Articles | Volume 15, issue 1
https://doi.org/10.5194/acp-15-223-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-223-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| Highlight paper
| 
12 Jan 2015
Research article | Highlight paper |
| 12 Jan 2015
Seasonal in situ observations of glyoxal and methylglyoxal over the temperate oceans of the Southern Hemisphere
Commonwealth Scientific and Industrial Research Organisation, Oceans and Atmosphere Flagship, Aspendale, Australia
P. W. Selleck
Commonwealth Scientific and Industrial Research Organisation, Oceans and Atmosphere Flagship, Aspendale, Australia
I. E. Galbally
Commonwealth Scientific and Industrial Research Organisation, Oceans and Atmosphere Flagship, Aspendale, Australia
M. D. Keywood
Commonwealth Scientific and Industrial Research Organisation, Oceans and Atmosphere Flagship, Aspendale, Australia
M. J. Harvey
National Institute of Water and Atmospheric Research, Wellington, New Zealand
Belgian Institute for Space Aeronomy, Brussels, Belgium
D. Helmig
Institute of Arctic and Alpine Research, University of Colorado, Boulder, USA
Z. Ristovski
International Laboratory for Air Quality & Health, Queensland University of Technology, Brisbane, Australia
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41 citations as recorded by crossref.
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- Potential controls of isoprene in the surface ocean S. Hackenberg et al. 10.1002/2016GB005531
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- Methanethiol, dimethyl sulfide and acetone over biologically productive waters in the southwest Pacific Ocean S. Lawson et al. 10.5194/acp-20-3061-2020
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- Dimethyl sulfide and other biogenic volatile organic compound emissions from branching coral and reef seawater: potential sources of secondary aerosol over the Great Barrier Reef H. Swan et al. 10.1007/s10874-016-9327-7
- Variability analyses, site characterization, and regional [OH] estimates using trace gas measurements from the NOAA Global Greenhouse Gas Reference Network J. Pollmann et al. 10.12952/journal.elementa.000128
- Substantial Seasonal Contribution of Observed Biogenic Sulfate Particles to Cloud Condensation Nuclei K. Sanchez et al. 10.1038/s41598-018-21590-9
- Multi-model simulation of CO and HCHO in the Southern Hemisphere: comparison with observations and impact of biogenic emissions G. Zeng et al. 10.5194/acp-15-7217-2015
- Field measurements of methylglyoxal using proton transfer reaction time-of-flight mass spectrometry and comparison to the DNPH–HPLC–UV method V. Michoud et al. 10.5194/amt-11-5729-2018
- Observations and modelling of glyoxal in the tropical Atlantic marine boundary layer H. Walker et al. 10.5194/acp-22-5535-2022
- Bias correction of OMI HCHO columns based on FTIR and aircraft measurements and impact on top-down emission estimates J. Müller et al. 10.5194/acp-24-2207-2024
- Overview and preliminary results of the Surface Ocean Aerosol Production (SOAP) campaign C. Law et al. 10.5194/acp-17-13645-2017
- Rapid increase in atmospheric glyoxal and methylglyoxal concentrations in Lhasa, Tibetan Plateau: Potential sources and implications Q. Li et al. 10.1016/j.scitotenv.2022.153782
- UV photochemistry of carboxylic acids at the air‐sea boundary: A relevant source of glyoxal and other oxygenated VOC in the marine atmosphere R. Chiu et al. 10.1002/2016GL071240
- Selected Ion Flow Tube – Mass Spectrometry (SIFT-MS) study of the reactions of H3O+, NO+ and O2+ with a range of oxygenated volatile organic carbons (OVOCs) I. Roberts et al. 10.1016/j.ijms.2022.116892
- Volatility of methylglyoxal cloud SOA formed through OH radical oxidation and droplet evaporation D. Ortiz-Montalvo et al. 10.1016/j.atmosenv.2015.12.013
- Marine volatile organic compounds and their impacts on marine aerosol—A review Z. Yu & Y. Li 10.1016/j.scitotenv.2021.145054
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- Possible Missing Sources of Atmospheric Glyoxal Part I: Phospholipid Oxidation from Marine Algae R. Williams et al. 10.3390/metabo14110639
- Comprehensive aerosol and gas data set from the Sydney Particle Study M. Keywood et al. 10.5194/essd-11-1883-2019
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- Chemistry and Release of Gases from the Surface Ocean L. Carpenter & P. Nightingale 10.1021/cr5007123
- In Situ Monitoring of the Aging of Mineral Particles by Methylglyoxal Using Infrared Spectroscopy. Part I: Unraveling Uptake under Dry Conditions A. Lostier et al. 10.1021/acsearthspacechem.5c00038
- Aircraft measurements of BrO, IO, glyoxal, NO2, H2O, O2–O2 and aerosol extinction profiles in the tropics: comparison with aircraft-/ship-based in situ and lidar measurements R. Volkamer et al. 10.5194/amt-8-2121-2015
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- Profiling of formaldehyde, glyoxal, methylglyoxal, and CO over the Amazon: normalized excess mixing ratios and related emission factors in biomass burning plumes F. Kluge et al. 10.5194/acp-20-12363-2020
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- The MUMBA campaign: measurements of urban, marine and biogenic air C. Paton-Walsh et al. 10.5194/essd-9-349-2017
- Chemical precursors of new particle formation in coastal New Zealand M. Peltola et al. 10.5194/acp-23-3955-2023
- Composition of Clean Marine Air and Biogenic Influences on VOCs during the MUMBA Campaign É. Guérette et al. 10.3390/atmos10070383
- Sink or Swim: Ions and Organics at the Ice–Air Interface A. Hudait et al. 10.1021/jacs.7b05233
40 citations as recorded by crossref.
- Glyoxal tropospheric column retrievals from TROPOMI – multi-satellite intercomparison and ground-based validation C. Lerot et al. 10.5194/amt-14-7775-2021
- Concentrations and Photochemistry of Acetaldehyde, Glyoxal, and Methylglyoxal in the Northwest Atlantic Ocean Y. Zhu & D. Kieber 10.1021/acs.est.9b01631
- Potential controls of isoprene in the surface ocean S. Hackenberg et al. 10.1002/2016GB005531
- Importance of reactive halogens in the tropical marine atmosphere: a regional modelling study using WRF-Chem A. Badia et al. 10.5194/acp-19-3161-2019
- Methanethiol, dimethyl sulfide and acetone over biologically productive waters in the southwest Pacific Ocean S. Lawson et al. 10.5194/acp-20-3061-2020
- Investigation of mercury emissions from burning of Australian eucalypt forest surface fuels using a combustion wind tunnel and field observations D. Howard et al. 10.1016/j.atmosenv.2018.12.015
- Dimethyl sulfide and other biogenic volatile organic compound emissions from branching coral and reef seawater: potential sources of secondary aerosol over the Great Barrier Reef H. Swan et al. 10.1007/s10874-016-9327-7
- Variability analyses, site characterization, and regional [OH] estimates using trace gas measurements from the NOAA Global Greenhouse Gas Reference Network J. Pollmann et al. 10.12952/journal.elementa.000128
- Substantial Seasonal Contribution of Observed Biogenic Sulfate Particles to Cloud Condensation Nuclei K. Sanchez et al. 10.1038/s41598-018-21590-9
- Multi-model simulation of CO and HCHO in the Southern Hemisphere: comparison with observations and impact of biogenic emissions G. Zeng et al. 10.5194/acp-15-7217-2015
- Field measurements of methylglyoxal using proton transfer reaction time-of-flight mass spectrometry and comparison to the DNPH–HPLC–UV method V. Michoud et al. 10.5194/amt-11-5729-2018
- Observations and modelling of glyoxal in the tropical Atlantic marine boundary layer H. Walker et al. 10.5194/acp-22-5535-2022
- Bias correction of OMI HCHO columns based on FTIR and aircraft measurements and impact on top-down emission estimates J. Müller et al. 10.5194/acp-24-2207-2024
- Overview and preliminary results of the Surface Ocean Aerosol Production (SOAP) campaign C. Law et al. 10.5194/acp-17-13645-2017
- Rapid increase in atmospheric glyoxal and methylglyoxal concentrations in Lhasa, Tibetan Plateau: Potential sources and implications Q. Li et al. 10.1016/j.scitotenv.2022.153782
- UV photochemistry of carboxylic acids at the air‐sea boundary: A relevant source of glyoxal and other oxygenated VOC in the marine atmosphere R. Chiu et al. 10.1002/2016GL071240
- Selected Ion Flow Tube – Mass Spectrometry (SIFT-MS) study of the reactions of H3O+, NO+ and O2+ with a range of oxygenated volatile organic carbons (OVOCs) I. Roberts et al. 10.1016/j.ijms.2022.116892
- Volatility of methylglyoxal cloud SOA formed through OH radical oxidation and droplet evaporation D. Ortiz-Montalvo et al. 10.1016/j.atmosenv.2015.12.013
- Marine volatile organic compounds and their impacts on marine aerosol—A review Z. Yu & Y. Li 10.1016/j.scitotenv.2021.145054
- Elucidating the critical oligomeric steps in secondary organic aerosol and brown carbon formation Y. Ji et al. 10.5194/acp-22-7259-2022
- Atmospheric isoprene measurements reveal larger-than-expected Southern Ocean emissions V. Ferracci et al. 10.1038/s41467-024-46744-4
- Contribution of Speciated Monoterpenes to Secondary Aerosol in the Eastern North Atlantic D. Kilgour et al. 10.1021/acsestair.3c00112
- Possible Missing Sources of Atmospheric Glyoxal Part I: Phospholipid Oxidation from Marine Algae R. Williams et al. 10.3390/metabo14110639
- Comprehensive aerosol and gas data set from the Sydney Particle Study M. Keywood et al. 10.5194/essd-11-1883-2019
- Airborne glyoxal measurements in the marine and continental atmosphere: comparison with TROPOMI observations and EMAC simulations F. Kluge et al. 10.5194/acp-23-1369-2023
- Comprehensive observations of carbonyls of Mt. Hua in Central China: Vertical distribution and effects on ozone formation Y. Zhang et al. 10.1016/j.scitotenv.2023.167983
- Global impacts of tropospheric halogens (Cl, Br, I) on oxidants and composition in GEOS-Chem T. Sherwen et al. 10.5194/acp-16-12239-2016
- Aging of mineral dusts and proxies by uptake of methylglyoxal: A Knudsen cell study A. Lostier et al. 10.1016/j.atmosenv.2024.120876
- Chemistry and Release of Gases from the Surface Ocean L. Carpenter & P. Nightingale 10.1021/cr5007123
- In Situ Monitoring of the Aging of Mineral Particles by Methylglyoxal Using Infrared Spectroscopy. Part I: Unraveling Uptake under Dry Conditions A. Lostier et al. 10.1021/acsearthspacechem.5c00038
- Aircraft measurements of BrO, IO, glyoxal, NO2, H2O, O2–O2 and aerosol extinction profiles in the tropics: comparison with aircraft-/ship-based in situ and lidar measurements R. Volkamer et al. 10.5194/amt-8-2121-2015
- Global Model for Depth‐Dependent Carbonyl Photochemical Production Rates in Seawater Y. Zhu & D. Kieber 10.1029/2019GB006431
- Wavelength- and Temperature-Dependent Apparent Quantum Yields for Photochemical Production of Carbonyl Compounds in the North Pacific Ocean Y. Zhu & D. Kieber 10.1021/acs.est.7b05462
- Basin-Scale Observations of Monoterpenes in the Arctic and Atlantic Oceans S. Hackenberg et al. 10.1021/acs.est.7b02240
- Online Speciation of Glyoxal Multiphase Reactions on Deliquesced Ammonium Sulfate Particles N. Brun et al. 10.1021/acsearthspacechem.4c00369
- Profiling of formaldehyde, glyoxal, methylglyoxal, and CO over the Amazon: normalized excess mixing ratios and related emission factors in biomass burning plumes F. Kluge et al. 10.5194/acp-20-12363-2020
- Characterization of the organic matter in submicron urban aerosols using a Thermo-Desorption Proton-Transfer-Reaction Time-of-Flight Mass Spectrometer (TD-PTR-TOF-MS) C. Salvador et al. 10.1016/j.atmosenv.2016.06.029
- The MUMBA campaign: measurements of urban, marine and biogenic air C. Paton-Walsh et al. 10.5194/essd-9-349-2017
- Chemical precursors of new particle formation in coastal New Zealand M. Peltola et al. 10.5194/acp-23-3955-2023
- Composition of Clean Marine Air and Biogenic Influences on VOCs during the MUMBA Campaign É. Guérette et al. 10.3390/atmos10070383
1 citations as recorded by crossref.
Saved (final revised paper)
Latest update: 31 May 2025
Short summary
Glyoxal and methylglyoxal are short-lived organic trace gases and important precursors of secondary organic aerosol. Measurements over oceans are sparse. We present the first in situ glyoxal and methylglyoxal observations over remote temperate oceans, alongside observations of precursor gases. Precursor gases cannot explain observed mixing ratios, highlighting an unknown source. We show a large discrepancy between calculated vertical column densities of glyoxal and those retrieved by satellite.
Glyoxal and methylglyoxal are short-lived organic trace gases and important precursors of...
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