MAX-DOAS tropospheric nitrogen dioxide column measurements compared with the Lotos-Euros air quality model

Abstract. A 14-month data set of MAX-DOAS (Multi-Axis Differential Optical Absorption Spectroscopy) tropospheric NO₂ column observations in De Bilt, the Netherlands, has been compared with the regional air quality model Lotos-Euros. The model was run on a 7×7 km² grid, the same resolution as the emission inventory used. A study was performed to assess the effect of clouds on the retrieval accuracy of the MAX-DOAS observations. Good agreement was found between modeled and measured tropospheric NO₂ columns, with an average difference of less than 1% of the average tropospheric column (14.5 · 10¹⁵ molec cm⁻²). The comparisons show little cloud cover dependence after cloud corrections for which ceilometer data were used. Hourly differences between observations and model show a Gaussian behavior with a standard deviation (σ) of 5.5 · 10¹⁵ molec cm⁻². For daily averages of tropospheric NO₂ columns, a correlation of 0.72 was found for all observations, and 0.79 for cloud free conditions. The measured and modeled tropospheric NO₂ columns have an almost identical distribution over the wind direction. A significant difference between model and measurements was found for the average weekly cycle, which shows a much stronger decrease during the weekend for the observations; for the diurnal cycle, the observed range is about twice as large as the modeled range. The results of the comparison demonstrate that averaged over a long time period, the tropospheric NO₂ column observations are representative for a large spatial area despite the fact that they were obtained in an urban region. This makes the MAX-DOAS technique especially suitable for validation of satellite observations and air quality models in urban regions.