies. Our recommendation is that 1) thermodynamic equilibrium models constrained by both gas and aerosol inputs run in the forward (open) mode, and 2) the phase partitioning of ammonia provides the best predictions of aerosol pH. Given the significance of acidity for numerous chemical processes in the atmosphere, the implications of this study are important and far reaching.
We show that the ion balance and molar ratio methods are unsuitable for use as aerosol pH...
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