Articles | Volume 15, issue 23
https://doi.org/10.5194/acp-15-13599-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-13599-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Viscous organic aerosol particles in the upper troposphere: diffusivity-controlled water uptake and ice nucleation?
D. M. Lienhard
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
present address: Department of Chemistry, University of Cambridge, Cambridge, UK
A. J. Huisman
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
present address: Chemistry Department, Union College, Schenectady, NY, USA
U. K. Krieger
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Y. Rudich
Department of Environmental Sciences, Weizmann Institute, Rehovot 76100, Israel
C. Marcolli
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Marcolli Chemistry and Physics Consulting GmbH, 8092 Zürich, Switzerland
B. P. Luo
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Physikalisch-Meteorologisches Observatorium Davos and World Radiation Center PMOD/WRC, 7260 Davos, Switzerland
D. L. Bones
School of Chemistry, University of Bristol, BS8 1TS Bristol, UK
present address: School of Chemistry, University of Leeds, Leeds, UK
J. P. Reid
School of Chemistry, University of Bristol, BS8 1TS Bristol, UK
A. T. Lambe
Chemistry Department, Boston College, Chestnut Hill, MA 02467, USA
Aerodyne Research Inc., Billerica, MA 01821, USA
M. R. Canagaratna
Aerodyne Research Inc., Billerica, MA 01821, USA
P. Davidovits
Chemistry Department, Boston College, Chestnut Hill, MA 02467, USA
T. B. Onasch
Chemistry Department, Boston College, Chestnut Hill, MA 02467, USA
Aerodyne Research Inc., Billerica, MA 01821, USA
D. R. Worsnop
Aerodyne Research Inc., Billerica, MA 01821, USA
S. S. Steimer
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Laboratory of Radiochemistry and Environmental Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
Faculty of Chemistry, Bielefeld University, 33615 Bielefeld, Germany
T. Peter
Institute for Atmospheric and Climate Science, ETH Zürich, 8092 Zürich, Switzerland
Viewed
Total article views: 5,200 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 09 Sep 2015)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
2,539 | 2,340 | 321 | 5,200 | 118 | 133 |
- HTML: 2,539
- PDF: 2,340
- XML: 321
- Total: 5,200
- BibTeX: 118
- EndNote: 133
Total article views: 4,281 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 09 Dec 2015)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
2,167 | 1,852 | 262 | 4,281 | 86 | 102 |
- HTML: 2,167
- PDF: 1,852
- XML: 262
- Total: 4,281
- BibTeX: 86
- EndNote: 102
Total article views: 919 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 09 Sep 2015)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
372 | 488 | 59 | 919 | 32 | 31 |
- HTML: 372
- PDF: 488
- XML: 59
- Total: 919
- BibTeX: 32
- EndNote: 31
Cited
93 citations as recorded by crossref.
- Modelling the effect of condensed-phase diffusion on the homogeneous nucleation of ice in ultra-viscous particles K. Fowler et al. 10.5194/acp-20-683-2020
- A predictive group-contribution model for the viscosity of aqueous organic aerosol N. Gervasi et al. 10.5194/acp-20-2987-2020
- Representation of Multiphase OH Oxidation of Amorphous Organic Aerosol for Tropospheric Conditions J. Li & D. Knopf 10.1021/acs.est.0c07668
- Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model R. Schmedding et al. 10.5194/acp-20-8201-2020
- The rate of equilibration of viscous aerosol particles S. O'Meara et al. 10.5194/acp-16-5299-2016
- Wildfire smoke triggers cirrus formation: lidar observations over the eastern Mediterranean R. Mamouri et al. 10.5194/acp-23-14097-2023
- Immersion ice nucleation of atmospherically relevant lipid particles L. Mehndiratta et al. 10.1039/D4EA00066H
- The viscosity of atmospherically relevant organic particles J. Reid et al. 10.1038/s41467-018-03027-z
- Equilibration times in viscous and viscoelastic aerosol particles T. Preston & A. Zuend 10.1039/D2EA00065B
- Comparison of Approaches for Measuring and Predicting the Viscosity of Ternary Component Aerosol Particles G. Rovelli et al. 10.1021/acs.analchem.8b05353
- Heterogeneous ice nucleation of α‐pinene SOA particles before and after ice cloud processing R. Wagner et al. 10.1002/2016JD026401
- Glass Transition Temperatures of Organic Mixtures from Isoprene Epoxydiol-Derived Secondary Organic Aerosol B. Chen et al. 10.1021/acs.jpca.2c08936
- Influence of particle viscosity on mass transfer and heterogeneous ozonolysis kinetics in aqueous–sucrose–maleic acid aerosol F. Marshall et al. 10.1039/C8CP01666F
- Influence of humidity and iron(iii) on photodegradation of atmospheric secondary organic aerosol particles P. Arroyo et al. 10.1039/C8CP03981J
- Phase state of organic aerosols may limit temperature-driven thermodynamic repartitioning following outdoor-to-indoor transport B. Cummings et al. 10.1039/D2EM00093H
- Ice cloud formation potential by free tropospheric particles from long‐range transport over the Northern Atlantic Ocean S. China et al. 10.1002/2016JD025817
- Water diffusion measurements of single charged aerosols using H2O/D2O isotope exchange and Raman spectroscopy in an electrodynamic balance K. Nadler et al. 10.1039/C8CP07052K
- Ozone uptake on glassy, semi-solid and liquid organic matter and the role of reactive oxygen intermediates in atmospheric aerosol chemistry T. Berkemeier et al. 10.1039/C6CP00634E
- Measurements and Predictions of Binary Component Aerosol Particle Viscosity Y. Song et al. 10.1021/acs.jpca.6b07835
- Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ Y. Li et al. 10.1021/acsearthspacechem.1c00094
- The Role of Organic Aerosol in Atmospheric Ice Nucleation: A Review D. Knopf et al. 10.1021/acsearthspacechem.7b00120
- Photolytic radical persistence due to anoxia in viscous aerosol particles P. Alpert et al. 10.1038/s41467-021-21913-x
- Overview of Ice Nucleating Particles Z. Kanji et al. 10.1175/AMSMONOGRAPHS-D-16-0006.1
- A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application T. Bannan et al. 10.5194/amt-12-1429-2019
- Heterogeneous Ice Nucleation in the Tropical Tropopause Layer E. Jensen et al. 10.1029/2018JD028949
- Time evolution of steep diffusion fronts in highly viscous aerosol particles measured with Mie resonance spectroscopy S. Bastelberger et al. 10.1063/1.5052216
- Reactive Uptake of Isoprene Epoxydiols Increases the Viscosity of the Core of Phase-Separated Aerosol Particles N. Olson et al. 10.1021/acsearthspacechem.9b00138
- Perspective: Aerosol microphysics: From molecules to the chemical physics of aerosols B. Bzdek & J. Reid 10.1063/1.5002641
- Heterogeneous oxidation of amorphous organic aerosol surrogates by O<sub>3</sub>, NO<sub>3</sub>, and OH at typical tropospheric temperatures J. Li et al. 10.5194/acp-20-6055-2020
- Kinetic Limitation to Inorganic Ion Diffusivity and to Coalescence of Inorganic Inclusions in Viscous Liquid–Liquid Phase-Separated Particles M. Fard et al. 10.1021/acs.jpca.7b05242
- Carbon Dioxide Diffusivity in Single, Levitated Organic Aerosol Particles J. Dou et al. 10.1021/acs.jpclett.9b01389
- Radical chemistry in oxidation flow reactors for atmospheric chemistry research Z. Peng & J. Jimenez 10.1039/C9CS00766K
- Comparison of saturation vapor pressures of <i>α</i>-pinene + O<sub>3</sub> oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al. 10.5194/acp-22-1195-2022
- Molecular-scale description of interfacial mass transfer in phase-separated aqueous secondary organic aerosol M. Lbadaoui-Darvas et al. 10.5194/acp-21-17687-2021
- Understanding interactions of organic nitrates with the surface and bulk of organic films: implications for particle growth in the atmosphere A. Vander Wall et al. 10.1039/C8EM00348C
- Accurate representations of the physicochemical properties of atmospheric aerosols: when are laboratory measurements of value? A. Marsh et al. 10.1039/C7FD00008A
- Water Uptake and Loss in Viscous Aerosol Particles with Concentration-Dependent Diffusivities B. Wallace & T. Preston 10.1021/acs.jpca.9b00907
- Multiphase reactivity of polycyclic aromatic hydrocarbons is driven by phase separation and diffusion limitations S. Zhou et al. 10.1073/pnas.1902517116
- Initial pH Governs Secondary Organic Aerosol Phase State and Morphology after Uptake of Isoprene Epoxydiols (IEPOX) Z. Lei et al. 10.1021/acs.est.2c01579
- Models of Isotopic Water Diffusion in Spherical Aerosol Particles A. Moridnejad & T. Preston 10.1021/acs.jpca.6b11241
- The Reactivity of Toluene-Derived Secondary Organic Material with Ammonia and the Influence of Water Vapor Y. Wang et al. 10.1021/acs.jpca.8b06685
- Optical deformation of single aerosol particles A. Rafferty et al. 10.1073/pnas.1907687116
- The effect of hydroxyl functional groups and molar mass on the viscosity of non-crystalline organic and organic–water particles J. Grayson et al. 10.5194/acp-17-8509-2017
- Visualizing reaction and diffusion in xanthan gum aerosol particles exposed to ozone P. Alpert et al. 10.1039/C9CP03731D
- The Role of Cloud Processing for the Ice Nucleating Ability of Organic Aerosol and Coal Fly Ash Particles K. Kilchhofer et al. 10.1029/2020JD033338
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- Heterogeneous ice nucleation ability of aerosol particles generated from Arctic sea surface microlayer and surface seawater samples at cirrus temperatures R. Wagner et al. 10.5194/acp-21-13903-2021
- Ice nucleation ability of ammonium sulfate aerosol particles internally mixed with secondary organics B. Bertozzi et al. 10.5194/acp-21-10779-2021
- Kinetic modeling studies of SOA formation from <i>α</i>-pinene ozonolysis K. Gatzsche et al. 10.5194/acp-17-13187-2017
- The wavelength-dependent optical properties of weakly absorbing aqueous aerosol particles A. Bain & T. Preston 10.1039/D0CC02737E
- Global distribution of particle phase state in atmospheric secondary organic aerosols M. Shiraiwa et al. 10.1038/ncomms15002
- Resolving the mechanisms of hygroscopic growth and cloud condensation nuclei activity for organic particulate matter P. Liu et al. 10.1038/s41467-018-06622-2
- Particle phase-state variability in the North Atlantic free troposphere during summertime is determined by atmospheric transport patterns and sources Z. Cheng et al. 10.5194/acp-22-9033-2022
- Diffusion coefficients of organic molecules in sucrose–water solutions and comparison with Stokes–Einstein predictions Y. Chenyakin et al. 10.5194/acp-17-2423-2017
- Inverse modelling of Köhler theory – Part 1: A response surface analysis of CCN spectra with respect to surface-active organic species S. Lowe et al. 10.5194/acp-16-10941-2016
- Diffusion of Organic Molecules as a Function of Temperature in a Sucrose Matrix (a Proxy for Secondary Organic Aerosol) K. Kiland et al. 10.1021/acs.jpclett.9b02182
- Influence of Functional Groups on the Viscosity of Organic Aerosol N. Rothfuss & M. Petters 10.1021/acs.est.6b04478
- The frequency-dependent response of single aerosol particles to vapour phase oscillations and its application in measuring diffusion coefficients T. Preston et al. 10.1039/C6CP07711K
- Condensed-phase biogenic–anthropogenic interactions with implications for cold cloud formation J. Charnawskas et al. 10.1039/C7FD00010C
- Multicomponent diffusion in atmospheric aerosol particles B. Wallace et al. 10.1039/D0EA00008F
- Shortwave radiative impact of liquid–liquid phase separation in brown carbon aerosols M. Fard et al. 10.5194/acp-18-13511-2018
- Exploring Volatility Properties of Discrete Secondary Organic Aerosol Constituents of α-Pinene and Polycyclic Aromatic Hydrocarbons Z. Babar et al. 10.1021/acsearthspacechem.0c00210
- Estimating viscosity of individual substrate-deposited particles from measurements of their height-to-width ratios F. Rivera-Adorno et al. 10.1080/02786826.2023.2270503
- Experimental Determination of the Relationship Between Organic Aerosol Viscosity and Ice Nucleation at Upper Free Tropospheric Conditions S. Kasparoglu et al. 10.1029/2021JD036296
- Highly Viscous States Affect the Browning of Atmospheric Organic Particulate Matter P. Liu et al. 10.1021/acscentsci.7b00452
- Maxwell–Stefan diffusion: a framework for predicting condensed phase diffusion and phase separation in atmospheric aerosol K. Fowler et al. 10.5194/acp-18-1629-2018
- Physical and Chemical Properties of 3-Methyl-1,2,3-butanetricarboxylic Acid (MBTCA) Aerosol E. Kostenidou et al. 10.1021/acs.est.7b04348
- Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition W. DeRieux et al. 10.5194/acp-18-6331-2018
- Tracking Water Sorption in Glassy Aerosol Particles using Morphology-Dependent Resonances A. Moridnejad et al. 10.1021/acs.jpca.7b06774
- Aerosol Composition, Mixing State, and Phase State of Free Tropospheric Particles and Their Role in Ice Cloud Formation N. Lata et al. 10.1021/acsearthspacechem.1c00315
- The effect of viscosity and diffusion on the HO<sub>2</sub> uptake by sucrose and secondary organic aerosol particles P. Lakey et al. 10.5194/acp-16-13035-2016
- Ice nucleation on surrogates of boreal forest SOA particles: effect of water content and oxidative age A. Piedehierro et al. 10.5194/acp-21-11069-2021
- Bulk phase water diffusion is significantly inhibited by inhomogeneity of single non-crystal particle at low relative humidity C. Cai et al. 10.1016/j.jnoncrysol.2019.119595
- <i>α</i>-Pinene secondary organic aerosol at low temperature: chemical composition and implications for particle viscosity W. Huang et al. 10.5194/acp-18-2883-2018
- Temperature‐ and Humidity‐Dependent Phase States of Secondary Organic Aerosols S. Petters et al. 10.1029/2018GL080563
- Diffusivity measurements of volatile organics in levitated viscous aerosol particles S. Bastelberger et al. 10.5194/acp-17-8453-2017
- Transient cavity dynamics and divergence from the Stokes–Einstein equation in organic aerosol Y. Song et al. 10.1039/C9SC06228A
- Discontinuities in hygroscopic growth below and above water saturation for laboratory surrogates of oligomers in organic atmospheric aerosols N. Hodas et al. 10.5194/acp-16-12767-2016
- Condensation Kinetics of Water on Amorphous Aerosol Particles N. Rothfuss et al. 10.1021/acs.jpclett.8b01365
- Heterogeneous ice nucleation of viscous secondary organic aerosol produced from ozonolysis of <i>α</i>-pinene K. Ignatius et al. 10.5194/acp-16-6495-2016
- Ice nucleation catalyzed by the photosynthesis enzyme RuBisCO and other abundant biomolecules A. Alsante et al. 10.1038/s43247-023-00707-7
- Kinetically Determined Hygroscopicity and Efflorescence of Sucrose–Ammonium Sulfate Aerosol Droplets under Lower Relative Humidity L. Wang et al. 10.1021/acs.jpcb.7b05551
- Effect of the Addition of Diblock Copolymer Nanoparticles on the Evaporation Kinetics and Final Particle Morphology for Drying Aqueous Aerosol Droplets B. Miles et al. 10.1021/acs.langmuir.3c02930
- Measurement report: Water diffusion in single suspended phase-separated aerosols Y. Tong et al. 10.5194/acp-24-2937-2024
- Unified Description of Diffusion Coefficients from Small to Large Molecules in Organic–Water Mixtures E. Evoy et al. 10.1021/acs.jpca.9b11271
- The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy Y. Zhang et al. 10.1021/acs.est.9b03317
- Observation of viscosity transition in <i>α</i>-pinene secondary organic aerosol E. Järvinen et al. 10.5194/acp-16-4423-2016
- Toward closure between predicted and observed particle viscosity over a wide range of temperatures and relative humidity S. Kasparoglu et al. 10.5194/acp-21-1127-2021
- Effect of waiting time on the water transport kinetics of magnesium sulfate aerosol at gel-forming relative humidity using optical tweezers P. Chang et al. 10.1016/j.saa.2019.117727
- Characterising the evaporation kinetics of water and semi-volatile organic compounds from viscous multicomponent organic aerosol particles S. Ingram et al. 10.1039/C7CP05172G
- A rapid scan vacuum FTIR method for determining diffusion coefficients in viscous and glassy aerosol particles Y. Zhang et al. 10.1039/C7CP04473A
- Surface Partitioning in Organic–Inorganic Mixtures Contributes to the Size-Dependence of the Phase-State of Atmospheric Nanoparticles J. Werner et al. 10.1021/acs.est.6b00789
- Direct imaging of changes in aerosol particle viscosity upon hydration and chemical aging N. Hosny et al. 10.1039/C5SC02959G
88 citations as recorded by crossref.
- Modelling the effect of condensed-phase diffusion on the homogeneous nucleation of ice in ultra-viscous particles K. Fowler et al. 10.5194/acp-20-683-2020
- A predictive group-contribution model for the viscosity of aqueous organic aerosol N. Gervasi et al. 10.5194/acp-20-2987-2020
- Representation of Multiphase OH Oxidation of Amorphous Organic Aerosol for Tropospheric Conditions J. Li & D. Knopf 10.1021/acs.est.0c07668
- Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model R. Schmedding et al. 10.5194/acp-20-8201-2020
- The rate of equilibration of viscous aerosol particles S. O'Meara et al. 10.5194/acp-16-5299-2016
- Wildfire smoke triggers cirrus formation: lidar observations over the eastern Mediterranean R. Mamouri et al. 10.5194/acp-23-14097-2023
- Immersion ice nucleation of atmospherically relevant lipid particles L. Mehndiratta et al. 10.1039/D4EA00066H
- The viscosity of atmospherically relevant organic particles J. Reid et al. 10.1038/s41467-018-03027-z
- Equilibration times in viscous and viscoelastic aerosol particles T. Preston & A. Zuend 10.1039/D2EA00065B
- Comparison of Approaches for Measuring and Predicting the Viscosity of Ternary Component Aerosol Particles G. Rovelli et al. 10.1021/acs.analchem.8b05353
- Heterogeneous ice nucleation of α‐pinene SOA particles before and after ice cloud processing R. Wagner et al. 10.1002/2016JD026401
- Glass Transition Temperatures of Organic Mixtures from Isoprene Epoxydiol-Derived Secondary Organic Aerosol B. Chen et al. 10.1021/acs.jpca.2c08936
- Influence of particle viscosity on mass transfer and heterogeneous ozonolysis kinetics in aqueous–sucrose–maleic acid aerosol F. Marshall et al. 10.1039/C8CP01666F
- Influence of humidity and iron(iii) on photodegradation of atmospheric secondary organic aerosol particles P. Arroyo et al. 10.1039/C8CP03981J
- Phase state of organic aerosols may limit temperature-driven thermodynamic repartitioning following outdoor-to-indoor transport B. Cummings et al. 10.1039/D2EM00093H
- Ice cloud formation potential by free tropospheric particles from long‐range transport over the Northern Atlantic Ocean S. China et al. 10.1002/2016JD025817
- Water diffusion measurements of single charged aerosols using H2O/D2O isotope exchange and Raman spectroscopy in an electrodynamic balance K. Nadler et al. 10.1039/C8CP07052K
- Ozone uptake on glassy, semi-solid and liquid organic matter and the role of reactive oxygen intermediates in atmospheric aerosol chemistry T. Berkemeier et al. 10.1039/C6CP00634E
- Measurements and Predictions of Binary Component Aerosol Particle Viscosity Y. Song et al. 10.1021/acs.jpca.6b07835
- Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ Y. Li et al. 10.1021/acsearthspacechem.1c00094
- The Role of Organic Aerosol in Atmospheric Ice Nucleation: A Review D. Knopf et al. 10.1021/acsearthspacechem.7b00120
- Photolytic radical persistence due to anoxia in viscous aerosol particles P. Alpert et al. 10.1038/s41467-021-21913-x
- Overview of Ice Nucleating Particles Z. Kanji et al. 10.1175/AMSMONOGRAPHS-D-16-0006.1
- A method for extracting calibrated volatility information from the FIGAERO-HR-ToF-CIMS and its experimental application T. Bannan et al. 10.5194/amt-12-1429-2019
- Heterogeneous Ice Nucleation in the Tropical Tropopause Layer E. Jensen et al. 10.1029/2018JD028949
- Time evolution of steep diffusion fronts in highly viscous aerosol particles measured with Mie resonance spectroscopy S. Bastelberger et al. 10.1063/1.5052216
- Reactive Uptake of Isoprene Epoxydiols Increases the Viscosity of the Core of Phase-Separated Aerosol Particles N. Olson et al. 10.1021/acsearthspacechem.9b00138
- Perspective: Aerosol microphysics: From molecules to the chemical physics of aerosols B. Bzdek & J. Reid 10.1063/1.5002641
- Heterogeneous oxidation of amorphous organic aerosol surrogates by O<sub>3</sub>, NO<sub>3</sub>, and OH at typical tropospheric temperatures J. Li et al. 10.5194/acp-20-6055-2020
- Kinetic Limitation to Inorganic Ion Diffusivity and to Coalescence of Inorganic Inclusions in Viscous Liquid–Liquid Phase-Separated Particles M. Fard et al. 10.1021/acs.jpca.7b05242
- Carbon Dioxide Diffusivity in Single, Levitated Organic Aerosol Particles J. Dou et al. 10.1021/acs.jpclett.9b01389
- Radical chemistry in oxidation flow reactors for atmospheric chemistry research Z. Peng & J. Jimenez 10.1039/C9CS00766K
- Comparison of saturation vapor pressures of <i>α</i>-pinene + O<sub>3</sub> oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al. 10.5194/acp-22-1195-2022
- Molecular-scale description of interfacial mass transfer in phase-separated aqueous secondary organic aerosol M. Lbadaoui-Darvas et al. 10.5194/acp-21-17687-2021
- Understanding interactions of organic nitrates with the surface and bulk of organic films: implications for particle growth in the atmosphere A. Vander Wall et al. 10.1039/C8EM00348C
- Accurate representations of the physicochemical properties of atmospheric aerosols: when are laboratory measurements of value? A. Marsh et al. 10.1039/C7FD00008A
- Water Uptake and Loss in Viscous Aerosol Particles with Concentration-Dependent Diffusivities B. Wallace & T. Preston 10.1021/acs.jpca.9b00907
- Multiphase reactivity of polycyclic aromatic hydrocarbons is driven by phase separation and diffusion limitations S. Zhou et al. 10.1073/pnas.1902517116
- Initial pH Governs Secondary Organic Aerosol Phase State and Morphology after Uptake of Isoprene Epoxydiols (IEPOX) Z. Lei et al. 10.1021/acs.est.2c01579
- Models of Isotopic Water Diffusion in Spherical Aerosol Particles A. Moridnejad & T. Preston 10.1021/acs.jpca.6b11241
- The Reactivity of Toluene-Derived Secondary Organic Material with Ammonia and the Influence of Water Vapor Y. Wang et al. 10.1021/acs.jpca.8b06685
- Optical deformation of single aerosol particles A. Rafferty et al. 10.1073/pnas.1907687116
- The effect of hydroxyl functional groups and molar mass on the viscosity of non-crystalline organic and organic–water particles J. Grayson et al. 10.5194/acp-17-8509-2017
- Visualizing reaction and diffusion in xanthan gum aerosol particles exposed to ozone P. Alpert et al. 10.1039/C9CP03731D
- The Role of Cloud Processing for the Ice Nucleating Ability of Organic Aerosol and Coal Fly Ash Particles K. Kilchhofer et al. 10.1029/2020JD033338
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- Heterogeneous ice nucleation ability of aerosol particles generated from Arctic sea surface microlayer and surface seawater samples at cirrus temperatures R. Wagner et al. 10.5194/acp-21-13903-2021
- Ice nucleation ability of ammonium sulfate aerosol particles internally mixed with secondary organics B. Bertozzi et al. 10.5194/acp-21-10779-2021
- Kinetic modeling studies of SOA formation from <i>α</i>-pinene ozonolysis K. Gatzsche et al. 10.5194/acp-17-13187-2017
- The wavelength-dependent optical properties of weakly absorbing aqueous aerosol particles A. Bain & T. Preston 10.1039/D0CC02737E
- Global distribution of particle phase state in atmospheric secondary organic aerosols M. Shiraiwa et al. 10.1038/ncomms15002
- Resolving the mechanisms of hygroscopic growth and cloud condensation nuclei activity for organic particulate matter P. Liu et al. 10.1038/s41467-018-06622-2
- Particle phase-state variability in the North Atlantic free troposphere during summertime is determined by atmospheric transport patterns and sources Z. Cheng et al. 10.5194/acp-22-9033-2022
- Diffusion coefficients of organic molecules in sucrose–water solutions and comparison with Stokes–Einstein predictions Y. Chenyakin et al. 10.5194/acp-17-2423-2017
- Inverse modelling of Köhler theory – Part 1: A response surface analysis of CCN spectra with respect to surface-active organic species S. Lowe et al. 10.5194/acp-16-10941-2016
- Diffusion of Organic Molecules as a Function of Temperature in a Sucrose Matrix (a Proxy for Secondary Organic Aerosol) K. Kiland et al. 10.1021/acs.jpclett.9b02182
- Influence of Functional Groups on the Viscosity of Organic Aerosol N. Rothfuss & M. Petters 10.1021/acs.est.6b04478
- The frequency-dependent response of single aerosol particles to vapour phase oscillations and its application in measuring diffusion coefficients T. Preston et al. 10.1039/C6CP07711K
- Condensed-phase biogenic–anthropogenic interactions with implications for cold cloud formation J. Charnawskas et al. 10.1039/C7FD00010C
- Multicomponent diffusion in atmospheric aerosol particles B. Wallace et al. 10.1039/D0EA00008F
- Shortwave radiative impact of liquid–liquid phase separation in brown carbon aerosols M. Fard et al. 10.5194/acp-18-13511-2018
- Exploring Volatility Properties of Discrete Secondary Organic Aerosol Constituents of α-Pinene and Polycyclic Aromatic Hydrocarbons Z. Babar et al. 10.1021/acsearthspacechem.0c00210
- Estimating viscosity of individual substrate-deposited particles from measurements of their height-to-width ratios F. Rivera-Adorno et al. 10.1080/02786826.2023.2270503
- Experimental Determination of the Relationship Between Organic Aerosol Viscosity and Ice Nucleation at Upper Free Tropospheric Conditions S. Kasparoglu et al. 10.1029/2021JD036296
- Highly Viscous States Affect the Browning of Atmospheric Organic Particulate Matter P. Liu et al. 10.1021/acscentsci.7b00452
- Maxwell–Stefan diffusion: a framework for predicting condensed phase diffusion and phase separation in atmospheric aerosol K. Fowler et al. 10.5194/acp-18-1629-2018
- Physical and Chemical Properties of 3-Methyl-1,2,3-butanetricarboxylic Acid (MBTCA) Aerosol E. Kostenidou et al. 10.1021/acs.est.7b04348
- Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition W. DeRieux et al. 10.5194/acp-18-6331-2018
- Tracking Water Sorption in Glassy Aerosol Particles using Morphology-Dependent Resonances A. Moridnejad et al. 10.1021/acs.jpca.7b06774
- Aerosol Composition, Mixing State, and Phase State of Free Tropospheric Particles and Their Role in Ice Cloud Formation N. Lata et al. 10.1021/acsearthspacechem.1c00315
- The effect of viscosity and diffusion on the HO<sub>2</sub> uptake by sucrose and secondary organic aerosol particles P. Lakey et al. 10.5194/acp-16-13035-2016
- Ice nucleation on surrogates of boreal forest SOA particles: effect of water content and oxidative age A. Piedehierro et al. 10.5194/acp-21-11069-2021
- Bulk phase water diffusion is significantly inhibited by inhomogeneity of single non-crystal particle at low relative humidity C. Cai et al. 10.1016/j.jnoncrysol.2019.119595
- <i>α</i>-Pinene secondary organic aerosol at low temperature: chemical composition and implications for particle viscosity W. Huang et al. 10.5194/acp-18-2883-2018
- Temperature‐ and Humidity‐Dependent Phase States of Secondary Organic Aerosols S. Petters et al. 10.1029/2018GL080563
- Diffusivity measurements of volatile organics in levitated viscous aerosol particles S. Bastelberger et al. 10.5194/acp-17-8453-2017
- Transient cavity dynamics and divergence from the Stokes–Einstein equation in organic aerosol Y. Song et al. 10.1039/C9SC06228A
- Discontinuities in hygroscopic growth below and above water saturation for laboratory surrogates of oligomers in organic atmospheric aerosols N. Hodas et al. 10.5194/acp-16-12767-2016
- Condensation Kinetics of Water on Amorphous Aerosol Particles N. Rothfuss et al. 10.1021/acs.jpclett.8b01365
- Heterogeneous ice nucleation of viscous secondary organic aerosol produced from ozonolysis of <i>α</i>-pinene K. Ignatius et al. 10.5194/acp-16-6495-2016
- Ice nucleation catalyzed by the photosynthesis enzyme RuBisCO and other abundant biomolecules A. Alsante et al. 10.1038/s43247-023-00707-7
- Kinetically Determined Hygroscopicity and Efflorescence of Sucrose–Ammonium Sulfate Aerosol Droplets under Lower Relative Humidity L. Wang et al. 10.1021/acs.jpcb.7b05551
- Effect of the Addition of Diblock Copolymer Nanoparticles on the Evaporation Kinetics and Final Particle Morphology for Drying Aqueous Aerosol Droplets B. Miles et al. 10.1021/acs.langmuir.3c02930
- Measurement report: Water diffusion in single suspended phase-separated aerosols Y. Tong et al. 10.5194/acp-24-2937-2024
- Unified Description of Diffusion Coefficients from Small to Large Molecules in Organic–Water Mixtures E. Evoy et al. 10.1021/acs.jpca.9b11271
- The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy Y. Zhang et al. 10.1021/acs.est.9b03317
- Observation of viscosity transition in <i>α</i>-pinene secondary organic aerosol E. Järvinen et al. 10.5194/acp-16-4423-2016
- Toward closure between predicted and observed particle viscosity over a wide range of temperatures and relative humidity S. Kasparoglu et al. 10.5194/acp-21-1127-2021
5 citations as recorded by crossref.
- Effect of waiting time on the water transport kinetics of magnesium sulfate aerosol at gel-forming relative humidity using optical tweezers P. Chang et al. 10.1016/j.saa.2019.117727
- Characterising the evaporation kinetics of water and semi-volatile organic compounds from viscous multicomponent organic aerosol particles S. Ingram et al. 10.1039/C7CP05172G
- A rapid scan vacuum FTIR method for determining diffusion coefficients in viscous and glassy aerosol particles Y. Zhang et al. 10.1039/C7CP04473A
- Surface Partitioning in Organic–Inorganic Mixtures Contributes to the Size-Dependence of the Phase-State of Atmospheric Nanoparticles J. Werner et al. 10.1021/acs.est.6b00789
- Direct imaging of changes in aerosol particle viscosity upon hydration and chemical aging N. Hosny et al. 10.1039/C5SC02959G
Saved (final revised paper)
Latest update: 23 Nov 2024
Short summary
New data of water diffusivity in secondary organic aerosol (SOA) material and organic/inorganic model mixtures is presented over an extensive temperature range. Our data suggest that water diffusion in SOA is sufficiently fast so that it is unlikely to have significant consequences on the direct climatic effect under tropospheric conditions. Glass formation in SOA is unlikely to restrict homogeneous ice nucleation.
New data of water diffusivity in secondary organic aerosol (SOA) material and organic/inorganic...
Altmetrics
Final-revised paper
Preprint