Articles | Volume 15, issue 23
https://doi.org/10.5194/acp-15-13615-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-13615-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
09 Dec 2015
Research article |
| 09 Dec 2015
Viscosity controls humidity dependence of N2O5 uptake to citric acid aerosol
G. Gržinić
Laboratory of Radiochemistry and Environmental Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Department of Chemistry and Biochemistry, University of Bern, 3012 Bern, Switzerland
T. Bartels-Rausch
Laboratory of Radiochemistry and Environmental Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
T. Berkemeier
Multiphase Chemistry Department, Max Planck Institute for Chemistry, 55128 Mainz, Germany
A. Türler
Laboratory of Radiochemistry and Environmental Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Department of Chemistry and Biochemistry, University of Bern, 3012 Bern, Switzerland
Department of Chemistry and Biochemistry, University of Bern, 3012 Bern, Switzerland
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37 citations as recorded by crossref.
- Coalescence-based assessment of aerosol phase state using dimers prepared through a dual-differential mobility analyzer technique N. Rothfuss & M. Petters 10.1080/02786826.2016.1221050
- Influence of Functional Groups on the Viscosity of Organic Aerosol N. Rothfuss & M. Petters 10.1021/acs.est.6b04478
- Viscosity, Glass Formation, and Mixing Times within Secondary Organic Aerosol from Biomass Burning Phenolics K. Kiland et al. 10.1021/acsearthspacechem.3c00039
- Characterization of the temperature and humidity-dependent phase diagram of amorphous nanoscale organic aerosols N. Rothfuss & M. Petters 10.1039/C6CP08593H
- Nitrate radical generation via continuous generation of dinitrogen pentoxide in a laminar flow reactor coupled to an oxidation flow reactor A. Lambe et al. 10.5194/amt-13-2397-2020
- Unexpected electrophiles in the atmosphere – anhydride nucleophile reactions and uptake to biomass burning emissions M. Loebel Roson et al. 10.1039/D3CP01751F
- Efficient bulk mass accommodation and dissociation of N<sub>2</sub>O<sub>5</sub> in neutral aqueous aerosol G. Gržinić et al. 10.5194/acp-17-6493-2017
- Night-time oxidation at the air–water interface: co-surfactant effects in binary mixtures F. Sebastiani et al. 10.1039/D2EA00056C
- Efficient N<sub>2</sub>O<sub>5</sub> uptake and NO<sub>3</sub> oxidation in the outflow of urban Beijing H. Wang et al. 10.5194/acp-18-9705-2018
- Estimating N<sub>2</sub>O<sub>5</sub> uptake coefficients using ambient measurements of NO<sub>3</sub>, N<sub>2</sub>O<sub>5</sub>, ClNO<sub>2</sub> and particle-phase nitrate G. Phillips et al. 10.5194/acp-16-13231-2016
- Effects of Relative Humidity and Particle Phase Water on the Heterogeneous OH Oxidation of 2-Methylglutaric Acid Aqueous Droplets M. Chim et al. 10.1021/acs.jpca.6b11606
- ClNO2 Yields From Aircraft Measurements During the 2015 WINTER Campaign and Critical Evaluation of the Current Parameterization E. McDuffie et al. 10.1029/2018JD029358
- Distribution Characteristics and Source Apportionment of Winter Carbonaceous Aerosols in a Rural Area in Shandong, China C. Zou et al. 10.3390/atmos13111858
- Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures A. Marsh et al. 10.1039/C8CP00760H
- Particle-Phase Photosensitized Radical Production and Aerosol Aging P. Corral Arroyo et al. 10.1021/acs.est.8b00329
- The viscosity of atmospherically relevant organic particles J. Reid et al. 10.1038/s41467-018-03027-z
- Evolution in the Reactivity of Citric Acid toward Heterogeneous Oxidation by Gas-Phase OH Radicals M. Chim et al. 10.1021/acsearthspacechem.8b00118
- Model simulation of NO 3 , N 2 O 5 and ClNO 2 at a rural site in Beijing during CAREBeijing-2006 H. Wang et al. 10.1016/j.atmosres.2017.06.013
- Explosive Secondary Aerosol Formation during Severe Haze in the North China Plain J. Peng et al. 10.1021/acs.est.0c07204
- A new hot-stage microscopy technique for measuring temperature-dependent viscosities of aerosol particles and its application to farnesene secondary organic aerosol K. Kiland et al. 10.5194/amt-15-5545-2022
- Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation D. Ullmann et al. 10.5194/acp-19-1491-2019
- Nighttime oxidation of surfactants at the air–water interface: effects of chain length, head group and saturation F. Sebastiani et al. 10.5194/acp-18-3249-2018
- Impact of aging on the sources, volatility, and viscosity of organic aerosols in Chinese outflows T. Feng et al. 10.5194/acp-23-611-2023
- Evaluating N2O5 heterogeneous hydrolysis parameterizations for CalNex 2010 W. Chang et al. 10.1002/2015JD024737
- The effect of viscosity and diffusion on the HO<sub>2</sub> uptake by sucrose and secondary organic aerosol particles P. Lakey et al. 10.5194/acp-16-13035-2016
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- Organic Nitrate Contribution to New Particle Formation and Growth in Secondary Organic Aerosols from α-Pinene Ozonolysis T. Berkemeier et al. 10.1021/acs.est.6b00961
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- Temperature‐ and Humidity‐Dependent Phase States of Secondary Organic Aerosols S. Petters et al. 10.1029/2018GL080563
- Fast particulate nitrate formation via N<sub>2</sub>O<sub>5</sub> uptake aloft in winter in Beijing H. Wang et al. 10.5194/acp-18-10483-2018
- Modeling Volatility-Based Aerosol Phase State Predictions in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.1c00255
- Diffusion coefficients of organic molecules in sucrose–water solutions and comparison with Stokes–Einstein predictions Y. Chenyakin et al. 10.5194/acp-17-2423-2017
- A dual-droplet approach for measuring the hygroscopicity of aqueous aerosol J. Choczynski et al. 10.5194/amt-14-5001-2021
- Effects of liquid–liquid phase separation and relative humidity on the heterogeneous OH oxidation of inorganic–organic aerosols: insights from methylglutaric acid and ammonium sulfate particles H. Lam et al. 10.5194/acp-21-2053-2021
- Carbon Dioxide Diffusivity in Single, Levitated Organic Aerosol Particles J. Dou et al. 10.1021/acs.jpclett.9b01389
- Chemical composition and hydrolysis of organic nitrate aerosol formed from hydroxyl and nitrate radical oxidation of <i>α</i>-pinene and <i>β</i>-pinene M. Takeuchi & N. Ng 10.5194/acp-19-12749-2019
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
2 citations as recorded by crossref.
Saved (final revised paper)
Latest update: 23 Nov 2024
Short summary
The heterogeneous loss of dinitrogen pentoxide (N2O5) to citric acid aerosol, a proxy for highly oxygenated secondary organic aerosol, is shown to be substantially lower than to other aqueous organic aerosol proxies investigated previously. This is attributed to the widely changing viscosity within the atmospherically relevant humidity range. It may explain some of the unexpectedly low loss rates of N2O5 to aerosol particles derived from field studies.
The heterogeneous loss of dinitrogen pentoxide (N2O5) to citric acid aerosol, a proxy for highly...
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