Articles | Volume 15, issue 23
https://doi.org/10.5194/acp-15-13377-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-13377-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
03 Dec 2015
Research article |
| 03 Dec 2015
Organic nitrate aerosol formation via NO3 + biogenic volatile organic compounds in the southeastern United States
B. R. Ayres
Department of Chemistry, Reed College, Portland, OR, USA
H. M. Allen
Department of Chemistry, Reed College, Portland, OR, USA
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA, USA
D. C. Draper
Department of Chemistry, Reed College, Portland, OR, USA
Department of Chemistry, University of California, Irvine, CA, USA
S. S. Brown
Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
R. J. Wild
Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
J. L. Jimenez
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
D. A. Day
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
P. Campuzano-Jost
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
W. Hu
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
J. de Gouw
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
A. Koss
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO, USA
R. C. Cohen
Department of Chemistry, University of California at Berkeley, CA, USA
K. C. Duffey
Department of Chemistry, University of California at Berkeley, CA, USA
P. Romer
Department of Chemistry, University of California at Berkeley, CA, USA
K. Baumann
Applied Research Associates, Inc., Research Triangle Park, NC, USA
E. Edgerton
Applied Research Associates, Inc., Research Triangle Park, NC, USA
S. Takahama
Department of Environmental Engineering, École polytechnique fédérale de Lausanne (EPFL), Switzerland
J. A. Thornton
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
B. H. Lee
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
F. D. Lopez-Hilfiker
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
C. Mohr
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
Karlsruhe Institute of Technology, Karlsruhe, Germany
P. O. Wennberg
Division of Geological and Planetary Sciences and Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA, USA
T. B. Nguyen
Division of Geological and Planetary Sciences and Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA, USA
A. Teng
Division of Geological and Planetary Sciences and Division of Engineering and Applied Science, California Institute of Technology, Pasadena, CA, USA
A. H. Goldstein
Department of Environmental Science, Policy, and Management, University of California, Berkeley, CA, USA
Department of Environmental Science, Policy, and Management, University of California, Berkeley, CA, USA
Department of Chemistry, Reed College, Portland, OR, USA
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107 citations as recorded by crossref.
- Chemistry of Secondary Organic Aerosol Formation from Reactions of Monoterpenes with OH Radicals in the Presence of NOx M. DeVault et al. 10.1021/acs.jpca.2c04605
- Development of a portable cavity ring down spectroscopy instrument for simultaneous, in situ measurement of NO3 and N2O5 Z. Li et al. 10.1364/OE.26.00A433
- Evaluation of isoprene nitrate chemistry in detailed chemical mechanisms A. Mayhew et al. 10.5194/acp-22-14783-2022
- Comparison of methods of functional group analysis using results from laboratory and field aerosol measurements M. Claflin et al. 10.1080/02786826.2021.1918325
- Simulation of organic nitrates in Pearl River Delta in 2006 and the chemical impact on ozone production X. Chen et al. 10.1007/s11430-017-9115-5
- Source apportionment of organic carbon in Centreville, AL using organosulfates in organic tracer-based positive matrix factorization A. Hettiyadura et al. 10.1016/j.atmosenv.2018.05.007
- Real-world emission characteristics of semivolatile/intermediate-volatility organic compounds originating from nonroad construction machinery in the working process X. Shen et al. 10.1016/j.scitotenv.2022.159970
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- Evaluation of the New Capture Vaporizer for Aerosol Mass Spectrometers (AMS): Elemental Composition and Source Apportionment of Organic Aerosols (OA) W. Hu et al. 10.1021/acsearthspacechem.8b00002
- Day and night-time formation of organic nitrates at a forested mountain site in south-west Germany N. Sobanski et al. 10.5194/acp-17-4115-2017
- Characterization of Organic Aerosol at a Rural Site in the North China Plain Region: Sources, Volatility and Organonitrates Q. Zhu et al. 10.1007/s00376-020-0127-2
- Direct measurement of NO<sub>3</sub> radical reactivity in a boreal forest J. Liebmann et al. 10.5194/acp-18-3799-2018
- Simultaneous measurement of NO and NO<sub>2</sub> by a dual-channel cavity ring-down spectroscopy technique Z. Li et al. 10.5194/amt-12-3223-2019
- New Reactions for the Formation of Organic Nitrate in the Atmosphere G. Li et al. 10.1021/acsomega.2c03321
- Using “Local Climate Zones” to Detect Urban Heat Island on Two Small Cities in Alabama J. Chieppa et al. 10.1175/EI-D-17-0020.1
- Discrepancies between modeled and observed nocturnal isoprene in an urban environment and the possible causes: A case study in Houston L. Diao et al. 10.1016/j.atmosres.2016.07.009
- Ubiquity of organic nitrates from nighttime chemistry in the European submicron aerosol A. Kiendler‐Scharr et al. 10.1002/2016GL069239
- Determination of Semivolatile Organic Nitrates in Ambient Atmosphere by Gas Chromatography/Electron Ionization–Mass Spectrometry R. Li et al. 10.3390/atmos10020088
- Vertically increased NO3 radical in the nocturnal boundary layer Y. Yan et al. 10.1016/j.scitotenv.2020.142969
- Chemical Characterization of Highly Functionalized Organonitrates Contributing to Night-Time Organic Aerosol Mass Loadings and Particle Growth W. Huang et al. 10.1021/acs.est.8b05826
- Exposure to volatile organic compounds (VOCs) at gas stations: a probabilistic analysis C. Jia et al. 10.1007/s11869-021-01124-5
- Secondary PM<sub>2.5</sub> decreases significantly less than NO<sub>2</sub> emission reductions during COVID lockdown in Germany V. Balamurugan et al. 10.5194/acp-22-7105-2022
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Short summary
This paper reports atmospheric gas- and aerosol-phase field measurements from the southeastern United States in summer 2013 to demonstrate that the oxidation of biogenic volatile organic compounds by nitrate radical produces a substantial amount of secondary organic aerosol in this region. This process, driven largely by monoterpenes, results in a comparable aerosol nitrate production rate to inorganic nitrate formation by heterogeneous uptake of HNO3 onto dust particles.
This paper reports atmospheric gas- and aerosol-phase field measurements from the southeastern...
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