Articles | Volume 15, issue 3
https://doi.org/10.5194/acp-15-1351-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-1351-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Effects of molecular weight and temperature on liquid–liquid phase separation in particles containing organic species and inorganic salts
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, V6T 1Z1, Canada
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, V6T 1Z1, Canada
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- New Mechanism of Extractive Electrospray Ionization Mass Spectrometry for Heterogeneous Solid Particles S. Kumbhani et al. 10.1021/acs.analchem.7b04164
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- Effect of Acidity on Ice Nucleation by Inorganic–Organic Mixed Droplets Z. Lei et al. 10.1021/acsearthspacechem.3c00242
- Does liquid–liquid phase separation impact ice nucleation in mixed polyethylene glycol and ammonium sulfate droplets? Y. Yao et al. 10.1039/D2CP04407B
- Effects of High Acidity on Phase Transitions of an Organic Aerosol D. Losey et al. 10.1021/acs.jpca.8b00399
- Characterization of aerosol composition, aerosol acidity, and organic acid partitioning at an agriculturally intensive rural southeastern US site T. Nah et al. 10.5194/acp-18-11471-2018
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45 citations as recorded by crossref.
- Mie scattering from optically levitated mixed sulfuric acid–silica core–shell aerosols: observation of core–shell morphology for atmospheric science M. McGrory et al. 10.1039/D1CP04068E
- Aerosol Optical Tweezers Constrain the Morphology Evolution of Liquid-Liquid Phase-Separated Atmospheric Particles K. Gorkowski et al. 10.1016/j.chempr.2019.10.018
- Geometric Analysis of Free and Accessible Volume in Atmospheric Nanoparticles P. Mermigkis et al. 10.1021/acsomega.3c03293
- Water diffusion in atmospherically relevant α-pinene secondary organic material H. Price et al. 10.1039/C5SC00685F
- Temperature-Dependent Phase Transitions of Aqueous Aerosol Droplet Systems in Microfluidic Traps P. Roy et al. 10.1021/acsearthspacechem.0c00114
- Advanced aerosol optical tweezers chamber design to facilitate phase-separation and equilibration timescale experiments on complex droplets K. Gorkowski et al. 10.1080/02786826.2016.1224317
- Kinetic Limitation to Inorganic Ion Diffusivity and to Coalescence of Inorganic Inclusions in Viscous Liquid–Liquid Phase-Separated Particles M. Fard et al. 10.1021/acs.jpca.7b05242
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- Morphology of Liquid–Liquid Phase Separated Aerosols Y. Qiu & V. Molinero 10.1021/jacs.5b05579
- New Mechanism of Extractive Electrospray Ionization Mass Spectrometry for Heterogeneous Solid Particles S. Kumbhani et al. 10.1021/acs.analchem.7b04164
- Flash Freeze Flow Tube to Vitrify Aerosol Particles at Fixed Relative Humidity Values T. Kucinski et al. 10.1021/acs.analchem.9b05757
- Effect of Acidity on Ice Nucleation by Inorganic–Organic Mixed Droplets Z. Lei et al. 10.1021/acsearthspacechem.3c00242
- Does liquid–liquid phase separation impact ice nucleation in mixed polyethylene glycol and ammonium sulfate droplets? Y. Yao et al. 10.1039/D2CP04407B
- Effects of High Acidity on Phase Transitions of an Organic Aerosol D. Losey et al. 10.1021/acs.jpca.8b00399
- Characterization of aerosol composition, aerosol acidity, and organic acid partitioning at an agriculturally intensive rural southeastern US site T. Nah et al. 10.5194/acp-18-11471-2018
- Phase Behavior of Internal Mixtures of Hydrocarbon-like Primary Organic Aerosol and Secondary Aerosol Based on Their Differences in Oxygen-to-Carbon Ratios F. Mahrt et al. 10.1021/acs.est.1c07691
- Effects of inorganic salts on the heterogeneous OH oxidation of organic compounds: insights from methylglutaric acid–ammonium sulfate H. Lam et al. 10.5194/acp-19-9581-2019
- Influence of particle-phase state on the hygroscopic behavior of mixed organic–inorganic aerosols N. Hodas et al. 10.5194/acp-15-5027-2015
- Prediction of Phase State of Secondary Organic Aerosol Internally Mixed with Aqueous Inorganic Salts Z. Yu et al. 10.1021/acs.jpca.1c06773
- Phase Transitions in Organic and Organic/Inorganic Aerosol Particles M. Freedman et al. 10.1146/annurev-physchem-083122-115909
- Liquid–Liquid Phase Separation in Aerosol Particles: Imaging at the Nanometer Scale R. O’Brien et al. 10.1021/acs.est.5b00062
- Inconsistency of ammonium–sulfate aerosol ratios with thermodynamic models in the eastern US: a possible role of organic aerosol R. Silvern et al. 10.5194/acp-17-5107-2017
- Insights into the morphology of multicomponent organic and inorganic aerosols from molecular dynamics simulations K. Karadima et al. 10.5194/acp-19-5571-2019
- Direct Measurement of pH in Individual Particles via Raman Microspectroscopy and Variation in Acidity with Relative Humidity J. Rindelaub et al. 10.1021/acs.jpca.5b12699
- Nitroarylurea-terminated supramolecular polymers that exhibit facile thermal repair and aqueous swelling-induced sealing of defects B. Baker et al. 10.1016/j.polymer.2018.02.029
- Size Dependence of Liquid–Liquid Phase Separation by in Situ Study of Flowing Submicron Aerosol Particles P. Ohno et al. 10.1021/acs.jpca.2c08224
- On the implications of aerosol liquid water and phase separation for organic aerosol mass H. Pye et al. 10.5194/acp-17-343-2017
- Fine particle pH and gas–particle phase partitioning of inorganic species in Pasadena, California, during the 2010 CalNex campaign H. Guo et al. 10.5194/acp-17-5703-2017
- The Role of Organic Aerosol in Atmospheric Ice Nucleation: A Review D. Knopf et al. 10.1021/acsearthspacechem.7b00120
- Direct observation for relative-humidity-dependent mixing states of submicron particles containing organic surfactants and inorganic salts C. Xiong et al. 10.5194/acp-23-8979-2023
- Influence of Ions on the Size Dependent Morphology of Aerosol Particles E. Ott & M. Freedman 10.1021/acsearthspacechem.1c00210
- Fine particle pH and the partitioning of nitric acid during winter in the northeastern United States H. Guo et al. 10.1002/2016JD025311
- Effects of Sucrose on Phase Transitions of Organic/Inorganic Aerosols E. Ott et al. 10.1021/acsearthspacechem.0c00006
- Study on the Mass transfer and hygroscopic behavior of glucose / ammonium sulfate aerosol droplets P. Chang & Z. Chen 10.1016/j.jaerosci.2024.106365
- Relative-humidity-dependent organic aerosol thermodynamics via an efficient reduced-complexity model K. Gorkowski et al. 10.5194/acp-19-13383-2019
- Photoinitiated Degradation Kinetics of the Organic UV Filter Oxybenzone in Solutions and Aerosols: Impacts of Salt, Photosensitizers, and the Medium A. Cooper et al. 10.1021/acsestair.4c00149
- Phase separation in organic aerosol M. Freedman 10.1039/C6CS00783J
- Fluorescence Aerosol Flow Tube Spectroscopy to Detect Liquid–Liquid Phase Separation P. Ohno et al. 10.1021/acsearthspacechem.1c00061
- Liquid–Liquid Phase Separation in Supermicrometer and Submicrometer Aerosol Particles M. Freedman 10.1021/acs.accounts.0c00093
- Liquid–liquid phase separation and evaporation of a laser-trapped organic–organic airborne droplet using temporal spatial-resolved Raman spectroscopy A. Kalume et al. 10.1039/C8CP02372G
- Dynamics of Liquid–Liquid Phase Separation in Submicrometer Aerosol T. Kucinski et al. 10.1021/acs.jpca.1c01985
- Heterogeneous and Photosensitized Oxidative Degradation Kinetics of the Plastic Additive Bisphenol-A in Sea Spray Aerosol Mimics S. Kruse & J. Slade 10.1021/acs.jpca.3c00127
- Insight into the interaction between water and surfactant aerosol particles based on molecular dynamics simulations C. Zhang et al. 10.1016/j.partic.2022.09.005
- Liquid-liquid phase separation in subcellular assemblages and signaling pathways: Chromatin modifications induced gene regulation for cellular physiology and functions including carcinogenesis S. Chakraborty et al. 10.1016/j.biochi.2024.05.007
- Emulsified and Liquid–Liquid Phase-Separated States of α-Pinene Secondary Organic Aerosol Determined Using Aerosol Optical Tweezers K. Gorkowski et al. 10.1021/acs.est.7b03250
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Latest update: 23 Nov 2024
Short summary
The first set of studies illustrates that the liquid/liquid phase separation relative humidity (SRH) does not depend strongly on molecular weight. The second set of studies shows that for most particle types and temperature range studied, SRH does not depend strongly on temperature. SRH did depend strongly on temperature for particles containing α,4-dihydroxy-3-methoxybenzeneacetic acid mixed with ammonium bisulfate due to a combination of low temperature and low water content.
The first set of studies illustrates that the liquid/liquid phase separation relative humidity...
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